Citation: ZHANG Xinghua, Robert West. ORGANOSILANE POLYMERS: OXIDATION—CROSSLINKABLE CYCLOTETRAMETHYLENESILYLENE POLYMER AND COPOLYMERS[J]. Chinese Journal of Polymer Science, ;1987, 5(2): 156-161. shu

ORGANOSILANE POLYMERS: OXIDATION—CROSSLINKABLE CYCLOTETRAMETHYLENESILYLENE POLYMER AND COPOLYMERS

Received Date: 23 August 1986

Polysilane polymers containing cyclotetramethylenesilylene units were synthesized by sodium coupling of diorganodichlorosilanes in toluene. These polymers are soluble in common solvents, can be formed into a variety of shapes by molding, castihg, coating or potting. They can be crosslinked by irradiation and oxidation at moderate or room temperature.
1. [1]
  Man Xu , Qianyi Li , Jingyao Ma , Hao Li , Yunfei Zhu , Fan Yu , Kuande Wang , Tao Zhou , Quanyou Feng , Linghai Xie , Jinyi Lin . Wide bandgap steric carbazole-fluorene-nanogrid polymers via metal-free CN polymerization for deep-blue polymer light-emitting diodes. Chinese Chemical Letters, 2026, 37(1): 111551-. doi: 10.1016/j.cclet.2025.111551
2. [2]
  Lizhuang Zhong , Ming Liu , Shilong Su , Dongxin Zeng , Jing Hu , Zhiqian Guo . Engineering stimuli-responsive block copolymers for multimodal bioimaging. Chinese Chemical Letters, 2026, 37(1): 111512-. doi: 10.1016/j.cclet.2025.111512
3. [3]
  Zixu Xie , Pengfei Zhang , Ziyao Zhang , Chen Chen , Xing Wang . The choice of antimicrobial polymers: Hydrophilic or hydrophobic?. Chinese Chemical Letters, 2024, 35(9): 109768-. doi: 10.1016/j.cclet.2024.109768
4. [4]
  Hanying Li , Wee-Liat Ong . “Super-heterojunctioned” thermoelectric polymers. Chinese Chemical Letters, 2025, 36(2): 110523-. doi: 10.1016/j.cclet.2024.110523
5. [5]
  Bowen Xu , Jiahao Chen , Lulu Cui , Xinyue Li , Yuan Xue , Sheng Han . Terpolymers of alkyl methacrylate-trans anethole-1,2,3,6-tetrahydrophthalic anhydride copolymers: A low dosage and high-efficiency cold flow improver for diesel fuel. Chinese Chemical Letters, 2025, 36(5): 110196-. doi: 10.1016/j.cclet.2024.110196
6. [6]
  Xiaoman Dang , Zhiying Wu , Tangxin Xiao , Zhouyu Wang , Leyong Wang . Highly robust supramolecular polymer networks crosslinked by metallacycles. Chinese Chemical Letters, 2024, 35(12): 110208-. doi: 10.1016/j.cclet.2024.110208
7. [7]
  Yaohua Li , Qi Cao , Xuanhua Li . Tailoring the configuration of polymer passivators in perovskite solar cells. Chinese Journal of Structural Chemistry, 2025, 44(2): 100413-100413. doi: 10.1016/j.cjsc.2024.100413
8. [8]
  Dayang Xie , Qiannan Cao , Huapan Fang , Yanhui Li , Huayu Tian . Applications and challenges of biomedical polymer materials in pulmonary diseases. Chinese Chemical Letters, 2026, 37(2): 111032-. doi: 10.1016/j.cclet.2025.111032
9. [9]
  Peng Meng , Qian-Cheng Luo , Aidan Brock , Xiaodong Wang , Mahboobeh Shahbazi , Aaron Micallef , John McMurtrie , Dongchen Qi , Yan-Zhen Zheng , Jingsan Xu . Molar ratio induced crystal transformation from coordination complex to coordination polymers. Chinese Chemical Letters, 2024, 35(4): 108542-. doi: 10.1016/j.cclet.2023.108542
10. [10]
  Pengcheng Su , Shizheng Chen , Zhihong Yang , Ningning Zhong , Chenzi Jiang , Wanbin Li . Vapor-phase postsynthetic amination of hypercrosslinked polymers for efficient iodine capture. Chinese Chemical Letters, 2024, 35(9): 109357-. doi: 10.1016/j.cclet.2023.109357
11. [11]
  Zhenzhong MEI , Hongyu WANG , Xiuqi KANG , Yongliang SHAO , Jinzhong GU . Syntheses and catalytic performances of three coordination polymers with tetracarboxylate ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1795-1802. doi: 10.11862/CJIC.20240081
12. [12]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
13. [13]
  Wei-Jia Wang , Kaihong Chen . Molecular-based porous polymers with precise sites for photoreduction of carbon dioxide. Chinese Chemical Letters, 2025, 36(1): 109998-. doi: 10.1016/j.cclet.2024.109998
14. [14]
  Xiumei LI , Linlin LI , Bo LIU , Yaru PAN . Syntheses, crystal structures, and characterizations of two cadmium(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 613-623. doi: 10.11862/CJIC.20240273
15. [15]
  Jiming XI , Yukang TENG , Rui ZHANG , Zhenzhong LU . Fluorescent coordination polymers based on anthracene-and pyrene-derivative ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 847-854. doi: 10.11862/CJIC.20240367
16. [16]
  Hui Liu , Baoying Xiao , Yaming Zhao , Wei Wang , Qiong Jia . Adsorption of heavy metals with hyper crosslinked polymers: Progress, challenges and perspectives. Chinese Chemical Letters, 2025, 36(8): 110619-. doi: 10.1016/j.cclet.2024.110619
17. [17]
  Qunpeng Duan , Qiaona Zhang , Jiayuan Zhang , Shihao Lin , Tangxin Xiao , Leyong Wang . Artificial light-harvesting systems based on supramolecular polymers ^✩. Chinese Chemical Letters, 2025, 36(12): 111421-. doi: 10.1016/j.cclet.2025.111421
18. [18]
  Wenjing Dai , Lan Luo , Zhen Yin . Interface reconstruction of hybrid oxide electrocatalysts for seawater oxidation. Chinese Journal of Structural Chemistry, 2025, 44(3): 100442-100442. doi: 10.1016/j.cjsc.2024.100442
19. [19]
  Tiankai Sun , Hui Min , Zongsu Han , Liang Wang , Peng Cheng , Wei Shi . Rapid detection of nanoplastic particles by a luminescent Tb-based coordination polymer. Chinese Chemical Letters, 2024, 35(5): 108718-. doi: 10.1016/j.cclet.2023.108718
20. [20]
  Mengjun Sun , Zhi Wang , Jvhui Jiang , Xiaobing Wang , Chuang Yu . Gelation mechanisms of gel polymer electrolytes for zinc-based batteries. Chinese Chemical Letters, 2024, 35(5): 109393-. doi: 10.1016/j.cclet.2023.109393

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1441)
HTML views(22)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return