Citation: ZHAO Li-Jia, ZHAORI Getu, HAN Wen-Jing, BAIYIN Menghe. Solvothermal Synthesis and Characterization of [TM(1,2-dap)₃]HgSb₂Se₅(TM=Co, Fe) with a Chain Structure[J]. Chinese Journal of Structural Chemistry, ;2016, 35(8): 1222-1230. doi: 10.14102/j.cnki.0254-5861.2011-1044 shu

Solvothermal Synthesis and Characterization of [TM(1,2-dap)₃]HgSb₂Se₅(TM=Co, Fe) with a Chain Structure

1.
a College of Chemistry & Environmental Science, Innner Mongolia Normal University, Hohhot 010022, China;
2.
b Key Laboratory for Physics and Chemistry of Functional Materials, Inner Mongolia, Hohhot 010022, China

Received Date: 5 November 2015
Available Online: 25 April 2016
Fund Project: This project was supported by the National Natural Science Foundation of China (No. 21461019) (No. 21461019)

One organic-decorated quanternaery[TM(1,2-dap)₃]HgSb₂Se₅(1,2-dap=1,2-dianinopropane, TM=Co (1), Fe (2)) compound has been solvothermally synthesized. The compounds crystallize in triclinic space group P1, with a=11.248(6), b=11.542(7), c=12.180(12)Å, V=1268.7(16)Å³, Z=2, F(000)=1010 for 1 and a=11.311(5), b=11.558(5), c=12.180(9)Å, V=1276.5(12)Å³, Z=2, F(000)=1008 for 2. The crystal structure consists of one-dimensional anionics chains composed of HgSe₄ tetrahedra and SbSe₃ trigonal pyramids sharing corners and [TM(dap)₃]²⁺ cations. The[HgSb₂Se₅^2-]_∞ anionic chains run along the [001] direction, and are surrounded by the [TM(dap)₃]²⁺ cations. Meanwhile, 8-ring[Hg₂Sb₂Se₄] and 6-ring[HgSb₂Se₂] are alternately found. The compounds were structurally characterized by elemental analysis, thermogravimetric analysis, infrared spectroscopy and UV-Vis diffuse reflectance spectroscopy.
- quaternary chalcogenidoantimonate,
- solvothermal synthesis,
- crystal structure,
- characterization
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