Citation: GUO Hang-Ming, SHEN Wei, CHEN Xiao-Ju, ZHAO Guo-Liang. Synthesis, Crystal Structure, Luminescent Property and DNA-Binding of a Cadmium Complex with 2,4-Bis-oxyacetate-benzoic Acid[J]. Chinese Journal of Structural Chemistry, ;2015, 34(7): 1080-1086. doi: 10.14102/j.cnki.0254-5861.2011-0562 shu

Synthesis, Crystal Structure, Luminescent Property and DNA-Binding of a Cadmium Complex with 2,4-Bis-oxyacetate-benzoic Acid

a.
a. Jinhua Radio and Television University, Jinhua 321022, China;
b.
b. College of Chemistry and Life Science, Zhejiang Normal University, Jinhua 321004, China;
c.
c. Xingzhi College, Zhejiang Normal University, Jinhua 321004, China

Received Date: 6 November 2014
Available Online: 11 February 2015
Fund Project: The project was supported by the Natural Science Project of Zhejiang Province (LY12B01003) (LY12B01003)

A complex [Cd₂Na₂(BOABA)₂(H₂O)₈]·H₂O (1) was synthesized by using 2,4-bisoxyacetate-benzoic acid (H₃BOABA) and Cd(OH)₂. It was characterized by elemental analysis, IR spectra, and single-crystal X-ray diffraction. Complex 1 shows a two-dimensional 3-connected rigid plane. The interactions between the ligand and its complex with DNA were studied by EtBr fluorescence probe. Photoluminescent studies indicate that the complex may be excellent candidates for potential photoactive materials.
- Cd complex,
- 2,4-bis-oxyacetate-benzoic acid,
- crystal structure,
- DNA-binding,
- photoluminescence
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