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Citation: LI Wen-Jiao, WANG Ya-Li, WANG Hai-Li, MA Yue, GUO Zhi-Lin, YU Jun-Jie, LI Li-Cun, WANG Qing-Lun, LIAO Dai-Zheng, CHENG Peng. Syntheses, Crystal Structures and Magnetic Properties of Two Nitrophenyl Substituted Nitronyl Nitroxide Radical-lanthanide Complexes[J]. Chinese Journal of Structural Chemistry, ;2016, 35(11): 1787-1796. doi: 10.14102/j.cnki.0254-5861.2011-1071 shu

Syntheses, Crystal Structures and Magnetic Properties of Two Nitrophenyl Substituted Nitronyl Nitroxide Radical-lanthanide Complexes

LI Wen-Jiao ^a ,
WANG Ya-Li ^a ,
WANG Hai-Li ^a ,
MA Yue ^a,b,, ,
GUO Zhi-Lin ^a ,
YU Jun-Jie ^a ,
LI Li-Cun ^a,b ,
WANG Qing-Lun ^a,b ,
LIAO Dai-Zheng ^a ,
CHENG Peng ^a,b

1.
a College of Chemistry, Collaborative Innovation Center of Chemical Science and Engineering, Nankai University, Tianjin 300071, China;
2.
b Key Laboratory of Advanced Energy Materials Chemistry(MOE) and TKL of Metal and Molecule Based Material Chemistry, Nankai University, Tianjin 300071, China

Corresponding author: MA Yue,
Received Date: 30 November 2015
Available Online: 23 February 2016
Fund Project: Supported by the National Natural Science Foundation of China (21471084, 21101096, 21471083, 21371104). National Innovating Experimentation Project 201410055097. 100 Projects of Creative Research for the Undergraduates of Nankai University in China (No. BX13165) (21471084, 21101096, 21471083, 21371104)

Syntheses, structures and magnetic properties of two nitrophenyl substituted nitronyl nitroxide radical-lanthanide complexes[Ln(hfac)₃(NITmNO₂)₂] (Ln=Sm(Ⅲ) (1), Tb(Ⅲ) (2), hfac=hexafluoroacetylacetonate, NITmNO₂=2-(3-nitrophenyl)-4,4,5,5-tetramethyl-imidazoline-1-oxyl-3-oxide) have been described in this paper. X-ray analysis shows that the two complexes have similar mononuclear trispin radical-Ln(Ⅲ)-radical structures, in which the central Ln(Ⅲ) ions are all eight coordinated in D^2d dodecahedral (DD) geometry formed by six oxygen atoms from three hfac and two oxygen atoms from nitronyl nitroxide. The magnetic study indicates the antiferromagnetic interaction between Sm(Ⅲ) ion and NITmNO₂ in complex 1, while weak ferromagnetic interaction between Tb(Ⅲ) ion and NITmNO₂ in complex 2.
- nitronyl nitroxide radical-lanthanide complexes,
- crystal structure,
- magnetic properties
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