Citation: Ling Hua CAO, Hong Yun GAO, Chuan Jian ZHOU, Yu Ting LIU. The Synthesis of Glycosyl Phosphite-Pt(Ⅱ) Complexes[J]. Chinese Chemical Letters, ;2004, 15(2): 171-174. shu

The Synthesis of Glycosyl Phosphite-Pt(Ⅱ) Complexes

1.
College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046;
2.
State Key Laboratory of Elements-Organic Chemistry, Nankai University, Tianjin 300071

Received Date: 12 February 2003

Fund Project: This work was supported by the National Natural Science Foundation of China (Grant No. 29962002) and Nankai University State Key Laboratory of Elemento-Organic Chemistry.

Ethylene glycol phosphorochloridite 1 or catechol phosphorochloridite 2 reacted with isopropylidene derivatives of D-glucose, D-galactose, D-mannose and D-fructose, a series of glycosyl phosphites were obtained. These glycosyl phosphites form optically active complexes with simple Pt (Ⅱ) salts. Pt (Ⅱ) is coordinated to the phosphorus atom, most of the metal complexes are quite stable.
- Glycosyl phosphite,
- metal complex,
- synthesis
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