Citation: Xi Kui WANG, Xiao Mei WANG, Guang Tong XU, Ping Rui MENG. SYNTHESIS OF DIALKYL TETRABROMOPHTHALATES BY PTC AND THEIR FLAME RETARDANCY[J]. Chinese Chemical Letters, ;1995, 6(11): 935-938. shu

SYNTHESIS OF DIALKYL TETRABROMOPHTHALATES BY PTC AND THEIR FLAME RETARDANCY

Applied Chemistry Department, Shandong Institute of Building Materials, Jinan 250022

Received Date: 31 March 1995

Fund Project: The project was supported by the National Natural Science Foundation of China.

Eight dialkyl tetrabromophthalates(DATBPs) were synthesized by reacting tetrabromophthalic anhydride with excess alcohols which were used not only as a reactant but also as a solvent and using a quaternary ammonium salt as a phase transfer catalyst(PTC).The yields were found to be between 85-93%.Their structures were characterized by IR,NMR and elementary analysis.The flame retardant properties of the compounds were also studied.
1. [1]
  Liping GUO . Synthesis and crystal structure characterization of yttrium imido complex: The reactivity of 2-substituted-1-amino-o-carborane with yttrium dialkyl complex. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1409-1415. doi: 10.11862/CJIC.20250065
2. [2]
  Xuan Song , Teng Fu , Yajie Yang , Yahan Kuang , Xiuli Wang , Yu-Zhong Wang . Spatial-confinement combustion strategy enabling free radicals chemiluminescence direct-measurement in flame-retardant mechanism. Chinese Chemical Letters, 2025, 36(5): 110699-. doi: 10.1016/j.cclet.2024.110699
3. [3]
  Yaxuan Fu , Xiaozhi Jiang , Chenyang Shi , Long Chen , Zhendong Yang , Mengran Wang , Bo Hong , Faping Zhong , Yanqing Lai . The role of flame-retardant electrolytes in lithium-ion batteries: Custom design for improved battery-level safety. Chinese Chemical Letters, 2026, 37(4): 110972-. doi: 10.1016/j.cclet.2025.110972
4. [4]
  Xing Cao , Xinyu Tian , Yuanyuan Huang , Liping Zhang , Yanpeng Ni , Yu-Zhong Wang . H₃PO₃-protonated chitosan enabling flame-retardant and antibacterial PVA composite films with high strength and toughness through multiple H-bonds and interlocking interfaces. Chinese Chemical Letters, 2025, 36(11): 111382-. doi: 10.1016/j.cclet.2025.111382
5. [5]
  Huimin Luan , Qinming Wu , Jianping Wu , Xiangju Meng , Feng-Shou Xiao . Templates for the synthesis of zeolites. Chinese Journal of Structural Chemistry, 2024, 43(4): 100252-100252. doi: 10.1016/j.cjsc.2024.100252
6. [6]
  Hang Wang , Qi Wang , Chuan-De Wu . Continuous synthesis of ammonia. Chinese Journal of Structural Chemistry, 2025, 44(3): 100437-100437. doi: 10.1016/j.cjsc.2024.100437
7. [7]
  Zhaojun Liu , Zerui Mu , Chuanbo Gao . Alloy nanocrystals: Synthesis paradigms and implications. Chinese Journal of Structural Chemistry, 2023, 42(11): 100156-100156. doi: 10.1016/j.cjsc.2023.100156
8. [8]
  Zhenhao Wang , Yuliang Tang , Ruyu Li , Shuai Tian , Yu Tang , Dehai Li . Bioinspired synthesis of cochlearol B and ganocin A. Chinese Chemical Letters, 2024, 35(7): 109247-. doi: 10.1016/j.cclet.2023.109247
9. [9]
  Hui Jin , Qin Cai , Peiwen Liu , Yan Chen , Derong Wang , Weiping Zhu , Yufang Xu , Xuhong Qian . Multistep continuous flow synthesis of Erlotinib. Chinese Chemical Letters, 2024, 35(4): 108721-. doi: 10.1016/j.cclet.2023.108721
10. [10]
  Jingjing Zhang , Xinrui Gu , Gao Li . Robust Metal Nanoclusters for Electrocatalytic Synthesis. Chinese Journal of Structural Chemistry, 2025, 44(8): 100650-100650. doi: 10.1016/j.cjsc.2025.100650
11. [11]
  Caihong Mao , Yanfeng He , Xiaohan Wang , Yan Cai , Xiaobo Hu . Synthesis and molecular recognition characteristics of a tetrapodal benzene cage. Chinese Chemical Letters, 2024, 35(8): 109362-. doi: 10.1016/j.cclet.2023.109362
12. [12]
  Mei Peng , Wei-Min He . Photochemical synthesis and group transfer reactions of azoxy compounds. Chinese Chemical Letters, 2024, 35(8): 109899-. doi: 10.1016/j.cclet.2024.109899
13. [13]
  Liyong Ding , Zhenhua Pan , Qian Wang . 2D photocatalysts for hydrogen peroxide synthesis. Chinese Chemical Letters, 2024, 35(12): 110125-. doi: 10.1016/j.cclet.2024.110125
14. [14]
  Xiaoyu Chen , Jiahao Hu , Jingyi Lin , Haiyang Huang , Changqing Ye , Hongli Bao . Biisoindolylidene solvatochromic fluorophores: Synthesis and photophysical properties. Chinese Chemical Letters, 2025, 36(2): 109923-. doi: 10.1016/j.cclet.2024.109923
15. [15]
  Tengfei Xuan , Xinyu Zhang , Wei Han , Yidong Huang , Weiwu Ren . Total synthesis of (+)-taberdicatine B and (+)-tabernabovine B. Chinese Chemical Letters, 2025, 36(2): 109816-. doi: 10.1016/j.cclet.2024.109816
16. [16]
  Mengyu Wu , Kewei Ren , Chengyu Zou , Jiacheng Chen , Rui Ma , Chuan Zhu , Chao Feng . A general synthesis of gem–difluorobicyclo[2.1.1]hexanes. Chinese Chemical Letters, 2025, 36(5): 110213-. doi: 10.1016/j.cclet.2024.110213
17. [17]
  Zhi-Lin Wu , Rong-Nan Yi , Chunlin Zhuang . Electrochemical synthesis strategy for the development of antitumor selenoheterocyclic compounds. Chinese Chemical Letters, 2025, 36(10): 111408-. doi: 10.1016/j.cclet.2025.111408
18. [18]
  Xuan Pan , Tao Sheng , Zhanzhu Liu . A concise total synthesis of monoterpenoid indole alkaloid (-)-voacafricine A. Chinese Chemical Letters, 2025, 36(10): 110913-. doi: 10.1016/j.cclet.2025.110913
19. [19]
  Hongjin Xu , Jinghua Wu , Hui Wang , Huanfeng Jiang , Zhiqiang Ma . Asymmetric total synthesis of (–)-14-epi-sinugyrosanolide A. Chinese Chemical Letters, 2026, 37(3): 112018-. doi: 10.1016/j.cclet.2025.112018
20. [20]
  Haitao Liu , Youlin Deng , Dan Ling , Lingzhu Chen , Zhichao Jin . Asymmetric catalysis for the synthesis of planar chiral ferrocene derivatives. Chinese Chemical Letters, 2026, 37(3): 111793-. doi: 10.1016/j.cclet.2025.111793

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(1385)
HTML views(34)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return