Citation: XU Feng, WEI Zhen-Hong, HUANG Xiang-Lei, MEI Ying-Xuan, CAI Hu. A Hydrogen Bond Stabilized 3D Network Built from Pyrazine-2,3,5,6-tetracarboxylic Acid and 8-Hydroxyquinoline[J]. Chinese Journal of Structural Chemistry, ;2015, 34(12): 1845-1850. doi: 10.14102/j.cnki.0254-5861.2011-0775 shu

A Hydrogen Bond Stabilized 3D Network Built from Pyrazine-2,3,5,6-tetracarboxylic Acid and 8-Hydroxyquinoline

1.
College of Chemistry, Nanchang University, Nanchang 330013, China

Received Date: 22 April 2015
Available Online: 11 August 2015
Fund Project: This project was supported by the National Natural Science Foundation of China (No. 21162015) (No. 21162015)Science Foundation of State Key Laboratory of Structural Chemistry (No. 20100009) (No. 20100009)

8-Hydroxyquinoline salt of pyrazine-2,3,5,6-tetracarboxylic acid [HQ]₂[H₂pztc]·2H₂O (1) was prepared and characterized by single-crystal X-ray diffraction, NMR, IR, TGA, elemental analysis and fluorescent measurements. Compound 1 crystallizes in orthorhombic, space group Pbcn with a=9.953(3), b=15.966(3), c=16.081(5) Å, V=2555.5(13) Å³, Z=4, μ=0.122 mm^-1, D_c=1.514 Mg/m³, T=296(2) K, C₂₆H₂₂N₄O₁₂, M_r=582.48, F(000)=1208, S=1.006, R=0.0448 and wR=0.1149. Compound 1 has a three-dimensional (3D) network, in which pyrazine-2,3,5,6-tetracarboxylic acids build up two-dimensional (2D) sheets and 8-hydroxyquinoline cations and water molecules act as pillars to connect the 2D sheets into an extended 3D network through strong intermolecular hydrogen bonding and π…π stacking interactions. Especially, a very short O-H…O hydrogen bond (O…O 2.470(2) Å) between two neighboring [H₂pztc] anions was observed.
- pyrazine-2,3,5,6-tetracarboxylic acid,
- 8-hydroxyquinoline,
- hydrogen bond
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