Citation: De Liang LONG, Xin Quan XIN, Bao Sheng LUO, Liao Rong CHEN, Kai Bei YU. CRYSTAL STRUCTURE OF (Et₄N)₂Pd(i-MNT)₂ AND ITS REACTION WITH (Et₄N)₂WS₄ (i-MNT＝S₂CC(CN)₂^2-)[J]. Chinese Chemical Letters, ;1995, 6(10): 899-902. shu

CRYSTAL STRUCTURE OF (Et₄N)₂Pd(i-MNT)₂ AND ITS REACTION WITH (Et₄N)₂WS₄ (i-MNT＝S₂CC(CN)₂^2-)

1.
State Key Laboratory of Coordination Chemistry, Naming University, Nanjing 210093;
2.
Analysis and Testing Center, Wuhan University, Wuhan 430072;
3.
Chengdu Center of Analysis and Determination, Academia Sinica, Chengdu 610041

Received Date: 23 March 1995

(Et₄N)₂Pd(i-mnt)₂,fw=647.04,monociinic,space group P2₁/c;a=9.511(1),b=11.612(2),c=14.820(3)Å,β=94.38(1)°, V=1631.9(5)Å³, Z=2, D_c=1.32 g·cm^-3, F(000)=672, R=0.0324, R_W=0.0298. This is a new example of X-ray characterized Pd complexes with bivalent anion 1,1-dithiolato ligands and its reaction with(Et₄N)₂WS₄ gives (Et₄N)₂WS₄Pd(i-mnt).
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