Citation: WANG Rong-Ming, ZHANG Ming-Hui, WANG Wen, XU Yu-Wen, WANG Zhi-Ying, DAI Fang-Na, ZHANG Liang-Liang, SUN Dao-Feng. Interpenetration of Three 2D In-MOFs with (6,3) Topology: Syntheses, Structures and Fluorescent Properties[J]. Chinese Journal of Structural Chemistry, ;2016, 35(11): 1714-1722. doi: 10.14102/j.cnki.0254-5861.2011-1150 shu

Interpenetration of Three 2D In-MOFs with (6,3) Topology: Syntheses, Structures and Fluorescent Properties

1.
a College of Science, China University of Petroleum(East China), Qingdao 266580, China;
2.
b State Key Laboratory of Structural Chemistry, Fuzhou 350002, China

Received Date: 22 January 2016
Available Online: 26 May 2016
Fund Project: Supported by the National Natural Science Foundation of China (No. 21371179, 21201179) (No. 21371179, 21201179) the Fundamental Research Funds for the Central Universities (14CX02213A, 16CX05015A) (14CX02213A, 16CX05015A)the Foundation of State Key Laboratory of Structural Chemistry (20150026, 20160006) (20150026, 20160006)

Three indium metal-organic frameworks (In-MOFs),[In(BTB)(2,2'-bipy)]·NMP (1),[In(BTB)(2,2'-bipy)]·NMP·2H₂O (2), and [In(BTB)(NMP)]·0.5NMP (3), have been constructed by the solvothermal reaction of In(NO₃)₃(OH)₂·5H₂O and 1,3,5-benzenetribenzoic acid (H₃BTB) in similar reaction conditions, and characterized by single-crystal X-ray crystallography, power X-ray diffraction (PXRD), infrared spectroscopy (IR), elemental analysis (EA) and thermogravimetry analysis (TGA). Complex 1 bears a two-dimensional (2D) layered structure of 6,3-connected hcb net topology, and complexes 2 and 3 have 2-fold interpenetrating structures based on 6,3-connected layer, which display the same net topologies with the C3₃-symmetric H₃BTB ligands as 3-connected linkers and the In(Ⅲ) ions as 6-connected nodes. Moreover, the fluorescent properties of 1~3 have also been studied.
- indium complex,
- interpenetration,
- metal-organic frameworks
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