Citation: Caili Yang, Tao Long, Ruotong Li, Chunyang Wu, Yuan-Li Ding. Pseudocapacitance dominated Li₃VO₄ encapsulated in N-doped graphene via 2D nanospace confined synthesis for superior lithium ion capacitors[J]. Chinese Chemical Letters, ;2025, 36(2): 109675. doi: 10.1016/j.cclet.2024.109675 shu

Pseudocapacitance dominated Li₃VO₄ encapsulated in N-doped graphene via 2D nanospace confined synthesis for superior lithium ion capacitors

Caili Yang ^{a, b} ,
Tao Long ^b ,
Ruotong Li ^b ,
Chunyang Wu ^{a, *,} ,
Yuan-Li Ding ^b

a.
National Key Laboratory of Electronic Thin Film and Integrated Devices, University of Electronic Science and Technology of China, Chengdu 611731, China
b.
College of Materials Science and Engineering, Hunan University, Changsha 410082, China

wucy@uestc.edu.cn

Received Date: 12 December 2023
Revised Date: 14 January 2024
Accepted Date: 22 February 2024
Available Online: 23 February 2024

Figures(6)

A pseudocapacitance dominated anode material assembled from Li₃VO₄ nanocrystals encapsulated in the interlayers of N-doped graphene has been developed via a facile 2D nanospace confined strategy for lithium ion capacitors (LICs). In this contribution, the N-doped graphene synthesized by a faicle solid state reaction using C₃N₄ nanosheets as template and glucose as carbon source provides sufficient 2D nanospace for the confined and homogeneous growth of Li₃VO₄ at the nanoscale, and simultaneously efficiently anchors each nanobuilding block inside the interlayers, thus realizing the utilizaiton of full potential of active components. The so-formed 3D hybrids not only ensure intimate electronic coupling between active materials and N-doped graphene, but also realize robust structure integrity. Owing to these unique advantages, the resulting hybrids show pseudocapacitance dominated lithium storage behaviors with capacitive contributions of over 90% at both low and high current rates. The LVO@C@NG delivers reversible capacities of 206 mAh/g at 10 A/g, capacity retention of 92.7% after 1000 cycles at 2 A/g, and a high energy density of 113.6 Wh/kg at 231.8 W/kg for LICs.
- Lithium ion capacitor,
- Li₃VO₄,
- Graphene,
- Anode,
- Pseudocapacitance
1. [1]
  A. Jagadale, X. Zhou, R. Xiong, et al., Energy Storage Mater. 19 (2019) 314–329.
2. [2]
  L. Jin, C. Shen, A. Shellikeri, et al., Energy Environ Sci. 13 (2020) 2341–2362. doi: 10.1039/d0ee00807a
3. [3]
  W. Liu, Y. An, L. Wang, et al., J. Energy Chem. 80 (2023) 68–76.
4. [4]
  L. Wang, X. Zhang, C. Li, et al., Chem. Eng. J. 468 (2023) 143507.
5. [5]
  N.S. Choi, Z. Chen, S.A. Freunberger, et al., Angew. Chem. Int. Ed. 51 (2012) 9994–10024. doi: 10.1002/anie.201201429
6. [6]
  L. Wang, X. Zhang, Y. Xu, et al., Adv. Funct. Mater. 31 (2021) 2104286.
7. [7]
  L. Wang, X. Zhang, C. Li, et al., Rare Metals 41 (2022) 2971–2984. doi: 10.1007/s12598-022-02028-8
8. [8]
  B. Li, J. Zheng, H. Zhang, et al., Adv. Mater. 30 (2018) 1705670.
9. [9]
  V. Augustyn, P. Simon, B. Dunn, Energy Environ. Sci. 7 (2014) 1597–1614. doi: 10.1039/c3ee44164d
10. [10]
  R. Marchand, L. Brohan, M. Tournoux, Mater. Res. Bull. 15 (1980) 1129–1133.
11. [11]
  M. Zukalová, M. Kalbác, L. Kavan, I. Exnar, M. Graetzel, Chem. Mater. 17 (2005) 1248–1255. doi: 10.1021/cm048249t
12. [12]
  M. Okubo, E. Hosono, J. Kim, et al., J. Am. Chem. Soc. 129 (2007) 7444–7452. doi: 10.1021/ja0681927
13. [13]
  M. Okubo, Y. Mizuno, H. Yamada, et al., ACS Nano 4 (2010) 741–752. doi: 10.1021/nn9012065
14. [14]
  H.S. Kim, J.B. Cook, S.H. Tolbert, B. Dunn, J. Electrochem. Soc. 162 (2015) A5083. doi: 10.1149/2.0141505jes
15. [15]
  C. Liao, Q. Zhang, T. Zhai, H. Li, H. Zhou, Energy Storage Mater. 7 (2017) 17–31. doi: 10.3390/photonics4010017
16. [16]
  C. Zhang, H. Song, C. Liu, et al., Adv. Funct. Mater. 25 (2015) 3497–3504. doi: 10.1002/adfm.201500644
17. [17]
  H. Tran Huu, N.H. Vu, H. Ha, et al., Nat. Commun. 12 (2021) 3081.
18. [18]
  W. Liu, X. Zhang, C. Li, et al., Chin. Chem. Lett. 31 (2020) 2225–2229.
19. [19]
  X. Ren, D. Ai, C. Zhan, et al., Electrochim. Acta 355 (2020) 136819.
20. [20]
  G. Wang, C. Lu, X. Zhang, et al., Nano Energy 36 (2017) 46–57.
21. [21]
  J.Y. Luo, Y.Y. Xia, J. Power Sources 186 (2009) 224–227.
22. [22]
  Z. Chen, H. Li, X. Lu, et al., ChemElectroChem 5 (2018) 1516–1524. doi: 10.1002/celc.201701390
23. [23]
  Y. Yue, H. Liang, Adv. Energy Mater. 7 (2017) 1602545.
24. [24]
  W. Zhu, B. Zou, C. Zhang, et al., Adv. Mater. Interfaces 7 (2020) 2000705.
25. [25]
  Q. Li, Q. Wei, J. Sheng, et al., Adv. Sci. 2 (2015) 1500284.
26. [26]
  Z. Liang, Y. Zhao, Y. Dong, et al., Electroanal. Chem. 745 (2015) 1–7. doi: 10.3901/JME.2015.05.001
27. [27]
  H. Cheng, Y. Zhang, X. Cai, et al., Small (2023) 2305762.
28. [28]
  M. Zhang, R. Bai, S. King, et al., Energy Storage Mater. 43 (2021) 482–491.
29. [29]
  Q. Hu, J.Y. Liao, X.D. He, et al., J. Mater. Chem. A 7 (2019) 4660–4667. doi: 10.1039/c8ta11890f
30. [30]
  C. Yang, Y. Ran, C. Gao, Z. Wang, Y.L. Ding, J. Alloy Compd. 918 (2022) 165668.
31. [31]
  Y.L. Ding, P. Kopold, K. Hahn, et al., Adv. Funct. Mater. 26 (2016) 1112–1119. doi: 10.1002/adfm.201504294
32. [32]
  H. Park, W. Jae, J. Kim, J. Alloy Compd. 767 (2018) 657–665.
33. [33]
  C. Liao, Y. Wen, B. Shan, T. Zhai, H. Li, J. Power Sources 348 (2017) 48–56.
34. [34]
  Z. Jian, M. Zheng, Y. Liang, et al., Chem. Commun. 51 (2015) 229–231.
35. [35]
  T. Brezesinski, J. Wang, S.H. Tolbert, B. Dunn, Nat. Mater. 9 (2010) 146–151. doi: 10.1038/nmat2612
36. [36]
  L. Zhu, Z. Li, G. Ding, et al., J. Mater. Sci. Technol. 89 (2021) 68–87. doi: 10.1117/12.2582764
1. [1]
  Xingang Kong , Yabei Su , Cuijuan Xing , Weijie Cheng , Jianfeng Huang , Lifeng Zhang , Haibo Ouyang , Qi Feng . Facile synthesis of porous TiO₂/SnO₂ nanocomposite as lithium ion battery anode with enhanced cycling stability via nanoconfinement effect. Chinese Chemical Letters, 2024, 35(11): 109428-. doi: 10.1016/j.cclet.2023.109428
2. [2]
  Tong Su , Yue Wang , Qizhen Zhu , Mengyao Xu , Ning Qiao , Bin Xu . Multiple conductive network for KTi₂(PO₄)₃ anode based on MXene as a binder for high-performance potassium storage. Chinese Chemical Letters, 2024, 35(8): 109191-. doi: 10.1016/j.cclet.2023.109191
3. [3]
  Yunyu Zhao , Chuntao Yang , Yingjian Yu . A review on covalent organic frameworks for rechargeable zinc-ion batteries. Chinese Chemical Letters, 2024, 35(7): 108865-. doi: 10.1016/j.cclet.2023.108865
4. [4]
  Zhanheng Yan , Weiqing Su , Weiwei Xu , Qianhui Mao , Lisha Xue , Huanxin Li , Wuhua Liu , Xiu Li , Qiuhui Zhang . Carbon-based quantum dots/nanodots materials for potassium ion storage. Chinese Chemical Letters, 2025, 36(4): 110217-. doi: 10.1016/j.cclet.2024.110217
5. [5]
  Cheng Guo , Xiaoxiao Zhang , Xiujuan Hong , Yiqiu Hu , Lingna Mao , Kezhi Jiang . Graphene as adsorbent for highly efficient extraction of modified nucleosides in urine prior to liquid chromatography-tandem mass spectrometry analysis. Chinese Chemical Letters, 2024, 35(4): 108867-. doi: 10.1016/j.cclet.2023.108867
6. [6]
  Sanmei Wang , Yong Zhou , Hengxin Fang , Chunyang Nie , Chang Q Sun , Biao Wang . Constant-potential simulation of electrocatalytic N₂ reduction over atomic metal-N-graphene catalysts. Chinese Chemical Letters, 2025, 36(3): 110476-. doi: 10.1016/j.cclet.2024.110476
7. [7]
  Sanmei Wang , Dengxin Yan , Wenhua Zhang , Liangbing Wang . Graphene-supported isolated platinum atoms and platinum dimers for CO₂ hydrogenation: Catalytic activity and selectivity variations. Chinese Chemical Letters, 2025, 36(4): 110611-. doi: 10.1016/j.cclet.2024.110611
8. [8]
  Wenjing Xiong , Yulin Xu , Fangzhou Zhao , Baokai Xia , Hongqiang Wang , Wei Liu , Sheng Chen , Yongzhi Zhang . Graphene architecture interpenetrated with mesoporous carbon nanosheets promotes fast and stable potassium storage. Chinese Chemical Letters, 2025, 36(4): 109738-. doi: 10.1016/j.cclet.2024.109738
9. [9]
  Li Lin , Song-Lin Tian , Zhen-Yu Hu , Yu Zhang , Li-Min Chang , Jia-Jun Wang , Wan-Qiang Liu , Qing-Shuang Wang , Fang Wang . Molecular crowding electrolytes for stabilizing Zn metal anode in rechargeable aqueous batteries. Chinese Chemical Letters, 2024, 35(7): 109802-. doi: 10.1016/j.cclet.2024.109802
10. [10]
  Junhan Luo , Qi Qing , Liqin Huang , Zhe Wang , Shuang Liu , Jing Chen , Yuexiang Lu . Non-contact gaseous microplasma electrode as anode for electrodeposition of metal and metal alloy in molten salt. Chinese Chemical Letters, 2024, 35(4): 108483-. doi: 10.1016/j.cclet.2023.108483
11. [11]
  Chaozheng He , Pei Shi , Donglin Pang , Zhanying Zhang , Long Lin , Yingchun Ding . First-principles study of the relationship between the formation of single atom catalysts and lattice thermal conductivity. Chinese Chemical Letters, 2024, 35(6): 109116-. doi: 10.1016/j.cclet.2023.109116
12. [12]
  Kailong Zhang , Chao Zhang , Luanhui Wu , Qidong Yang , Jiadong Zhang , Guang Hu , Liang Song , Gaoran Li , Wenlong Cai . Chloride molten salt derived attapulgite with ground-breaking electrochemical performance. Chinese Chemical Letters, 2024, 35(10): 109618-. doi: 10.1016/j.cclet.2024.109618
13. [13]
  Yixin Lu , Minghan Qin , Shixian Zhang , Zhen Liu , Wang Sun , Zhenhua Wang , Jinshuo Qiao , Kening Sun . Triple-conducting heterostructure anodes for electrochemical ethane nonoxidative dehydrogenation by protonic ceramic electrolysis cells. Chinese Chemical Letters, 2025, 36(4): 110567-. doi: 10.1016/j.cclet.2024.110567
14. [14]
  Mianying Huang , Zhiguang Xu , Xiaoming Lin . Mechanistic analysis of Co2VO4/X (X = Ni, C) heterostructures as anode materials of lithium-ion batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100309-100309. doi: 10.1016/j.cjsc.2024.100309
15. [15]
  Haixia Wu , Kailu Guo . Iodized polyacrylonitrile as fast-charging anode for lithium-ion battery. Chinese Chemical Letters, 2024, 35(10): 109550-. doi: 10.1016/j.cclet.2024.109550
16. [16]
  Jun Dong , Senyuan Tan , Sunbin Yang , Yalong Jiang , Ruxing Wang , Jian Ao , Zilun Chen , Chaohai Zhang , Qinyou An , Xiaoxing Zhang . Spatial confinement of free-standing graphene sponge enables excellent stability of conversion-type Fe₂O₃ anode for sodium storage. Chinese Chemical Letters, 2025, 36(3): 110010-. doi: 10.1016/j.cclet.2024.110010
17. [17]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
18. [18]
  Xuejie Gao , Xinyang Chen , Ming Jiang , Hanyan Wu , Wenfeng Ren , Xiaofei Yang , Runcang Sun . Long-lifespan thin Li anode achieved by dead Li rejuvenation and Li dendrite suppression for all-solid-state lithium batteries. Chinese Chemical Letters, 2024, 35(10): 109448-. doi: 10.1016/j.cclet.2023.109448
19. [19]
  Yihong Li , Zhong Qiu , Lei Huang , Shenghui Shen , Ping Liu , Haomiao Zhang , Feng Cao , Xinping He , Jun Zhang , Yang Xia , Xinqi Liang , Chen Wang , Wangjun Wan , Yongqi Zhang , Minghua Chen , Wenkui Zhang , Hui Huang , Yongping Gan , Xinhui Xia . Plasma enhanced reduction method for synthesis of reduced graphene oxide fiber/Si anode with improved performance. Chinese Chemical Letters, 2024, 35(11): 109510-. doi: 10.1016/j.cclet.2024.109510
20. [20]
  Xin-Tong Zhao , Jin-Zhi Guo , Wen-Liang Li , Jing-Ping Zhang , Xing-Long Wu . Two-dimensional conjugated coordination polymer monolayer as anode material for lithium-ion batteries: A DFT study. Chinese Chemical Letters, 2024, 35(6): 108715-. doi: 10.1016/j.cclet.2023.108715

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(393)
HTML views(18)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Pseudocapacitance dominated Li3VO4 encapsulated in N-doped graphene via 2D nanospace confined synthesis for superior lithium ion capacitors

Metrics

通讯作者: 陈斌, bchen63@163.com

Pseudocapacitance dominated Li₃VO₄ encapsulated in N-doped graphene via 2D nanospace confined synthesis for superior lithium ion capacitors