Citation: Ji Tao WANG, Yun WenZHANG, Yu Ming XU, Chun Ming CUI. SYTHESE AND REACTIONS OF HETEROBINUCLEAR COMPLEXES[PhCl₂SnM(Cl)(CO)₃(CH₃CN)₂] (M=Mo, W)[J]. Chinese Chemical Letters, ;1993, 4(7): 641-644. shu

SYTHESE AND REACTIONS OF HETEROBINUCLEAR COMPLEXES[PhCl₂SnM(Cl)(CO)₃(CH₃CN)₂] (M=Mo, W)

Department of Chemistry, Nankai University, 300071, Tianjin

Received Date: 13 January 1993

Fund Project: Supported by THE NATIONAL SCIENCE FOUNDATION OF CHINA.

The complexes[M(CO)₃(CH₃CN)₃] (M=Mo, W) react with an equimolar quantity of PhSnCl₃ in dichloromethane at room tempreture to afford new heterobinuclear complexes[PhCl₂SnM(Cl)(CO)₃(CH3CN)₂] [M=Mo (1); W (2)].The complexes react with two equivalents of PR₂R'(R=Ph, R'=Ph, Me; R=Cy, R'=H) to yield stablecomplexes[PhCl₂SnM(Cl)(CO)₃(PR₂R')₂].Reaction of[PhCl₂SnM (Cl) (CO)₃(CH₃CN)₂]with one equivalent of PPh₂(CH₂)nPPh₂(n=I,2) or bulky phosphine ligands PBu₂^tCl in dichloromethane at room tempreture to give[PhCl₂SnMo(Cl)(CO)₃{PPh₂(CH₂)n-PPh₂}].CH₂Cl₂,[PhCl₂SnMo(Cl)(CO)₃PBu₂^tCl].CH₂Cl₂, respectively.The complexes 1 and 2 react with phosphite donor ligands P(OMe)₃ to give[PhCl₂SnM(Cl)(CO)₂-{P(OMe)₃}₃].All complexes have been characterized by elemental analysis, IR and ¹HNMR spectroscopies.Here we report the preliminary results of this work.
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