Citation: Yangping Zhang, Tianpeng Liu, Jun Yu, Zhengying Wu, Dongqiong Wang, Yukou Du. Amorphous/crystalline AgS@CoS core@shell catalysts for efficient oxygen evolution reaction[J]. Chinese Chemical Letters, ;2025, 36(8): 110275. doi: 10.1016/j.cclet.2024.110275 shu

Amorphous/crystalline AgS@CoS core@shell catalysts for efficient oxygen evolution reaction

Yangping Zhang ^a ,
Tianpeng Liu ^a ,
Jun Yu ^a ,
Zhengying Wu ^{b, *,} ,
Dongqiong Wang ^a ,
Yukou Du ^{a, c, *,}

a.
College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China
b.
Jiangsu Key Laboratory for Environment Functional Materials, School of Materials Science and Engineering, Suzhou University of Science and Technology, Suzhou 215009, China
c.
School of Optical and Electronic Information, Suzhou City University, Suzhou 215104, China

zywu@mail.usts.edu.cn

duyk@suda.edu.cn

Received Date: 24 June 2024
Revised Date: 11 July 2024
Accepted Date: 16 July 2024
Available Online: 20 July 2024

Figures(5)

The core@shell structure materials with the synergistic effect have been confirmed as promising catalysts for oxygen evolution reaction (OER). However, the conventional catalysts with crystalline phase suffer from deficient active sites, elemental dissolution, and structural collapse during OER catalysis, which results in the limited OER performance. Herein, we introduced the amorphous phase structure by controllable wet-chemical sulfuration strategy, thus to prepare the amorphous/crystalline (a/c) AgS@CoS core@shell catalysts. Benefitting from the core@shell construction with synergistic interaction, a/c heterophase with well-balanced catalytic activity and stability, favorable sulfides components with positive oxysulfide reconstructed layer formation, the optimized AgS@CoS-2 catalysts displayed superior OER catalytic behaviors with a low overpotential of 260 mV and Tafel slope of 64.4 mV/dec on the current density of 10 mA/cm², surpassing the counterpart catalysts and commercial RuO₂ catalysts. Meanwhile, the AgS@CoS-2 catalysts possessed remarkable OER catalytic stability, as well as the favorable overall water splitting performance.
- Hierarchical core@shell catalysts amorphous/crystalline,
- AgS@CoS,
- Oxygen revolution reaction,
- Overall water splitting
1. [1]
  M. Luo, Z. Zhao, Y. Zhang, et al., Nature 574 (2019) 81–85. doi: 10.1038/s41586-019-1603-7
2. [2]
  Y. Liu, E.H. Ang, X. Zhong, et al., J. Colloid Interface Sci. 652 (2023) 418–428.
3. [3]
  Y. Zhang, D. Wang, C. Ye, et al., Chem. Eng. J. 466 (2023) 143059.
4. [4]
  H. Zhu, R. Du, H. Zhao, et al., J. Mater. Chem. A 12 (2024) 8487–8501. doi: 10.1039/d3ta07853a
5. [5]
  Y. Wang, L. Yan, K. Dastafkan, et al., Adv. Mater. 34 (2022) 2006351.
6. [6]
  Y. Chen, P. Liao, K. Jin, et al., Inorg. Chem. Front. 10 (2023) 6489–6505. doi: 10.1039/d3qi01468a
7. [7]
  J. Yang, Y. Shen, Y. Sun, et al., Angew. Chem. Int. Ed. 62 (2023) 202302220.
8. [8]
  F. Gao, Y. Zhang, Z. Wu, H. You, Y. Du, Coord. Chem. Rev. 436 (2021) 214244.
9. [9]
  F. Gao, Y. Zhang, F. Ren, Y. Shiraishi, Y. Du, Adv. Funct. Mater. 30 (2020) 2000255.
10. [10]
  T. Hu, F. Zhu, J.J. Xia, et al., Adv. Funct. Mater. 33 (2023) 2305567.
11. [11]
  Y. Bai, C. Liu, Y. Shan, et al., Adv. Energy Mater. 12 (2021) 2100346.
12. [12]
  Y. Hao, Q. Liu, Y. Zhou, et al., Energy Environ. Mater. 2 (2019) 18–21. doi: 10.1002/eem2.12024
13. [13]
  R.A. Acedera, A.T. Dumlao, D.J.D. Matienzo, et al., J. Energy Chem. 89 (2024) 646–669.
14. [14]
  R. He, C. Wang, L. Feng, Chin. Chem. Lett. 34 (2022) 107241.
15. [15]
  Z. Chen, C. Lu, Y. Zhuo, et al., Scr. Mater. 235 (2023) 115626.
16. [16]
  M. Guo, R. Deng, C. Wang, Q. Zhang, J. Energy Chem. 78 (2023) 537–553.
17. [17]
  Y. Zhang, F. Gao, D. Wang, et al., Coord. Chem. Rev. 475 (2023) 214916.
18. [18]
  P. Ding, H.Q. Song, J.W. Chang, S.Y. Lu, Nano Res. 15 (2022) 7063–7070. doi: 10.1007/s12274-022-4377-4
19. [19]
  D.P. Sahoo, K.K. Das, S. Mansingh, S. Sultana, K. Parida, Coord. Chem. Rev. 469 (2022) 214666.
20. [20]
  J.N. Song, Y. Chen, H.J. Huang, et al., Adv. Sci. 9 (2022) 2104522.
21. [21]
  Q. Shi, H.A. Guo, D.L. Ou, et al., J. Energy Storage 72 (2023) 108073.
22. [22]
  H. Xu, X. Niu, Z. Liu, et al., Small 17 (2021) 2103064.
23. [23]
  M. Zhang, Y. Zhang, L. Ye, B. Guo, Y. Gong, Appl. Catal. B: Environ. 298 (2021) 120601.
24. [24]
  Y. Deng, H. Liu, X. Wei, et al., J. Colloid. Interface Sci. 585 (2021) 800–807.
25. [25]
  C. Lee, C. Lee, K. Shin, et al., Catal. Commun. 129 (2019) 105749.
26. [26]
  J. Liu, G. Qian, H. Zhang, et al., Chem. Eng. J. 426 (2021) 131253.
27. [27]
  H. Han, H. Choi, S. Mhin, et al., Energy Environ. Sci. 12 (2019) 2443–2454. doi: 10.1039/c9ee00950g
28. [28]
  Y. Zhang, F. Gao, H. You, et al., Coord. Chem. Rev. 450 (2022) 214244.
29. [29]
  M. Kuang, J. Zhang, D. Liu, et al., Adv. Energy Mater. 10 (2020) 2002215.
30. [30]
  Z. Xiong, B. Sun, H. Zou, et al., J. Am. Chem. Soc. 144 (2022) 6583–6593. doi: 10.1021/jacs.2c02089
31. [31]
  J. Bak, T.G. Yun, J.S. An, H.B. Bae, S.Y. Chung, Energy Environ. Sci. 15 (2022) 610–620. doi: 10.1039/d1ee01826d
32. [32]
  Z. Gu, X. Wei, X. Zhang, et al., Small 17 (2021) 2104125.
33. [33]
  Y. Lei, L. Zhang, W. Xu, et al., Nano Res. 15 (2022) 6054–6061. doi: 10.1007/s12274-022-4304-8
34. [34]
  X. Yu, W. Zhang, L. She, et al., Chem. Eng. J. 430 (2022) 133073.
35. [35]
  Z. Li, X. Zhang, Y. Kang, et al., Adv. Sci. 8 (2021) 2002631.
36. [36]
  Y.J. Jiang, T.Y. Chen, J.L. Chen, et al., Adv. Mater. 36 (2023) 2306910.
37. [37]
  W. Cheng, H. Zhang, D. Luan, X.W. Lou, Sci. Adv. 7 (2021) eabg2580.
38. [38]
  C. Qiu, F. Cai, Y. Wang, et al., J. Colloid Interface Sci. 565 (2020) 351–359.
39. [39]
  P. Geng, S. Cao, X. Guo, et al., J. Mater. Chem. A 7 (2019) 19465–19470. doi: 10.1039/c9ta05812e
40. [40]
  X. Liu, Y. Zhang, M. Li, X. Dong, B. Wang, J. Hazard Mater. 426 (2022) 128098.
41. [41]
  P.X. Zhang, S.L. Liu, J.J. Zhou, et al., Small 20 (2023) 2307662.
42. [42]
  M. Duan, S. Liu, Q. Jiang, et al., Chin. Chem. Lett. 33 (2022) 4428–4436.
43. [43]
  S.K. Li, H.R. Chai, L. Zhang, et al., J. Colloid Interface Sci. 642 (2023) 235–245.
44. [44]
  Y. Tian, X. Liu, L. Xu, et al., Adv. Funct. Mater. 31 (2021) 2101239.
45. [45]
  X. Guo, M. Duan, J. Zhang, et al., Adv. Funct. Mater. 32 (2022) 2209397.
46. [46]
  N. Guo, H. Xue, A. Bao, et al., Angew. Chem. Int. Ed. 59 (2020) 13778–13784. doi: 10.1002/anie.202002394
47. [47]
  Y. Hu, Y. Zheng, J. Jin, et al., Nat. Commun. 14 (2023) 1949.
48. [48]
  X. Liu, J. Meng, J. Zhu, et al., Adv. Mater. 33 (2021) 2007344.
49. [49]
  Y. Zhang, X. Zheng, X. Guo, et al., Appl. Catal. B: Environ. 336 (2023) 122891.
50. [50]
  G. Zhang, J. Zeng, J. Yin, et al., Appl. Catal B: Environ. 286 (2021) 119902.
51. [51]
  D. Yang, Z. Su, Y. Chen, et al., Chem. Eng. J. 430 (2022) 133046.
1. [1]
  Yuchen Guo , Xiangyu Zou , Xueling Wei , Weiwei Bao , Junjun Zhang , Jie Han , Feihong Jia . Fe regulating Ni3S2/ZrCoFe-LDH@NF heterojunction catalysts for overall water splitting. Chinese Journal of Structural Chemistry, 2024, 43(2): 100206-100206. doi: 10.1016/j.cjsc.2023.100206
2. [2]
  Anna Dai , Zhenxiong Huang , Li Tian , Zheng Zhang , Xiangjiu Guan , Liejin Guo . Polymeric Carbon Nitride for Photocatalytic Overall Water Splitting: Modification Strategies and Recent Advances. Chinese Journal of Structural Chemistry, 2025, 44(8): 100630-100630. doi: 10.1016/j.cjsc.2025.100630
3. [3]
  Jun Yu , Yangping Zhang , Nannan Zhang , Jie Li , Huiyu Sun , Xinyu Gu , Changqing Ye , Tianpeng Liu , Yukou Du . The interface engineering strategy assists the 3D core-shell structure Co₃S₄/CuS@NiFe LDH nanocoral spheres to achieve significant overall water splitting. Chinese Chemical Letters, 2026, 37(2): 110830-. doi: 10.1016/j.cclet.2025.110830
4. [4]
  Weilong Liu , Jipeng Dong , Luyao Zhang , Ning Li , Yangqin Gao , Lei Ge . Dynamic tuning of d-p orbital hybridization during sulfur vacancy evolution in Co9S8 toward efficient overall water splitting. Chinese Journal of Structural Chemistry, 2025, 44(9): 100661-100661. doi: 10.1016/j.cjsc.2025.100661
5. [5]
  Sumiya Akter Dristy , Md Ahasan Habib , Mehedi Hasan Joni , Md Najibullah , Rutuja Mandavkar , Shusen Lin , Jihoon Lee . Binder-free bimetallic vanadium-nickel-boride-phosphide spherical structure for highly efficient and stable industrial-level water splitting. Chinese Journal of Structural Chemistry, 2025, 44(12): 100747-100747. doi: 10.1016/j.cjsc.2025.100747
6. [6]
  Ji Chen , Yifan Zhao , Shuwen Zhao , Hua Zhang , Youyu Long , Lingfeng Yang , Min Xi , Zitao Ni , Yao Zhou , Anran Chen . Heterogeneous bimetallic oxides/phosphides nanorod with upshifted d band center for efficient overall water splitting. Chinese Chemical Letters, 2024, 35(9): 109268-. doi: 10.1016/j.cclet.2023.109268
7. [7]
  Liang Dong , Jingkuo Qu , Tuo Zhang , Guanghui Zhu , Ningning Ma , Chang Zhao , Yi Yuan , Xiangjiu Guan , Liejin Guo . MOF-derived NiCo bimetallic cocatalyst for enhanced photocatalytic overall water splitting. Chinese Chemical Letters, 2025, 36(3): 110397-. doi: 10.1016/j.cclet.2024.110397
8. [8]
  Xu Huang , Kai-Yin Wu , Chao Su , Lei Yang , Bei-Bei Xiao . Metal-organic framework Cu-BTC for overall water splitting: A density functional theory study. Chinese Chemical Letters, 2025, 36(4): 109720-. doi: 10.1016/j.cclet.2024.109720
9. [9]
  Li Tian , Xiangjiu Guan , Jingkuo Qu , Anna Dai , Jiaye Cai , Zheng Zhang , Shichao Zong , Liejin Guo . Boosting photocatalytic overall water splitting efficiency and stability with adjacent cobalt-based dual cocatalysts. Chinese Chemical Letters, 2026, 37(4): 111581-. doi: 10.1016/j.cclet.2025.111581
10. [10]
  Gen Zhang , Ying Gu , Lin Li , Fuli Ma , Dan Yue , Xiaoguang Zhou , Chungui Tian . Anion-modulated HER and OER activity of 1D Co-Mo based interstitial compound heterojunctions for the effective overall water splitting. Chinese Chemical Letters, 2025, 36(7): 110110-. doi: 10.1016/j.cclet.2024.110110
11. [11]
  Jing Cao , Dezheng Zhang , Bianqing Ren , Ping Song , Weilin Xu . Mn incorporated RuO₂ nanocrystals as an efficient and stable bifunctional electrocatalyst for oxygen evolution reaction and hydrogen evolution reaction in acid and alkaline. Chinese Chemical Letters, 2024, 35(10): 109863-. doi: 10.1016/j.cclet.2024.109863
12. [12]
  Xiaxi Yao , Xiuli Hu , Fangcheng Huang , Xuhong Wang , Xuekun Hong , Dawei Wang . Improved hydrogen and oxygen evolution rates in Pt@TiO₂@RuO₂ hollow nanoshells through dielectric Mie resonance and spatial cocatalyst separation. Chinese Chemical Letters, 2025, 36(5): 110192-. doi: 10.1016/j.cclet.2024.110192
13. [13]
  Zuyou Song , Yong Jiang , Qiao Gou , Yini Mao , Yimin Jiang , Wei Shen , Ming Li , Rongxing He . Promoting the generation of active sites through "Co-O-Ru" electron transport bridges for efficient water splitting. Chinese Chemical Letters, 2025, 36(4): 109793-. doi: 10.1016/j.cclet.2024.109793
14. [14]
  Rui Deng , Wenjie Jiang , Tianqi Yu , Jiali Lu , Boyao Feng , Panagiotis Tsiakaras , Shibin Yin . Cycad-leaf-like crystalline-amorphous heterostructures for efficient urea oxidation-assisted water splitting. Chinese Journal of Structural Chemistry, 2024, 43(7): 100290-100290. doi: 10.1016/j.cjsc.2024.100290
15. [15]
  Jiawei Ge , Xian Wang , Heyuan Tian , Hao Wan , Wei Ma , Jiangying Qu , Junjie Ge . Iridium-based catalysts for oxygen evolution reaction in proton exchange membrane water electrolysis. Chinese Chemical Letters, 2025, 36(5): 109906-. doi: 10.1016/j.cclet.2024.109906
16. [16]
  Shudi Yu , Jie Li , Jiongting Yin , Wanyu Liang , Yangping Zhang , Tianpeng Liu , Mengyun Hu , Yong Wang , Zhengying Wu , Yuefan Zhang , Yukou Du . Built-in electric field and core-shell structure of the reconstructed sulfide heterojunction accelerated water splitting. Chinese Chemical Letters, 2024, 35(12): 110068-. doi: 10.1016/j.cclet.2024.110068
17. [17]
  Min Song , Qian Zhang , Tao Shen , Guanyu Luo , Deli Wang . Surface reconstruction enabled o-PdTe@Pd core-shell electrocatalyst for efficient oxygen reduction reaction. Chinese Chemical Letters, 2024, 35(8): 109083-. doi: 10.1016/j.cclet.2023.109083
18. [18]
  Tianli Hui , Tao Zheng , Xiaoluo Cheng , Tonghui Li , Rui Zhang , Xianghai Meng , Haiyan Liu , Zhichang Liu , Chunming Xu . A review of plasma treatment on nano-microstructure of electrochemical water splitting catalysts. Chinese Journal of Structural Chemistry, 2025, 44(3): 100520-100520. doi: 10.1016/j.cjsc.2025.100520
19. [19]
  Lu Qi , Zhaoyang Chen , Xiaoyu Luan , Zhiqiang Zheng , Yurui Xue , Yuliang Li . Atomically dispersed Mn enhanced catalytic performance for overall water splitting on graphdiyne-coated copper hydroxide nanowire. Chinese Journal of Structural Chemistry, 2024, 43(1): 100197-100197. doi: 10.1016/j.cjsc.2023.100197
20. [20]
  Qing Li , Bing Wang , Qi Xu , Ruiyou Liu , Chen Li , Fang Luo , Yifei Li , Yingjie Yu , Zehui Yang . Pt dopants in ruthenium/iridium oxides promote catalytic activity in overall acidic water splitting. Chinese Chemical Letters, 2025, 36(12): 111658-. doi: 10.1016/j.cclet.2025.111658

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(1060)
HTML views(53)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142