Citation: Xing Gao, Luofeng Wang, Jia Cheng, Jialiang Zhao, Xueli Liu. Manufacturing process of MOF-based separator for lithium sulfur batteries: A mini review[J]. Chinese Chemical Letters, ;2025, 36(8): 110247. doi: 10.1016/j.cclet.2024.110247 shu

Manufacturing process of MOF-based separator for lithium sulfur batteries: A mini review

School of Material and Chemical Engineering, Chuzhou University, Chuzhou 239000, China

gaoxinggxone@163.com

n_xueli@163.com

Received Date: 15 May 2024
Revised Date: 29 June 2024
Accepted Date: 12 July 2024
Available Online: 14 July 2024

Figures(10)

Metal organic frameworks (MOFs) are crystalline materials with three-dimensional porous network structure. They are obtained by self-assembly of coordinate bond with metal ions as the nodes and organic ligands as the connecting chains. MOFs have attracted extensive attention from researchers over the years due to their clear pore and rich topological structure. As the typical powder materials, a specific separator manufacturing process must be possessed when incorporating MOFs into lithium sulfur batteries separator. This mini review summarized the manufacturing process of MOFs separator for LSBs in recent years, and summed up the effects and mechanisms of separators prepared by various separator-forming processes on the performance of LSBs, the potential for industrialization of different separator manufacturing processes is also mentioned briefly.
- Metal-organic frameworks,
- Lithium sulfur batteries,
- Shuttling effect,
- Separator,
- Manufacturing process
1. [1]
  R. Deng, M. Wang, H. Yu, et al., Energy Environ. Mater. 5 (2022) 777–799. doi: 10.1002/eem2.12257
2. [2]
  M. Zhao, B.Q. Li, X.Q. Zhang, et al., ACS Cent. Sci. 6 (2020) 1095–1104. doi: 10.1021/acscentsci.0c00449
3. [3]
  Y. Li, S. Guo, Matter 4 (2021) 1142–1188.
4. [4]
  J. Zhao, Y. Qi, Q. Yang, et al., Chem. Eng. J. 429 (2022) 131997.
5. [5]
  R. Zou, W. Liu, F. Ran, InfoMat 4 (2022) 12319.
6. [6]
  Y.W. Tian, Y.J. Zhang, L. Wu, et al., ACS Appl. Mater. Interfaces 15 (2023) 6877–6887. doi: 10.1021/acsami.2c20461
7. [7]
  J.G. Kim, Y. Noh, Y. Kim, Chem. Eng. J. 435 (2022) 131339.
8. [8]
  Z.W. Seh, Y. Sun, Q. Zhang, et al., Chem. Soc. Rev. 45 (2016) 5605–5634.
9. [9]
  F. Pei, S. Dai, B. Guo, et al., Energy Environ. Sci. 14 (2021) 975–985. doi: 10.1039/d0ee03005h
10. [10]
  Q. Shao, S. Zhu, J. Chen, Nano Res. 16 (2023) 8097–8138. doi: 10.1007/s12274-022-5227-0
11. [11]
  S. Li, H. Dai, Y. Li, et al., Energy Storage Mater. 18 (2019) 222–228.
12. [12]
  Z. Li, J. Wu, P. Chen, et al., Chem. Eng. J. 435 (2022) 135125.
13. [13]
  C. Shi, M. Yu, Energy Storage Mater. 57 (2023) 429–459.
14. [14]
  Y. Zhang, C. Guo, J. Zhou, et al., Small 19 (2023) e2206616.
15. [15]
  Z. Han, S. Li, M. Sun, et al., J. Energy Chem. 68 (2022) 752–761. doi: 10.3390/su14020752
16. [16]
  H. Sul, A. Bhargav, A. Manthiram, Adv. Energy Mater. 12 (2022) 2200680.
17. [17]
  X. Zhang, W. Yuan, H. Huang, et al., Inter. J. Extreme Manufac. 5 (2022) 015501.
18. [18]
  Y. Zhang, C. Guo, L. Zhou, et al., Small Sci. 3 (2023) 2300056.
19. [19]
  S. Foley, H. Geaney, G. Bree, et al., Adv. Funct. Mater. 28 (2018) 1800587.
20. [20]
  P. Marino, P.R. Donnarumma, H.A. Bicalho, et al., ACS Sustain. Chem. Eng. 9 (2021) 16356–16362. doi: 10.1021/acssuschemeng.1c06032
21. [21]
  C.W. Ashling, D.N. Johnstone, R.N. Widmer, et al., J. Am. Chem. Soc. 141 (2019) 15641–15648. doi: 10.1021/jacs.9b07557
22. [22]
  D. Sun, M. Xu, Y. Jiang, et al., Small Methods 2 (2018) 1800164.
23. [23]
  S. Hou, W. Ding, S. Liu, et al., Chem. Eng. J. 460 (2023) 141785.
24. [24]
  S. Xie, F. Li, S. Xu, et al., Chin. J. Catal. 40 (2019) 1205–1211.
25. [25]
  K. Ge, S. Sun, Y. Zhao, et al., Angew. Chem. Int. Ed. 60 (2021) 12097–12102. doi: 10.1002/anie.202102632
26. [26]
  Z. Zhao, H. Li, K. Zhao, et al., Chem. Eng. J. 428 (2022) 131006.
27. [27]
  W. Li, Y. Zhang, Z. Yu, et al., ACS Nano 16 (2022) 14779–14791. doi: 10.1021/acsnano.2c05624
28. [28]
  Y. Jeon, J. Lee, H. Jo, et al., Chem. Eng. J. 407 (2021) 126967.
29. [29]
  S. Qiu, J. Zhang, X. Liang, et al., Chem. Eng. J. 450 (2022) 138287.
30. [30]
  F. Wu, S. Zhao, L. Chen, et al., Energy Storage Mater. 14 (2018) 383–391.
31. [31]
  C. Qi, L. Xu, J. Wang, et al., ACS Sustain. Chem. Eng. 8 (2020) 12968–12975. doi: 10.1021/acssuschemeng.0c03536
32. [32]
  S. Suriyakumar, M. Kanagaraj, M. Kathiresan, et al., Electro. Acta 265 (2018) 151–159.
33. [33]
  X.J. Hong, C.L. Song, Y. Yang, et al., ACS Nano 13 (2019) 1923–1931.
34. [34]
  X. Leng, J. Zeng, M. Yang, et al., J. Energy Chem. 82 (2023) 484–496.
35. [35]
  H.G. Jin, M. Wang, J.X. Wen, et al., ACS Appl. Mater. Interfaces 13 (2021) 3899–3910. doi: 10.1021/acsami.0c18899
36. [36]
  Z. Chang, Y. Qiao, J. Wang, et al., Energy Storage Mater. 25 (2020) 164–171.
37. [37]
  Z. Wang, W. Huang, J. Hua, et al., Small Methods 4 (2020) 2000082.
38. [38]
  S. Bai, K. Zhu, S. Wu, et al., J. Mater. Chem. A 4 (2016) 16812–16817.
39. [39]
  Y. He, Z. Chang, S. Wu, et al., Adv. Energy Mater. 8 (2018) 1802130.
40. [40]
  Y. Chen, L. Zhang, H. Pan, et al., J. Mater. Chem. A 9 (2021) 26929–26938. doi: 10.1039/d1ta07820h
41. [41]
  H. Chen, Y. Xiao, C. Chen, et al., ACS Appl. Mater. Interfaces 11 (2019) 11459–11465. doi: 10.1021/acsami.8b22564
42. [42]
  S.H. Kim, J.S. Yeon, R. Kim, et al., J. Mater. Chem. A 6 (2018) 24971–24978. doi: 10.1039/c8ta08843h
43. [43]
  Y. Li, S. Lin, D. Wang, et al., Adv. Mater. 32 (2020) 1906722.
44. [44]
  M. Li, Y. Wan, J.K. Huang, et al., ACS Energy Lett. 2 (2017) 2362–2367. doi: 10.1021/acsenergylett.7b00692
45. [45]
  M. Tian, F. Pei, M. Yao, et al., Energy Storage Mater. 21 (2019) 14–21.
46. [46]
  S. Bai, X. Liu, K. Zhu, et al., Nat. Energy 1 (2016) 16010.
47. [47]
  C. Zhou, Q. He, Z. Li, et al., Chem. Eng. J. 395 (2020) 124979.
48. [48]
  J. Liu, J. Wang, L. Zhu, et al., Chem. Eng. J. 411 (2021) 128540.
49. [49]
  J. Liu, J. Wang, L. Zhu, et al., J. Mater. Chem. A 10 (2022) 14098–14110. doi: 10.1039/d2ta03301a
50. [50]
  Y. Zang, F. Pei, J. Huang, et al., Adv. Energy Mater. 8 (2018) 1802052.
51. [51]
  Y. Guo, M. Sun, H. Liang, et al., ACS Appl. Mater. Interfaces 10 (2018) 30451–30459. doi: 10.1021/acsami.8b11042
52. [52]
  G. Gao, Y. Wang, H. Zhu, et al., Adv. Sci. 7 (2020) 2002190.
53. [53]
  Y. Feng, G. Wang, W. Kang, et al., Electro. Acta 365 (2021) 137344.
54. [54]
  N. Deng, L. Wang, Y. Feng, et al., Chem. Eng. J. 388 (2020) 124241.
55. [55]
  H. Wu, Y. Yang, W. Jia, et al., J. Alloy. Compd. 874 (2021) 159917.
56. [56]
  G.K. Gao, Y.R. Wang, S.B. Wang, et al., Angew. Chem. Int. Ed. 60 (2021) 10147–10154. doi: 10.1002/anie.202016608
1. [1]
  Ze Liu , Xiaochen Zhang , Jinlong Luo , Yingjian Yu . Application of metal-organic frameworks to the anode interface in metal batteries. Chinese Chemical Letters, 2024, 35(11): 109500-. doi: 10.1016/j.cclet.2024.109500
2. [2]
  Qingyun Yang , Yue Ma , Quanyi Ye , Yiqing Liu , Yuhong Luo , Yongbo Wu , Zhiguang Xu , Xiaoming Lin . Prussian blue analogues derived MO/MFe2O4 (M = Ni, Cu, Zn) nanoparticles as a high-performance anode material for enhanced lithium storage. Chinese Journal of Structural Chemistry, 2025, 44(8): 100631-100631. doi: 10.1016/j.cjsc.2025.100631
3. [3]
  Pengfu Gao , Yuan Geng , Wei Gong . Homochiral metal-organic frameworks bearing privileged ligands for heterogeneous asymmetric catalysis. Chinese Journal of Structural Chemistry, 2025, 44(10): 100719-100719. doi: 10.1016/j.cjsc.2025.100719
4. [4]
  Chao Jia , Min Ren , Yingdi Jin , Xingxing Li . Hydrogen migration induced magnetic phase transitions in two-dimensional Fe-porphyrinoid metal-organic frameworks. Chinese Journal of Structural Chemistry, 2026, 45(2): 100801-100801. doi: 10.1016/j.cjsc.2025.100801
5. [5]
  Chengye Lou , Yu Hu , Yunjia Jiang , Lingyao Wang , Yuanbin Zhang . Borane cage hybrid supramolecular metal-organic frameworks (BSFs): Design, synthesis and gas separation performance. Chinese Journal of Structural Chemistry, 2026, 45(2): 100789-100789. doi: 10.1016/j.cjsc.2025.100789
6. [6]
  Yuhao Xiong , Jian Zhang , Yue Sun , Boyuan Hu , Wei Wang , Yuanyuan Yin , Debin Xia , Kaifeng Lin , Yulin Yang , Evgeny Tretyakov . Metal-organic frameworks in perovskite solar cells: Harnessing structural diversity for enhanced photovoltaic performance. Chinese Journal of Structural Chemistry, 2026, 45(3): 100842-100842. doi: 10.1016/j.cjsc.2025.100842
7. [7]
  Jun-Xian Chen , Xian-Xian Xiao , Libo Li , Jinping Li , Rui-Biao Lin , Xiao-Ming Chen . Fine-tuning of Hofmann-type metal-organic frameworks for highly efficient separation of C4 olefins. Chinese Journal of Structural Chemistry, 2025, 44(12): 100744-100744. doi: 10.1016/j.cjsc.2025.100744
8. [8]
  Feng Cao , Chunxiang Xian , Tianqi Yang , Yue Zhang , Haifeng Chen , Xinping He , Xukun Qian , Shenghui Shen , Yang Xia , Wenkui Zhang , Xinhui Xia . Gelation-pyrolysis strategy for fabrication of advanced carbon/sulfur cathodes for lithium-sulfur batteries. Chinese Chemical Letters, 2025, 36(3): 110575-. doi: 10.1016/j.cclet.2024.110575
9. [9]
  Ruofan Qi , Jing Zhang , Wang Sun , Bai Yu , Zhenhua Wang , Kening Sun . Solid-acid-Lewis-base interaction accelerates lithium ion transport for uniform lithium deposition. Chinese Chemical Letters, 2025, 36(6): 110009-. doi: 10.1016/j.cclet.2024.110009
10. [10]
  Muhammad Riaz , Rakesh Kumar Gupta , Di Sun , Mohammad Azam , Ping Cui . Selective adsorption of organic dyes and iodine by a two-dimensional cobalt(II) metal-organic framework. Chinese Journal of Structural Chemistry, 2024, 43(12): 100427-100427. doi: 10.1016/j.cjsc.2024.100427
11. [11]
  Tengjia Ni , Xianbiao Hou , Huanlei Wang , Lei Chu , Shuixing Dai , Minghua Huang . Controllable defect engineering based on cobalt metal-organic framework for boosting oxygen evolution reaction. Chinese Journal of Structural Chemistry, 2024, 43(1): 100210-100210. doi: 10.1016/j.cjsc.2023.100210
12. [12]
  Sihong Li , Weiping Deng , Qijie Mo , Haili Song , Chunying Chen , Li Zhang . Engineering S-coordinated Ru single-atoms in a porphyrinic metal-organic framework for CO2 photoreduction. Chinese Journal of Structural Chemistry, 2026, 45(3): 100841-100841. doi: 10.1016/j.cjsc.2025.100841
13. [13]
  Zhiqi Hu , Lingling Wu , Duo Zhang , Yixue An , Jiao Wang , Binbin Zhao , Robert Chunhua Zhao , Rong Cao , Xue Yang . Ultrathin transparent metal-organic framework-based nanocomposite membranes for antibacterial wound healing. Chinese Journal of Structural Chemistry, 2025, 44(12): 100749-100749. doi: 10.1016/j.cjsc.2025.100749
14. [14]
  Mengjin Li , Tian Xia , Mengyu Wang , Yujie Peng , Sihan Zhang , Xueliang Jiang , Huan Yang . Biocarbon-Confined Bimetallic FeCo Metal-Organic Framework Orthogonal Nanosheet Arrays for Industry-level Ethylene Glycol Oxidation. Chinese Journal of Structural Chemistry, 2025, 44(8): 100627-100627. doi: 10.1016/j.cjsc.2025.100627
15. [15]
  Xi Feng , Ding-Yi Hu , Zi-Jun Liang , Mu-Yang Zhou , Zhi-Shuo Wang , Wen-Yu Su , Rui-Biao Lin , Dong-Dong Zhou , Jie-Peng Zhang . A metal azolate framework with small aperture for highly efficient ternary benzene/cyclohexene/cyclohexane separation. Chinese Journal of Structural Chemistry, 2025, 44(3): 100540-100540. doi: 10.1016/j.cjsc.2025.100540
16. [16]
  Xiao-Hong Yi , Hong-Yu Chu , Chao-Yang Wang , Hang Ren , Li-hong Zhou , Yujie Zhao , Fu-Xue Wang , Hao Du , Yixuan Zhai , Tao Xia , Shaohua Guo , Xiaoning Wang , Yunlong Wang , Qian Wen , Ge Shen , Meng Yang , Yu-Hang Li , Mingjia Xu , Xiaoyuan Zhang , Hao Wang , Xudong Zhao , Yifei Sun , Yi-Lin Liu , Qingyi Zeng , Yuying Deng , Qi Wang , Xiaodong Zhang , Jie Li , Ning Liu , Chuanxi Yang , Jiansheng Li , Anping Wang , Xun Wang , Xuchun Qiu , Haodong Ji , Xuedong Du , Jiaxing Wu , Chong-Chen Wang . Metal-organic frameworks for clean water. Chinese Chemical Letters, 2026, 37(3): 112243-. doi: 10.1016/j.cclet.2025.112243
17. [17]
  Jiayu Huang , Kuan Chang , Qi Liu , Yameng Xie , Zhijia Song , Zhiping Zheng , Qin Kuang . Fe-N-C nanostick derived from 1D Fe-ZIFs for Electrocatalytic oxygen reduction. Chinese Journal of Structural Chemistry, 2023, 42(10): 100097-100097. doi: 10.1016/j.cjsc.2023.100097
18. [18]
  Chao Wei , Zi-Yi Zhao , Jing-Jing Li , Jinli Zhang , Ming Lu , Xiao-Qin Liu , Guoliang Liu , Jiandong Pang , Lin-Bing Sun . Topology guided construction of MOF by linking Zr-MOLs with perylene diimide motifs for photocatalytic oxidation. Chinese Journal of Structural Chemistry, 2025, 44(8): 100625-100625. doi: 10.1016/j.cjsc.2025.100625
19. [19]
  Yun Zhou , Geqian Fang , Haiyan Wang , Wenjun Yu , Chun Zhu , Jin-Xia Liang , Jian Lin . Non-covalent interactions between adsorbed •OH species and UiO-66-NH2 for methane hydroxylation. Chinese Journal of Structural Chemistry, 2025, 44(8): 100629-100629. doi: 10.1016/j.cjsc.2025.100629
20. [20]
  Longlong Geng , Huiling Liu , Wenfeng Zhou , Yong-Zheng Zhang , Hongliang Huang , Da-Shuai Zhang , Hui Hu , Chao Lv , Xiuling Zhang , Suijun Liu . Construction of metal-organic frameworks with unsaturated Cu sites for efficient and fast reduction of nitroaromatics: A combined experimental and theoretical study. Chinese Chemical Letters, 2024, 35(8): 109120-. doi: 10.1016/j.cclet.2023.109120

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1189)
HTML views(57)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142