Citation: Dong-Ju Zhou, Li-Bo Dai, Hui Ni, Gen-Lei Hui, Si-Guo Yuan. Preparation and characterization of polyphenylene sulfide-based chelating fibers[J]. Chinese Chemical Letters, ;2014, 25(2): 221-225. shu

Preparation and characterization of polyphenylene sulfide-based chelating fibers

Dong-Ju Zhou ^a,b ,
Li-Bo Dai ^a ,
Hui Ni ^a ,
Gen-Lei Hui ^a ,
Si-Guo Yuan ^a,,

1.
a College of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou 450001, China;
2.
b College of Chemical and Pharmaceutical Engineering, Henan University of Science and Technology, Luoyang 470003, China

Corresponding author: Si-Guo Yuan,
Received Date: 22 July 2013
Available Online: 6 November 2013
Fund Project: We gratefully acknowledge generous support by the National Natural Science Foundation of China (No. 20574063) (No. 20574063) Doctoral Foundation of Ministry of Education of China (No. 20104101110005). (No. 20104101110005)

A series of novel chelating fibers containing sulfur, nitrogen, oxygen heteroatoms were prepared via the functionalization of chloromethylated polyphenylene sulfide (CMPPS). The structures, micromorphology and physicochemical properties of these fibrous adsorptive materials were characterized by FT-IR, elementary analysis, TG and SEM-EDS. The results show that chelating fibers had high functional group contents (3.94 mmol/g for thiourea, 3.85 mmol/g for mercapto, 5.00 mmol/g for methylamine and 6.07 mmol/g for ethylenediamine, respectively). Owing to the unique matrix of polyphenylene sulfide fiber, these fibrous adsorbents possess excellent thermostability. This syntheticmethod proved a simple and efficient way for the preparation of chelating fibers.
- Polyphenylene sulfide,
- Thiourea,
- Thiol,
- Amination,
- Chelating fiber
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