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Citation: OU Guang-Chuan, HUANG Zhong-Wen, PAN Ze-Yi, ZHOU Dong-Lai, YUAN Xian-You. Synthesis and Characterization of Two Binuclear Macrocyclic Zinc(Ⅱ) Complexes by Anion Exchange[J]. Chinese Journal of Structural Chemistry, ;2014, 33(6): 903-908. shu

Synthesis and Characterization of Two Binuclear Macrocyclic Zinc(Ⅱ) Complexes by Anion Exchange

a.
a. Department of Biology and Chemistry, Hunan University of Science and Engineering, Yongzhou, Hunan 425199, China;
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b. Key Laboratory of Functional Organometallic Materials of Hunan Province College, Hengyang Normal University, Hengyang, Hunan 421008, China

Received Date: 25 October 2013
Available Online: 27 February 2014
Fund Project: National Undergraduate Training Programs for Innovation and Entrepreneurship (201310551158) (2013-191) the Key Laboratory of Functional Organometallic Materials of Hunan Province College (13K09, 13K10) (201310551158) the Program for Excellent Talents in Hunan University of Science and Engineering, the Construct Program of the Key Discipline in Hunan Province (2011-76) (13B029, 13A030) the Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province (2012-318) (13K09, 13K10)

Two macrocyclic zinc(Ⅱ) complexes {[ZnL(VO₃)₂]·0.33H₂O}_n (1) and [ZnL(H₂O)₂][Ni(CN)₄] (2) (L=5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane) have been obtained from the reactions of [ZnL](ClO₄)₂ with NH₄VO₃ and K₂[Ni(CN)₄], respectively, and structurally characterized by elemental analysis, IR, XRPD, TG and X-ray diffraction. Single-crystal X-ray diffraction analyses indicated that the Zn(Ⅱ) atom lies on an inversion center and is octahedrally coordinated by four nitrogen atoms of the tetradentate macrocyclic ligand in the equatorial plane and two oxygen atoms of [VO₄] tetrahedra in the axial positions in 1, and two oxygen atoms of two water molecules in 2. Complex 1 shows a three-dimensional structure, which is constructed by the links of [VO₃]_n^n- chains with [ZnL]²⁺, forming one-dimensional channels occupied by guest water molecules. The monomers of [ZnL(H₂O)₂]²⁺ and [Ni(CN)₄]^2- are connected through the intermolecular hydrogen bonds to form a two-dimensional sheet in complex 2.
- macrocyclic zinc(Ⅱ) complexes,
- binuclear,
- vanadium,
- anion exchange
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