Citation: Shao-Lei Xie, Yong-Hai Hui, Xiang-Ju Long, Chang-Chun Wang, Zheng-Feng Xie. Aza-Michael addition reactions between nitroolefins and benzotriazole catalyzed by MCM-41 immobilized heteropoly acids in water[J]. Chinese Chemical Letters, ;2013, 24(01): 28-30. shu

Aza-Michael addition reactions between nitroolefins and benzotriazole catalyzed by MCM-41 immobilized heteropoly acids in water

1.
Key Laboratory of Oil&Gas Fine Chemicals, Ministry of Education&Xinjiang Uyghur Autonomous Region, College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, China

Corresponding author: Yong-Hai Hui, Zheng-Feng Xie,
Received Date: 21 October 2012
Available Online: 30 November 2012

MCM-41 supported heteropoly acids(HPAs)catalysts were synthesized,characterized and their catalytic activity was evaluated in an aza-Michael addition reaction between nitroolefins and benzotriazole in water at room temperature.50 wt%PW/MCM-41 showed the highest activity(up to 96%yield).The catalyst was used in six consecutive experiments without obvious loss of activity, confirming the success of the anchoring process and the catalyst stability.
- Aza-Michael addition,
- MCM-41,
- Heteropoly acids,
- Heterogenous catalysts
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沈阳化工大学材料科学与工程学院沈阳 110142