Citation: Tian Ying GUO, Dong Lin TANG, Jing Wei ZHU, Mou Dao SONG, Bang Hua ZHANG. RAFT Miniemulsion Polymerization of MMA with Cumyl Dithiobenzoate as Chain Transfer Agent[J]. Chinese Chemical Letters, ;2006, 17(9): 1247-1250. shu

RAFT Miniemulsion Polymerization of MMA with Cumyl Dithiobenzoate as Chain Transfer Agent

Key Laboratory of Functional Polymer Materials, Ministry of Education, Institute of Polymer Chemistry, Nankai University, Tianjin 300071

Received Date: 3 March 2006

Fund Project: We gratefully appreciate the financial support of Tianjin Committee of Science and Technology (No. 043602711).

Reversible addition-fragmentation transfer (RAFT) miniemulsion polymerizations for PMMA with cumyl dithiobenzoate (CDB) as a chain transfer agent (CTA) has been carried out.Higher temperature made the polymerization much faster and the PDI remained below 1.20, when the temperature was upon 70℃.
- RAFT polymerization,
- miniemulsion,
- chain transfer agent,
- cumyl dithiobenzoate
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