Citation: Yan LI, Wen-Zhen WANG, Chang-Sheng TANG, Xin-Gang JIA, Wei FAN, Li WANG. A Novel Tripyridyldiamine Nickel Complex: Synthesis, Structure and Characterization[J]. Chinese Journal of Structural Chemistry, ;2021, 40(1): 91-95. doi: 10.14102/j.cnki.0254–5861.2011–2771 shu

A Novel Tripyridyldiamine Nickel Complex: Synthesis, Structure and Characterization

School of Chemistry and Chemical Engineering, Xi'an Shiyou University, Xi'an 710065, China

Corresponding author: Wen-Zhen WANG, wzwang@xsyu.edu.cn
Received Date: 19 February 2020
Accepted Date: 25 May 2020

Fund Project: the National Natural Science Foundation of China 11847140the Natural Science Foundation of Shannxi Province 2019JZ-44the Natural Science Foundation of Shannxi Province 2017JQ2009the Natural Science Basic Research Plan in Shaanxi Province of China 2019JQ-490the Scientific Research Program Funds by Shannxi Provincial Education Department Z18165the Xi'an Shiyou University Postgraduate Innovation and Practical Ability Training Project YCS17211017

Figures(5)

A novel nickel(II) complex [Ni(H₂tpda)(NCS)₂(CH₃OH)] was synthesized by using tripyridyldiamine as ligand and Ni(NCS)₂ as starting materials, and characterized by a variety of techniques including single-crystal X-ray diffraction, IR spectroscopy and TG-DSC. The single-crystal structure reveals that the complex exhibits as a neutral molecule and that the central atom Ni(II) is octahedrally coordinated by an H₂tpda, two NCS^- ions and a ligand molecule CH₃OH. The 3D supramolecular network is formed through hydrogen bonds and π-π interactions. The complex can catalyze the addition reaction of carbon dioxide and propylene oxide.
- tripyridyldiamine,
- functional complexes,
- supramolecular chemistry,
- crystal structures
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