Citation: Shan-Shan GUO, Lv-Lan HUANG, Ying-Xiang YE, Li-Zhen LIU, Zi-Zhu YAO, Sheng-Chang XIANG, Jin-Dan ZHANG, Zhang-Jing ZHANG. Carbazole Based Anionic MOF for Proton Conductivity[J]. Chinese Journal of Structural Chemistry, ;2021, 40(1): 55-60. doi: 10.14102/j.cnki.0254–5861.2011–2761 shu

Carbazole Based Anionic MOF for Proton Conductivity

a.
College of Chemistry and Materials Science, Fujian Provincial Key Laboratory of Polymer Materials, Fujian Normal University, Fuzhou 350007, China
b.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: Sheng-Chang XIANG, scxiang@fjnu.edu.cn Jin-Dan ZHANG, zhangjindan@fjnu.edu.cn Zhang-Jing ZHANG, zzhang@fjnu.edu.cn
Received Date: 10 February 2020
Accepted Date: 29 February 2020

Fund Project: the National Natural Science Foundation of China 21673039the National Natural Science Foundation of China 21573042the National Natural Science Foundation of China 21805039the National Natural Science Foundation of China 21975044the National Natural Science Foundation of China 21971038the Fujian Provincial Department of Science and Technology 2018J07001the Fujian Provincial Department of Science and Technology 2019H6012Education Department of Fujian province JT180090

Figures(3)

A non-interpenetrated anionic In-MOF (FJU-302) based on a linear H₂bpdc and an angled H₂cdc as dual-ligands was characterized by FT-IR, TGA and X-ray single-crystal/powder diffraction. FJU-302 crystallizes in the monoclinic system and I4₁/amd space group with a = 27.1274(8), b = 27.1274(8), c = 29.788(3) Å, V = 21921(2) Å³, Z = 16, M_r = 608.32, D_c = 0.737 g/cm³, F(000) = 4848, μ(CuKα) = 3.659 mm^–1, R = 0.0800 and wR = 0.1911 for 5703 observed reflections (I > 2σ(I)), and R = 0.1470 and wR = 0.2342 for all data. In this work, a carbazole based anionic In-MOF (FJU-302) was designed and synthesized, and the proton conductivity from subzero temperature (–30 ℃) to 70 ℃ was measured without additional humidity. FJU-302 presents a max proton conductivity of 6.47 × 10^–4 S·cm^–1 at 70 ℃, and it can maintain 5.88 × 10^–7 S·cm^–1 at –30 ℃. This work reports a first carbazole based MOF for proton conductivity at subzero temperature conditions.
- metal-organic frameworks,
- carbazole,
- proton conductivity
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