Citation: Jian-Chao Liu, Ying Liang, Hong-Wu He. Synthesis, characterization and herbicidal activity of new thiazoline derivatives[J]. Chinese Chemical Letters, ;2013, 24(3): 233-235. shu

Synthesis, characterization and herbicidal activity of new thiazoline derivatives

1.
a College of Chemistry, Central China Normal University, Wuhan 430079, China;
2.
b Hubei Biopesticide Engineering Research Center, Hubei Academy of Agricultural Science, Wuhan 430064, China

Corresponding author: Hong-Wu He,
Received Date: 19 November 2012
Available Online: 6 January 2013

A series of new thiazoline derivatives 2-alkyl(aryl) imino-4-amino-5-ethoxycarbonyl-3-phenyl-3Hthiazoline (3) and bis(2-imino-4-amino-5-ethoxycarbonyl-3-phenyl-3H-thiazoline alkylene (4) have been synthesized by reactions of intermediate 4-amino-5-ethoxycarbonyl-2-methylthio-3-phenyl-3H-thiazolinium sulphate (2) with alkylamines or arylamine in 64%-89% yields. The structures of 3 and 4 have been confirmed by ¹H NMR, EI-MS, IR spectroscopy and elemental analyses. Some compounds exhibited high or moderate herbicidal activities against the roots of rapeseed and barnyard grass at 100 mg/L.
- Thiazoline,
- Alkylamine,
- Arylamine,
- Herbicidal activity
References
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  [11] G. Turan-Zitouni, D.M. Sivaci, Z.A. Kaplancikli, A. Ozdemir, Synthesis and antimicrobial activity of some pyridinyliminothiazoline derivatives, Il Farmaco 57 (2002) 569-572.
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  [12] M.W. Ding, S.J. Yang, J. Zhu, New efficient synthesis of 2-substituted 5,6,7,8-tetrahydro-benzo-thieno[2,3-d]pyrimidin-4(3H)-ones, Synthesis 1 (2004) 75-79.
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  [13] J.C. Liu, H.W. He, Synthesis, characterization and fungicidal activity of new thienopyridopyrimidine derivatives, Synth. Commun. 42 (2012) 2075-2082.
14. [14]
  [14] B.F. Han, Q.M. Shi, X.F. Wang, et al., Synthesis and bioactivity of novel 3-(1-hydroxyethylidene)-5-substituted-pyrrolidine-2,4-dione derivatives, Chin. Chem. Lett. 23 (2012) 1023-1026.
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis, characterization and herbicidal activity of new thiazoline derivatives

References

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通讯作者: 陈斌, bchen63@163.com