Citation: Deepanjali Pandey, Shahid S. Narvi, Gopal K. Mehrotra, Raymond J. Butcher. Hydrogen Bonded 3D Molecular Self Assembly Constructed from [(Ni(nicotinamide)₂(thiocyanate)₂(H₂O)₂] Complex Showing Spin Canted Anti-ferromagnetic Character[J]. Chinese Journal of Structural Chemistry, ;2015, 34(5): 777-785. doi: 10.14102/j.cnki.0254-5861.2011-0259 shu

Hydrogen Bonded 3D Molecular Self Assembly Constructed from [(Ni(nicotinamide)₂(thiocyanate)₂(H₂O)₂] Complex Showing Spin Canted Anti-ferromagnetic Character

1.
a Department of Chemistry, Motilal Nehru National Institute of Technology Allahabad-211004, India;
b Department of Chemistry, Howard University, 2400 Sixth Street, N.
b Department of Chemistry, Howard University, 2400 Sixth Street, N.W, Washington, DC 20059, USA)

Corresponding author: Deepanjali Pandey,
Received Date: 3 March 2014
Available Online: 12 March 2015

A new three-dimensional nickel (II) hydrogen-bonded molecular self assembly containing [(Ni(nicotinamide)₂(thiocyanate)₂(H₂O)₂] complex has been synthesized and characterized by single-crystal X-ray diffraction, FTIR spectroscopy, thermal analysis and magnetic measurements. Structural analysis reveals that the complex crystallizes in triclinic space group P1 (crystal data a=7.5574, b=8.2683, c=9.0056 Å, α=73.010, β=69.698, γ=66.51°) and exhibits a distorted octahedral coordination sphere. Most interesting point in its structure is the involvement of sulphur atom of thiocyanate moiety in the trifurcated hydrogen bonding to build up the hydrogen-bonded self assembly. The magnetic behavior as determined by squid magnetometer (2~300 K temp. range) reveals dominating antiferromagnetic interaction followed by spin canting behavior below 20 K.
- hydrogen bonded 3D structure,
- intermolecular magnetic interaction,
- spin canting
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