Citation: Xin Yi ZHU, Wei Qiang ZHANG, Yu Hua ZHANG, Li Ren CHEN, Yong Min LI. Application of High Performance Liquid Chromatography to Separation of Novel Chiral Tetrahedral Heterometal Clusters[J]. Chinese Chemical Letters, ;2003, 14(9): 942-945. shu

Application of High Performance Liquid Chromatography to Separation of Novel Chiral Tetrahedral Heterometal Clusters

Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000

Received Date: 21 October 2002

A series of novel chiral tetrahedral heterometal clusters have firstly been separated oncellulose tris-(3,5-dimethylphenylcarbamate) stationary phase by high performance liquid chrom-atography, using hexane as the mobile phase with various alcohols as modifiers.
- Chiral stationary phase,
- cellulose tris-(3,
- 5-dimethylphenylcarbamate),
- mobile-phase composition,
- chiral tetrahedral clusters,
- enantioseparation
1. [1]
  Jun-Hui Zhang , Rui-Xue Liang , Bin Huang , Li-Qin Yu , Juan Chen , Bang-Jin Wang , Sheng-Ming Xie , Li-Ming Yuan . Preparation of a homochiral metal-organic cage and its bonded silicas for efficient enantioseparation in high-performance liquid chromatography and gas chromatography. Chinese Chemical Letters, 2026, 37(1): 111146-. doi: 10.1016/j.cclet.2025.111146
2. [2]
  Genlin Sun , Yachun Luo , Zhihong Yan , Hongdeng Qiu , Weiyang Tang . Chiral metal-organic frameworks-based materials for chromatographic enantioseparation. Chinese Chemical Letters, 2024, 35(12): 109787-. doi: 10.1016/j.cclet.2024.109787
3. [3]
  Ya-Xuan Xue , Han Xu , Jia-Nan Chen , Hai-Quan Tian , Tao Jia , Wei-Dong Liu , Chong-Yang Li , La-Sheng Long , Lan-Sun Zheng , Xiang-Jian Kong . Chiral Ln3Co5 clusters with geometry-dependent chiroptical and magneto-optical properties. Chinese Journal of Structural Chemistry, 2026, 45(1): 100764-100764. doi: 10.1016/j.cjsc.2025.100764
4. [4]
  Wangyan Hu , Ke Li , Xiangnan Dou , Ning Li , Xiayan Wang . Nano-sized stationary phase packings retained by single-particle frit for microchip liquid chromatography. Chinese Chemical Letters, 2024, 35(4): 108806-. doi: 10.1016/j.cclet.2023.108806
5. [5]
  Tong Zhang , Xiaojing Liang , Licheng Wang , Shuai Wang , Xiaoxiao Liu , Yong Guo . An ionic liquid assisted hydrogel functionalized silica stationary phase for mixed-mode liquid chromatography. Chinese Chemical Letters, 2025, 36(1): 109889-. doi: 10.1016/j.cclet.2024.109889
6. [6]
  Zhen Liu , Zhi-Yuan Ren , Chen Yang , Xiangyi Shao , Li Chen , Xin Li . Asymmetric alkenylation reaction of benzoxazinones with diarylethylenes catalyzed by B(C₆F₅)₃/chiral phosphoric acid. Chinese Chemical Letters, 2024, 35(5): 108939-. doi: 10.1016/j.cclet.2023.108939
7. [7]
  Gui-Xin Yan , Er-Xia Chen , Jin-Xia Yang , Jian Zhang , and Qipu Lin . Chiral europium-organotin oxo-clusters with dual-emission circularly polarized luminescence. Chinese Journal of Structural Chemistry, 2025, 44(12): 100759-100759. doi: 10.1016/j.cjsc.2025.100759
8. [8]
  Mao-Fan Li , Ming‐Yu Guo , De-Xuan Liu , Xiao-Xian Chen , Wei-Jian Xu , Wei-Xiong Zhang . Multi-stimuli responsive behaviors in a new chiral hybrid nitroprusside salt (R-3-hydroxypyrrolidinium)₂[Fe(CN)₅(NO)]. Chinese Chemical Letters, 2024, 35(12): 109507-. doi: 10.1016/j.cclet.2024.109507
9. [9]
  Yu Tian , Yijun Lin , Siyu Deng , Yinghe Tan , Xuanyi Bie , Zhaoyang Chen , Pangkuan Chen . Metal-Coordinate Complexes (M = 3d, 4f) with Enhanced Circularly Polarized Luminescence in Planar Chiral Pillar[5]arenes. Chinese Journal of Structural Chemistry, 2025, 44(8): 100626-100626. doi: 10.1016/j.cjsc.2025.100626
10. [10]
  Cui-Ting Yang , Dan-Dan Wang , Shuai Chen , Jian-Mei Yang , Jun-Nan He , Jun-Hui Zhang , Xiao-Qing Liu , Jin Zhang , Lei Zhang , Yan Zhao . A chiral supramolecular nanocatcher prepared by d-biotin-pillar[5]arene for the selective capture and targeted delivery of oxaliplatin enantiomers. Chinese Chemical Letters, 2025, 36(9): 110820-. doi: 10.1016/j.cclet.2025.110820
11. [11]
  Zhiwen Li , Jingjing Zhang , Gao Li . Dynamic assembly of chiral golden knots. Chinese Journal of Structural Chemistry, 2024, 43(7): 100300-100300. doi: 10.1016/j.cjsc.2024.100300
12. [12]
  Bo Luo , Mingfang Ma , Aiyou Hao , Pengyao Xing . Arene-perfluoroarene force driven chiral transfer, chiral amplification and chiral inversion. Chinese Chemical Letters, 2026, 37(1): 111736-. doi: 10.1016/j.cclet.2025.111736
13. [13]
  Yongjing Deng , Feiyang Li , Zijian Zhou , Mengzhu Wang , Yongkang Zhu , Jianwei Zhao , Shujuan Liu , Qiang Zhao . Chiral induction and Sb³⁺ doping in indium halides to trigger second harmonic generation and circularly polarized luminescence. Chinese Chemical Letters, 2024, 35(8): 109085-. doi: 10.1016/j.cclet.2023.109085
14. [14]
  Yuan Liu , Zhu Yin , Xintuo Yang , Jiajia Cheng . Advances in photocatalytic deracemization of sp³-hybridized chiral centers via hydrogen atom transfer. Chinese Chemical Letters, 2025, 36(5): 110521-. doi: 10.1016/j.cclet.2024.110521
15. [15]
  Shengyu Zhao , Qinhao Shi , Wuliang Feng , Yang Liu , Xinxin Yang , Xingli Zou , Xionggang Lu , Yufeng Zhao . Suppression of multistep phase transitions of O3-type cathode for sodium-ion batteries. Chinese Chemical Letters, 2024, 35(5): 108606-. doi: 10.1016/j.cclet.2023.108606
16. [16]
  Linxin Zheng , Shuai Li , Liuting Zhang , Tao Zhong , Xiuzhen Wang , Ting Bian , Petr Senin , Ying Wu . A MOF derived multi-phase FeNi₃-S catalyst for efficient hydrogen storage in magnesium hydride. Chinese Chemical Letters, 2026, 37(1): 110414-. doi: 10.1016/j.cclet.2024.110414
17. [17]
  Junying LI , Xinyan CHEN , Xihui DIAO , Muhammad Yaseen , Chao CHEN , Hao WANG , Chuansong QI , Wei LI . Chiral fluorescent sensor Tb³⁺@Cd-CP based on camphoric acid for the enantioselective recognition of R- and S-propylene glycol. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2497-2504. doi: 10.11862/CJIC.20240084
18. [18]
  Fuxing Yang , Mengjie Gong , Yifei Zhang , Bangchi Wei , Nan Huang , Jun Jiang . Organocatalytic enantioselective construction of axially chiral phosphorodithiolated styrenes. Chinese Chemical Letters, 2026, 37(1): 111219-. doi: 10.1016/j.cclet.2025.111219
19. [19]
  Ze Cao , Chenqi Ge , Yating Wu , Hua Tang , Yueyan Kuang , Yuyang Wu , Hao Li . Self-assembled chiral cages for anion recognition. Chinese Chemical Letters, 2026, 37(3): 111554-. doi: 10.1016/j.cclet.2025.111554
20. [20]
  Haitao Liu , Youlin Deng , Dan Ling , Lingzhu Chen , Zhichao Jin . Asymmetric catalysis for the synthesis of planar chiral ferrocene derivatives. Chinese Chemical Letters, 2026, 37(3): 111793-. doi: 10.1016/j.cclet.2025.111793

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1238)
HTML views(32)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return