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Citation: ZHAO Ling-Ling, WANG Hai-Feng, QI Gang. Catalytic Hydrogenation ofNitrobenzene to Aniline by Ag/γ-Fe2O3[J]. Chinese Journal of Structural Chemistry, ;2016, 35(6): 872-878. doi: 10.14102/j.cnki.0254-5861.2011-1158 shu

Catalytic Hydrogenation ofNitrobenzene to Aniline by Ag/γ-Fe2O3

  • a.

    a. Department of Chemistry and Chemical Engineering, Yancheng Institute of Technology, Yancheng 224051, China;

  • b.

    b. Binhai County Safety Supervison Bureau, Yancheng 224500, China

  • Received Date: 29 January 2016
    Available Online: 7 April 2016

    Fund Project:

  • The Ag/γ-Fe2O3 nanocomposite was synthesized by solvothermal reduction method via using ferric nitrate and silver nitrate as raw materials, and ethylene glycol as the reducing agent. The composite was characterized by X-ray powder diffraction, scanning electron microscope, transmission electron microscope, and energy dispersive X-ray. The prepared Ag/γ-Fe2O3 was used for the catalytic hydrogenation of nitrobenzene to aniline by hydrazine hydrate. The factors such as the silver content in the catalyst, reaction time, reaction temperature and the regeneration of catalyst were investigated. The results showed that the yield of aniline reached 100% by utilizing the 1%wt (nitrobenzene) Ag/γ-Fe2O3 for the catalytic hydrogenation of nitrobenzene for 3 h to obtain aniline at 78 ℃, hydrazine hydrate as the hydrogen source, while the silver content in the catalyst was 3%mol.
  • 

    References

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      (1) Jana, S.; Ghosh, S. K.; Nath, S. Synthesis of silver nanoshell-coated cationic polystyrene beads: a solid phase catalyst for the reduction of 4-nitrophenol. Appl. Catal. A- Gen. 2006, 313, 41–48.

    2. [2]

      (2) Sonavane, S. U.; Gawande, M. B.; Deshpande, S. S. Chemoselective transfer hydrogenation reactions over nanosized γ-Fe2O3 catalyst prepared by novel combustion route. Catal. Commun. 2007, 8, 1803–1806.

    3. [3]

      (3) Benza, M.; Kraanb, A. M.; Prins, R. Reduction of aromatic nitrocompounds with hydrazine hydrate in the presence of an iron oxide hydroxide catalyst II. Activity, X-ray diffraction and Mossbauer study of the iron oxide hydroxide catalyst. Appl. Catal. A-Gen. 1998, 172, 149–157.

    4. [4]

      (4) Liu, X. M.; Li. Y. S. One-step facile fabrication of Ag/γ-Fe2O3 composite microspheres. Mater. Sci. Eng., C 2009, 29, 1128–1132.

    5. [5]

      (5) Tao, S. W.; Liu, X. Q.; Chu, X. F.; Shen, Y. S. Preparation and properties of γ-Fe2O3 and Y2O3 doped γ-Fe2O3 by a sol-gel process. Sens. Actuators, B 1999, 61, 33–38.

    6. [6]

      (6) Garza-Navarro, M.; Torres-Castro, A.; Ortiz, U. Magnetite and magnetite/silver core/shell nanoparticles with diluted magnet-like behavior. J. Solid State Chem. 2010, 183, 99–104.

    7. [7]

      (7) Fan, G. L.; Wang, J.; Li, F. Synthesis of high-surface-area micro/mesoporous ZnAl2O4 catalyst support and application in selective hydrogenation of o-chloronitrobenzene. Catal. Commun. 2011, 15, 113–117.

    8. [8]

      (8) Choudhary, V. R.; Dumbre, D. K. Supported nano-gold catalysts for epoxidation of styrene and oxidation of benzyl alcohol to benzaldehyde. Top Catal. 2009, 52, 1677–1687. Nie, R. F.; Wang, J. H.; Wang, L. N. Platinum supported on reduced graphene oxide as a catalyst for hydrogenation of nitroarenes. Carbon 2012, 50, 586–596.

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