Citation: Rui Nian HUA, Zhi Hong JIA, De Min XIE, Chun Shan SHI. Synthesis of the Complex Fluoride LiBaF₃ through a Solvothermal Process[J]. Chinese Chemical Letters, ;2002, 13(10): 1021-1024. shu

Synthesis of the Complex Fluoride LiBaF₃ through a Solvothermal Process

1.
Faculty of Chemistry, Northeast Normal University, Changchun 130024;
2.
Key Laboratory of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022

Received Date: 15 January 2002

Fund Project: This work was supported by the State Key Project of Foundation Research (G1998061306) and the National Natural Science Foundation of China (50072031).

The complex fluoride LiBaF₃ is solvothermally synthesized at 180℃ and characterized by means of X-ray powder diffraction, scanning electron microscopy, thermogravimetric analysis and infrared spectroscopy. In the solvothermal process, the solvents, mole ratios of initial mixtures and reaction temperature play important roles in the growth of the single crystal.
- Solvothermal synthesis,
- complex fluoride
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