Citation: Yaru Geng, Ruiqing Li, Tingting Zhu, Xinling Li, Qianwen Guan, Huang Ye, Peng Wang, Junlin Li, Junhua Luo. Formamidine intercalation to broaden photoresponsive range in alternating-cations-interlayered hybrid perovskite[J]. Chinese Chemical Letters, ;2025, 36(8): 110216. doi: 10.1016/j.cclet.2024.110216 shu

Formamidine intercalation to broaden photoresponsive range in alternating-cations-interlayered hybrid perovskite

Yaru Geng ^{a, b} ,
Ruiqing Li ^a ,
Tingting Zhu ^a ,
Xinling Li ^a ,
Qianwen Guan ^a ,
Huang Ye ^a ,
Peng Wang ^a ,
Junlin Li ^{a, b} ,
Junhua Luo ^{a, b, *,}

a.
State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
b.
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350002, China

jhluo@fjirsm.ac.cn

Received Date: 28 April 2024
Revised Date: 17 June 2024
Accepted Date: 4 July 2024
Available Online: 5 July 2024

Figures(4)

Two-dimensional (2D) organic-inorganic hybrid perovskites (OIHPs) have been developed as promising candidates for photodetection, owing to their excellent semiconducting features and structural tunability. However, as an important parameter for photodetection, the photoresponsive range of 2D OIHPs is usually modulated by finite metal-halide combinations, constraining their further development. The emerging aromatic amine-based alternating-cations-interlayered (A-ACI) hybrid perovskites that exhibit excellent charge transport and additional interlayered structural designability, provide an extra solution for achieving ideal photoresponsive range. Herein, for the first time, the photoresponsive range is successfully broadened in A-ACI hybrid perovskites (NMA)₄(FA)₂Pb₃Br₁₂ (2) remolding from (NMA)₄(MA)₂Pb₃Br₁₂ (1) (NMA = N-methylbenzylaminium, FA = formamidinium and MA = methylammonium). Particularly, 1 and 2 adopt an unprecedented configuration that NMA and MA/FA are alternately arranged in the interlayer in a 4:2 manner. Importantly, 2 exhibits a narrower bandgap than 1, which can be ascribed to the low-lying conduct band composed of intercalation FA π^* orbitals. Meanwhile, 2 possesses a shorter interlayer distance and flatter inorganic skeleton, synergistically facilitating the wider photo-absorption range and further endowing a broadening photoresponsive range (70 nm). This research not only enriches the perovskite family but also provides insights into structure-property relationships.
- Hybrid perovskites,
- Alternating-cations-interlayered,
- Formamidine intercalation,
- Broadening photoresponsive range,
- Photodetection
1. [1]
  M. Ren, S. Cao, J. Zhao, et al., Nano-Micro Lett. 13 (2021) 163.
2. [2]
  Y. Wang, D. Yan, L. Wang, Tang, et al., Adv. Sci. 8 (2021) 2100811.
3. [3]
  L. Zhang, C. Sun, T. He, et al., Light Sci. Appl. 10 (2021) 61.
4. [4]
  J. Sala, M. Heydarian, S. Lammar, et al., ACS Appl. Energy Mater. 4 (2021) 6377–6384. doi: 10.1021/acsaem.1c00810
5. [5]
  R. Prasanna, A. Gold-Parker, T. Leijtens, et al., J. Am. Chem. Soc. 139 (2017) 11117–11124. doi: 10.1021/jacs.7b04981
6. [6]
  H. Gao, J. Feng, Y. Pi, et al., Adv. Funct. Mater. 28 (2018) 1804349.
7. [7]
  Z. Xiao, Y. Zhou, H. Hosono, et al., Chem. Eur. J. 24 (2018) 2305–2316. doi: 10.1002/chem.201705031
8. [8]
  A.K. Jena, A. Kulkarni, T. Miyasaka, Chem. Rev. 119 (2019) 3036–3103. doi: 10.1021/acs.chemrev.8b00539
9. [9]
  L. Ma, J. Dai, X.C. Zeng, Adv. Energy Mater. 7 (2017) 1601731.
10. [10]
  L. Mao, H. Tsai, W. Nie, et al., Chem. Mater. 28 (2016) 7781–7792. doi: 10.1021/acs.chemmater.6b03054
11. [11]
  X. Li, Y. Guan, X. Li, Y. Fu, J. Am. Chem. Soc. 144 (2022) 18030–18042. doi: 10.1021/jacs.2c07535
12. [12]
  D. Ma, Y. Fu, L. Dang, et al., Nano Res. 10 (2017) 2117–2129. doi: 10.1007/s12274-016-1401-6
13. [13]
  K. Du, Q. Tu, X. Zhang, et al., Inorg. Chem. 56 (2017) 9291–9302. doi: 10.1021/acs.inorgchem.7b01094
14. [14]
  H.Y. Ye, W.Q. Liao, C.L. Hu, et al., Adv. Mater. 28 (2016) 2579–2586. doi: 10.1002/adma.201505224
15. [15]
  J. Wu, S. You, P. Yu, et al., ACS Energy Lett. 8 (2023) 2809–2816. doi: 10.1021/acsenergylett.3c00629
16. [16]
  J.C. Blancon, H. Tsai, W. Nie, et al., Science 355 (2017) 1288–1292. doi: 10.1126/science.aal4211
17. [17]
  D. Fu, Z. Hou, Y. He, et al., ACS Appl. Mater. Interfaces 14 (2022) 11690–11698. doi: 10.1021/acsami.2c00806
18. [18]
  O. Nazarenko, M.R. Kotyrba, M. Wörle, et al., Inorg. Chem. 56 (2017) 11552–11564. doi: 10.1021/acs.inorgchem.7b01204
19. [19]
  C.M.M. Soe, C.C. Stoumpos, M. Kepenekian, et al., J. Am. Chem. Soc. 139 (2017) 16297–16309. doi: 10.1021/jacs.7b09096
20. [20]
  T. Zhu, H. Wu, C. Ji, et al., Adv. Opt. Mater. 10 (2022) 2200146.
21. [21]
  Y.Y. Guo, L.J. Yang, S. Biberger, et al., Inorg. Chem. 59 (2020) 12858–12866. doi: 10.1021/acs.inorgchem.0c01807
22. [22]
  C. Ma, D. Shen, T.W. Ng, et al., Adv. Mater. 30 (2018) 1800710.
23. [23]
  T. Zhu, W. Weng, C. Ji, et al., J. Am. Chem. Soc. 144 (2022) 18062–18068. doi: 10.1021/jacs.2c07891
24. [24]
  H. Dai, S. You, H. Ye, et al., Small 19 (2023) 2304332.
25. [25]
  W. Wu, X. Shang, Z. Xu, et al., Adv. Sci. 10 (2023) 2206070.
26. [26]
  G. Kieslich, S. Sun, A.K. Cheetham, Chem. Sci. 5 (2014) 4712–4715.
27. [27]
  M.K. Jana, R. Song, Y. Xie, et al., Nat. Commun. 12 (2021) 4982.
28. [28]
  Z. Xiao, W. Meng, J. Wang, et al., Mater. Horiz. 4 (2017) 206–216.
29. [29]
  S.A. Fateev, A.A. Petrov, E.I. Marchenko, et al., Chem. Mater. 33 (2021) 1900–1907. doi: 10.1021/acs.chemmater.1c00382
30. [30]
  M. Li, Y. Xu, S. Han, et al., Adv. Mater. 32 (2020) 2002972.
31. [31]
  Y. Liu, J. Wang, S. Han, et al., Chem. Eur. J. 26 (2020) 3494–3498. doi: 10.1002/chem.201905531
32. [32]
  X. Li, D. Li, Y. Peng, et al., J. Mater. Chem. C 9 (2021) 9499–9504. doi: 10.1039/d1tc01291f
33. [33]
  B. Wang, H. Chen, W. Guo, et al., J. Mater. Chem. C 9 (2021) 17349–17356. doi: 10.1039/d1tc05064h
1. [1]
  Hao-Fei Ni , Jia-He Lin , Gele Teri , Qiang-Qiang Jia , Pei-Zhi Huang , Hai-Feng Lu , Chang-Feng Wang , Zhi-Xu Zhang , Da-Wei Fu , Yi Zhang . B-site ion regulation strategy enables performance optimization and multifunctional integration of hybrid perovskite ferroelectrics. Chinese Chemical Letters, 2025, 36(3): 109690-. doi: 10.1016/j.cclet.2024.109690
2. [2]
  Dongying Fu , Lin Pan , Yanli Ma , Yue Zhang . Bilayered Dion–Jacobson lead-iodine hybrid perovskite with aromatic spacer for broadband photodetection. Chinese Chemical Letters, 2025, 36(2): 109621-. doi: 10.1016/j.cclet.2024.109621
3. [3]
  Yan Cheng , Hai-Quan Yao , Ya-Di Zhang , Chao Shi , Heng-Yun Ye , Na Wang . Nitrate-bridged hybrid organic-inorganic perovskites. Chinese Journal of Structural Chemistry, 2024, 43(9): 100358-100358. doi: 10.1016/j.cjsc.2024.100358
4. [4]
  Zixuan Chen , Yafeng Wu , Zhaoyan Tian , Zhaohan Wang , Weiwei Liu , Songqin Liu . A reproducible hybrid membrane for in situ analysis of cell secretions with a wide size range. Chinese Chemical Letters, 2025, 36(12): 110917-. doi: 10.1016/j.cclet.2025.110917
5. [5]
  Weihong Ding , Kaiyue Song , Xianglong Li , Xiaoxia Sun . High-temperature-stable RRAMs with well-defined thermal effect mechanisms enable by engineering of robust 2D <100>-oriented organic-inorganic hybrid perovskites. Chinese Chemical Letters, 2025, 36(4): 110495-. doi: 10.1016/j.cclet.2024.110495
6. [6]
  Changsheng Yang , Yuhang Jiang , Panpan Yu , Shiguo Han , Shihai You , Zeng-Kui Zhu , Zihao Yu , Junhua Luo . Realizing self-powered broadband photodetection with low detection limit in a trilayered perovskite ferroelectric. Chinese Chemical Letters, 2025, 36(8): 110218-. doi: 10.1016/j.cclet.2024.110218
7. [7]
  Xian-Mei Zhao , Li-Wei Tang , Yi Liu , Yu Ma , Tian Yang , Hao Rong , Lin-Jie Wei , Jun-Hua Luo , Zhi-Hua Sun . Enhancing interlayer hydrogen bonds of 2D Ruddlesden-Popper perovskite toward stable polarization-sensitive photodetection. Chinese Chemical Letters, 2025, 36(7): 110092-. doi: 10.1016/j.cclet.2024.110092
8. [8]
  Qianxi Wang , Xiaoqi Li , Fen Zhang , Qingyin Wei , Zengshan Yue , Xiantan Lin , Yicong Lv , Xitao Liu , Junhua Luo . Mixed cation ordering scaffold polar 2D halide perovskite semiconductor for self-powered polarization-sensitive photodetection. Chinese Chemical Letters, 2025, 36(10): 110405-. doi: 10.1016/j.cclet.2024.110405
9. [9]
  Shilong Li , Ming Zhao , Yefei Xu , Zhanyi Liu , Mian Li , Qing Huang , Xiang Wu . Performance optimization of aqueous Zn/MnO₂ batteries through the synergistic effect of PVP intercalation and GO coating. Chinese Chemical Letters, 2025, 36(3): 110701-. doi: 10.1016/j.cclet.2024.110701
10. [10]
  Xiaojuan Huang , Zerui Yan , Xiaoqing Chang , Dafu Tang , Qiulong Wei . Size effect of graphite anode with boosted capacitive solvated-Na⁺ co-intercalation for high-power sodium-ion capacitors. Chinese Chemical Letters, 2026, 37(5): 110953-. doi: 10.1016/j.cclet.2025.110953
11. [11]
  Shu-Ran Xu , Fang-Xing Xiao . Metal halide perovskites quantum dots: Synthesis, and modification strategies for solar CO2 conversion. Chinese Journal of Structural Chemistry, 2023, 42(12): 100173-100173. doi: 10.1016/j.cjsc.2023.100173
12. [12]
  Xingwen Cheng , Haoran Ren , Jiangshan Luo . Boosting the self-trapped exciton emission in vacancy-ordered double perovskites via supramolecular assembly. Chinese Journal of Structural Chemistry, 2024, 43(6): 100306-100306. doi: 10.1016/j.cjsc.2024.100306
13. [13]
  Ruijing Fu , Junpeng Gao , Lingrui Wang , Bin Xiao , Guangxia Wang , Qingguang Zeng , Guanjun Xiao . Pressure-induced tunable photoluminescence of Mn-doped post-perovskites (TDMP)PbBr₄. Chinese Chemical Letters, 2026, 37(2): 111507-. doi: 10.1016/j.cclet.2025.111507
14. [14]
  Xin Zhang , Tongxia Jin , Changyin Yang , Dezheng Xu , Haidong Jia , Lin Xu . Azobenzene-containing photoresponsive metal-organic cages. Chinese Chemical Letters, 2025, 36(12): 111135-. doi: 10.1016/j.cclet.2025.111135
15. [15]
  Jinlv Wei , Jianlong Zhang , Huan Wen , Zhixiang Zhai , Fangyuan Guan , Zelong Sun , Jia Wu , Shibin Yin . Tuning the eg∗ band broadening of the in-situ NiOOH by W doping for efficient biomass electrooxidation. Chinese Journal of Structural Chemistry, 2025, 44(5): 100541-100541. doi: 10.1016/j.cjsc.2025.100541
16. [16]
  Xin Dong , Tianqi Chen , Jing Liang , Lei Wang , Huajie Wu , Zhijin Xu , Junhua Luo , Li-Na Li . Structure design of lead-free chiral-polar perovskites for sensitive self-powered X-ray detection. Chinese Journal of Structural Chemistry, 2024, 43(6): 100256-100256. doi: 10.1016/j.cjsc.2024.100256
17. [17]
  Haiyang Gu , Xiang Xu . Multicolor hybrid metal halides and anti-counterfeiting. Chinese Journal of Structural Chemistry, 2024, 43(9): 100352-100352. doi: 10.1016/j.cjsc.2024.100352
18. [18]
  Wenjing Dai , Lan Luo , Zhen Yin . Interface reconstruction of hybrid oxide electrocatalysts for seawater oxidation. Chinese Journal of Structural Chemistry, 2025, 44(3): 100442-100442. doi: 10.1016/j.cjsc.2024.100442
19. [19]
  Shuqi Chen , Cankun Zhang , Xiaonuo Dong , Hui-Jun Zhang , Jianbin Lin . Synthesis and photophysical properties of alternating donor-acceptor conjugated nanorings. Chinese Chemical Letters, 2025, 36(6): 110354-. doi: 10.1016/j.cclet.2024.110354
20. [20]
  Ran Gao , Qian Zou , Qian-Qian Su , Xiu-Fang Ma , Ye-Hui Qin , Rui Liao , Song-Song Bao , Li-Min Zheng . Photoresponsive lanthanide-dianthracene framework: Introduction of photoactive anthracene pairs by controlling the synthesis temperature. Chinese Chemical Letters, 2025, 36(10): 110404-. doi: 10.1016/j.cclet.2024.110404

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(952)
HTML views(48)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142