Citation: Yu Lai HU, Jian Hua YU, Shi Yan YANG, Yuan Qi YIN, Jin Xian WANG. Nickel (Ⅱ) Complex Catalyzed Conjugate Addition Reaction of Functionalized Organozinc Reagents to α,β-Unsaturated Esters[J]. Chinese Chemical Letters, ;1999, 10(1): 17-18. shu

Nickel (Ⅱ) Complex Catalyzed Conjugate Addition Reaction of Functionalized Organozinc Reagents to α,β-Unsaturated Esters

a State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000;
b Department of Chemistry, Northwest Normal University, Lanzhou 730070

Received Date: 28 July 1998

Functionalized organozinc reagents can easily under 1, 4-addition reaction with unsaturated esters in the presence of catalytic amount of Ni (acac)₂ and tertiary amines under very mild conditions to give the products in excellent yields.
- Conjugate addition reaction,
- organozinc reagents,
- α, β-unsaturated esters,
- nickel complex,
- catalysis
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