Citation: ZHOU Chun-Hui, ZHOU Jie, HU Zhen-Yuan, JIN Kuang, HU Jin-Song. Three New Coordination Polymers Constructed by Adjusting the Angles of Pyridyl or Imidazolyl-based Synthons: Structures and Solid UV-vis Properties[J]. Chinese Journal of Structural Chemistry, ;2016, 35(8): 1245-1252. doi: 10.14102/j.cnki.0254-5861.2011-1043 shu

Three New Coordination Polymers Constructed by Adjusting the Angles of Pyridyl or Imidazolyl-based Synthons: Structures and Solid UV-vis Properties

1.
School of Chemical Engineering, Anhui University of Science and Technology, Huainan, Anhui 232001, China

Corresponding author: HU Jin-Song,
Received Date: 4 November 2015
Available Online: 22 March 2016
Fund Project: This project was supported by the Natural Science Foundation of China (21301005) (21301005)Natural Science Foundation of Anhui Province (1408085QB31) (1408085QB31)

Three new 2D metal-organic frameworks,[M(BIDPE)₂(bdc)₂]_n (M=Co for 1, Ni for 2) and [Ni(PIDPE)₂(H₂O)₂(bdc)]_n (3) (BIDPE=4,4'-bis(imidazol-1-yl) diphenyl ether, PIDPE=4-(pyridyl)-4'-(imidazol-1-yl) diphenyl ether, bdc^2-=1,3-benzenedicarboxylate), were characterized by single-crystal X-ray diffraction, elemental analysis, PXRD, IR spectroscopy and TGA analysis. Complex 1 crystallizes in monoclinic, space group P2₁/n, with a=9.1568(12), b=16.943(2), c=15.441(2)Å, β=104.049(2)°, V=2323.9(5)Å³, D_c=1.420 g/cm³, M_r=993.83, F(000)=1026, μ=0.440 mm^-1 and Z=2. Complex 2 crystallizes in monoclinic, space group P2₁/n, with a=9.1395(17), b=17.019 (3), c=15.473(3)Å, β=104.651(2)°, V=2328.5(7)Å³, D_c=1.414 g/cm³, M_r=991.58, F(000)=1024, μ=0.487 mm^-1, Z=2. Complex 3 also belongs to the monoclinic system, space group P2₁/n, with a=11.4365(16), b=18.346(3), c=11.7068(17)Å, β=91.022(2)°, V=2455.9(6)Å³, D_c=1.422 g/cm³, M_r=1051.66, F(000)=1092, μ=0.468 mm^-1, Z=2. All complexes 1, 2 and 3 are 2D layer structures constructed from intermolecular hydrogen bonds. In addition, the solid UV-vis properties of complexes 1, 2 and 3 were also studied.
- metal-organic frameworks,
- intermolecular hydrogen bonds,
- solid UV-vis spectrum
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