Citation: MA Zhi-Hong, HAN Ya-Xue, WANG Hong, HAN Zhan-Gang, ZHENG Xue-Zhong, LIN Jin. Syntheses and Crystal Structures of Three Metal Carbonyl Complexes Based on Pyridyl Side Chain Functionalized Tetramethylcyclopentadienyl Ligand[J]. Chinese Journal of Structural Chemistry, ;2015, 34(6): 931-937. doi: 10.14102/j.cnki.0254-5861.2011-0639 shu

Syntheses and Crystal Structures of Three Metal Carbonyl Complexes Based on Pyridyl Side Chain Functionalized Tetramethylcyclopentadienyl Ligand

1.
a The College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang 050024, China;
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b College of Basic Medicine, Hebei Medical University, Shijiazhuang 050017, China;
3.
c Hebei Institute of Food Quality Supervision Inspection and Research, Shijiazhuang 050091, China

Corresponding author: LIN Jin,
Received Date: 14 January 2015
Available Online: 9 April 2015
Fund Project: This work was financially supported by the National Natural Science Foundation of China (No.21372061) (No.21372061)

Thermal treatment of the pyridyl side chain functionalized tetramethyl cyclopentadiene C₅Me₄CH₂(C₅H₄N) with Fe(CO)₅, Ru₃(CO)₁₂ and Mo(CO)₆ in refluxing xylene respectively gave the corresponding dinuclear metal carbonyl complexes 1~3. These complexes have been characterized by elemental analysis, IR and ¹H NMR spectra. The molecular structures of 1~3 were determined by X-ray diffraction analysis.
- cyclopentadienyl,
- lmetal carbonyl,
- X-ray diffraction
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