Citation: HUO Li-Ni, CHEN Rui, LIAO Yan-Fang, WEI Jan-Hua, LI Pei-Yuan, HU Yue. Synthesis, Crystal Structure and Antibacterial Activity of Ammonium Bromide[J]. Chinese Journal of Structural Chemistry, ;2015, 34(5): 667-672. doi: 10.14102/j.cnki.0254-5861.2011-0539 shu

Synthesis, Crystal Structure and Antibacterial Activity of Ammonium Bromide

HUO Li-Ni ^a ,
CHEN Rui ^b,, ,
LIAO Yan-Fang ^c ,
WEI Jan-Hua ^a ,
LI Pei-Yuan ^a ,
HU Yue ^a

1.
a College of Pharmacy, Guangxi University of Chinese Medicine, Nanning 530001, China;
2.
b Faculty of Chinese Medicine Science, Guangxi University of Chinese Medicine, Nanning 530001, China;
3.
c Guangxi Research Institute of Chemical Industry, Nanning 530001, China

Corresponding author: CHEN Rui,
Received Date: 20 October 2014
Available Online: 4 March 2015
Fund Project: Supported by the National Natural Science Foundation of China (No.51263002) (No.51263002) Natural Science Foundation of Guangxi Province (No.2014GXNSFBA118182) (No.2014GXNSFBA118182) the Scientific Research Fund of Guangxi Provincial Education Department (No.YB2014181) (No.YB2014181)subject for Guangxi University of Chinese Medicine (No.QN14017) (No.QN14017)

The new title compound N-(2-hydroxy ethyl) tetrahydropalmatine ammonium bromide has been synthesized starting from palmatine hydrochloride. The structure of the product was confirmed by ¹H NMR, MS (ESI) and single-crystal X-ray diffraction. The title compound crystallizes in the triclinic system, space group P1 with a=10.5887(11), b=10.8652(9), c=12.0914(12) Å, β=84.808(9)°, V=1253.3(2) Å³, Z=2, D_c=1.355 g/cm³, F(000)=530, μ=1.680 mm^-1, the final R=0.0833 and wR=0.2371 for 5112 observed reflections (I>2σ(I)). X-ray analysis indicates that the two planar parts (C(2) C(3) C(4) C(5) C(6) C(7) N(1) C(20) C(21) C(21)) and (C(7) C(8) C(9) C(10) C(12) C(14) N(15) C(16) C(17)) are not coplanar, with the dihedral angles to be 67.9°. Weak interactions mainly between O(5)-H(5)···O from two water molecules and O(5)···Br are observed.
- palmatine hydrochloride,
- crystal structure,
- antibacterial activities
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