Citation: Hong Liang SUN, Yu Qiu GONG. ¹HNMR STUDY OF INTRAMOLECULAR STACKING IN TERNARY PALLADIUM (Ⅰ) COMPLEXES INVOLVING ADENOSLNE 5'-TRIPHOSPHATE AND LIGANDS CONTAINING OXYGEN AND/OR NITROGEN AS DONOR ATOMS[J]. Chinese Chemical Letters, ;1995, 6(4): 315-316. shu

¹HNMR STUDY OF INTRAMOLECULAR STACKING IN TERNARY PALLADIUM (Ⅰ) COMPLEXES INVOLVING ADENOSLNE 5'-TRIPHOSPHATE AND LIGANDS CONTAINING OXYGEN AND/OR NITROGEN AS DONOR ATOMS

a Department of Food, Hangzhou Institute of Commerce, Hangzhou 310035;
b Department of Chemistry, Hangzhou University, Hangzhou 310028

Received Date: 7 November 1994

Fund Project: Project was supported by the National Natural Science Foundation of China.

The intramolecular aromatic-ring stacking interaction of mixed-ligand complexes Pd (A) (ATP)^2- in the system Pd²⁺-A-ATP^4- has been determined by ¹HNMR,where A=1,10-phenanthroline (Phen),2,2'-bipyridyl (Bpy) and L-tryptophan (Trp^-);ATP^4-=adenosine 5'-triphosphate.The result indicates that it is the partial stacking between the indole ring of ATP^4- and the heterocyclic ring of A that makes H(2),H(8) and H(1') in the ATP^4- shift upfield significantly.Accordingly,the order of aromatic-ring interaction in the mixed-ligand complexes has been obtained as follows:Pd (Phen) (ATP)^2- > Pd(Bpy) (ATP)^2- > Pd(Trp) (ATP)^3-.
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