Citation: Zhi Huan WENG, Jin Yan WANG, Xi Gao JIAN. Heteropolymolybdate as a New Reaction-controlled Phase-transfer Catalyst for Efficient Alcohol Oxidation with Hydrogen Peroxide[J]. Chinese Chemical Letters, ;2006, 17(6): 848-850. shu

Heteropolymolybdate as a New Reaction-controlled Phase-transfer Catalyst for Efficient Alcohol Oxidation with Hydrogen Peroxide

Department of Polymer Science and Materials, Dalian University of Technology, Liaoning High Performance Polymer Engineering Research Center, Dalian 116012

Received Date: 7 December 2005

Fund Project: This work was financially supported by the National High Technology Research and Development Program of China (863 Program) (No. 2003AA33G030).

A new catalytic process for the synthesis of aldehyde from alcohol by oxidation with H₂O₂ with high selectivity was studied. In this system, heteropolymolybdate [C₇H₇N(CH₃)₃]₃{PO₄[MoO(O₂)₂]₄} was utilized as the reaction-controlled phase-transfer catalyst to catalyze oxidation of benzyl and aliphatic alcohols. The molar ratio of H₂O₂ and alcohol was 0.75, no other by-products were detected by gas chromatography, the results of oxidation reaction indicated that the catalyst has high activity and stability.
- Heteropolymolybdate,
- reaction-controlled phase-transfer,
- alcohol,
- oxidation
1. [1]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
2. [2]
  Yufeng ZHANG , Haotian QI , Jingya ZHONG , Leiming LANG , Guojun YUAN , Siqi LU , Haiying WANG , Guangxiang LIU . S-anion effects on the improvement of adsorption capacity and performance for benzyl alcohol electro-oxidation catalysts. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2591-2600. doi: 10.11862/CJIC.20250282
3. [3]
  Xinyu Gu , Jun Yu , Huiyu Sun , Nannan Zhang , Zhengying Wu , Yukou Du . One-step synthesis of trimetallic PdCuNi porous nanoflowers for enhanced alcohol oxidation. Chinese Chemical Letters, 2026, 37(1): 111756-. doi: 10.1016/j.cclet.2025.111756
4. [4]
  Hai-Bo Huang , Fang-Long Sun , Ze Luo , Meng-Yu Sun , Ben-Hao Liu , Xu-Sheng Wang , Hua Tang . MOF@MOF hierarchical heterotructures for enhanced photocatalytic H2O2 production and furfuryl alcohol oxidation. Chinese Journal of Structural Chemistry, 2025, 44(11): 100717-100717. doi: 10.1016/j.cjsc.2025.100717
5. [5]
  Gang Hu , Chun Wang , Qinqin Wang , Mingyuan Zhu , Lihua Kang . The controlled oxidation states of the H₄PMo₁₁VO₄₀ catalyst induced by plasma for the selective oxidation of methacrolein. Chinese Chemical Letters, 2025, 36(2): 110298-. doi: 10.1016/j.cclet.2024.110298
6. [6]
  Xia Chen , Ting Dai , Meng-Ying Yin , Xing-Yuan Xia , Qiu-Ju Xing , Lei Tian , Jian-Ping Zou . Enhanced anodic mass transfer enables interfacial Cl^• for efficient ammonia oxidation. Chinese Chemical Letters, 2026, 37(3): 111445-. doi: 10.1016/j.cclet.2025.111445
7. [7]
  Yi Zhang , Biao Wang , Chao Hu , Muhammad Humayun , Yaping Huang , Yulin Cao , Mosaad Negem , Yigang Ding , Chundong Wang . Fe–Ni–F electrocatalyst for enhancing reaction kinetics of water oxidation. Chinese Journal of Structural Chemistry, 2024, 43(2): 100243-100243. doi: 10.1016/j.cjsc.2024.100243
8. [8]
  Guo Yang , Kai Li , Hanshi Qu , Jianbing Zhu , Chunyu Ru , Meiling Xiao , Wei Xing , Changpeng Liu . Tailoring OH* adsorption strength on Ni/NbO_x for boosting alkaline hydrogen oxidation reaction via oxygen vacancy. Chinese Chemical Letters, 2025, 36(7): 110150-. doi: 10.1016/j.cclet.2024.110150
9. [9]
  Nana Yang , Rui Yuan , Xinyue Fu , Xiao Tian , Jin Yu , Shengzhou Ma , Liuqing Wen , Jiabin Zhang . Concise synthesis of NDP-activated uronic acid by an oxidation reaction insertion strategy. Chinese Chemical Letters, 2025, 36(8): 110757-. doi: 10.1016/j.cclet.2024.110757
10. [10]
  Yiming Jin , Mingming Pan , Wei Luo . Ir/Ni-N-C electrocatalyst with promoted CO-tolerance towards alkaline hydrogen oxidation reaction. Chinese Journal of Structural Chemistry, 2026, 45(1): 100760-100760. doi: 10.1016/j.cjsc.2025.100760
11. [11]
  Manman Ou , Yunjian Zhu , Jiahao Liu , Zhaoxuan Liu , Jianjun Wang , Jun Sun , Chuanxiang Qin , Lixing Dai . Polyvinyl alcohol fiber with enhanced strength and modulus and intense cyan fluorescence based on covalently functionalized graphene quantum dots. Chinese Chemical Letters, 2025, 36(2): 110510-. doi: 10.1016/j.cclet.2024.110510
12. [12]
  Jingxiong Jiang , Yao Dong , Yuchun Wang , Lijuan Qi , Zhen-Yu Li , Tai-Bao Wei , Wen-Juan Qu , Qi Lin , Bingbing Shi . Separation of toluene-alcohol azeotropes by porous crystals of fluorinated leaning pillar[6]arene. Chinese Chemical Letters, 2025, 36(8): 110759-. doi: 10.1016/j.cclet.2024.110759
13. [13]
  Xiao Li , Wanqiang Yu , Yujie Wang , Ruiying Liu , Qingquan Yu , Riming Hu , Xuchuan Jiang , Qingsheng Gao , Hong Liu , Jiayuan Yu , Weijia Zhou . Metal-encapsulated nitrogen-doped carbon nanotube arrays electrode for enhancing sulfion oxidation reaction and hydrogen evolution reaction by regulating of intermediate adsorption. Chinese Chemical Letters, 2024, 35(8): 109166-. doi: 10.1016/j.cclet.2023.109166
14. [14]
  Fenglin Wang , Chengwei Kuang , Zhicheng Zheng , Dan Wu , Hao Wan , Gen Chen , Ning Zhang , Xiaohe Liu , Renzhi Ma . Noble metal clusters substitution in porous Ni substrate renders high mass-specific activities toward oxygen evolution reaction and methanol oxidation reaction. Chinese Chemical Letters, 2025, 36(6): 109989-. doi: 10.1016/j.cclet.2024.109989
15. [15]
  Weixu Li , Yuexin Wang , Lin Li , Xinyi Huang , Mengdi Liu , Bo Gui , Xianjun Lang , Cheng Wang . Promoting energy transfer pathway in porphyrin-based sp2 carbon-conjugated covalent organic frameworks for selective photocatalytic oxidation of sulfide. Chinese Journal of Structural Chemistry, 2024, 43(7): 100299-100299. doi: 10.1016/j.cjsc.2024.100299
16. [16]
  Yan Zhao , Zhenming Tian , Qisen Jia , Ting Yao , Jiashu Li , Yanan Wang , Xuejing Cui , Jing Liu , Xin Chen , Luhua Jiang . Crystal orientation dependent charge transfer dynamics and interfacial water configuration boosting photoelectrocatalytic water oxidation to H2O2. Chinese Journal of Structural Chemistry, 2025, 44(7): 100619-100619. doi: 10.1016/j.cjsc.2025.100619
17. [17]
  Huixin Chen , Chen Zhao , Hongjun Yue , Guiming Zhong , Xiang Han , Liang Yin , Ding Chen . Unraveling the reaction mechanism of high reversible capacity CuP₂/C anode with native oxidation PO_x component for sodium-ion batteries. Chinese Chemical Letters, 2025, 36(1): 109650-. doi: 10.1016/j.cclet.2024.109650
18. [18]
  Mengzhao Liu , Jie Yin , Chengjian Wang , Weiji Wang , Yuan Gao , Mengxia Yan , Ping Geng . P doped Ni₃S₂ and Ni heterojunction bifunctional catalysts for electrocatalytic 5-hydroxymethylfurfural oxidation coupled hydrogen evolution reaction. Chinese Chemical Letters, 2025, 36(9): 111271-. doi: 10.1016/j.cclet.2025.111271
19. [19]
  Zongyi Huang , Cheng Guo , Quanxing Zheng , Hongliang Lu , Pengfei Ma , Zhengzhong Fang , Pengfei Sun , Xiaodong Yi , Zhou Chen . Efficient photocatalytic biomass-alcohol conversion with simultaneous hydrogen evolution over ultrathin 2D NiS/Ni-CdS photocatalyst. Chinese Chemical Letters, 2024, 35(7): 109580-. doi: 10.1016/j.cclet.2024.109580
20. [20]
  Yan-Jia Lin , Qing-Xin Zeng , Xiao-Min Shen , Shou-Tian Zheng , Xin-Xiong Li . Construction of metal cluster-based materials directed by a bifunctional pyridyl tripodal alcohol ligand according to hard and soft acid-base theory. Chinese Journal of Structural Chemistry, 2025, 44(10): 100702-100702. doi: 10.1016/j.cjsc.2025.100702

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1348)
HTML views(23)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return