Citation: Wenxiang Ma, Xinyu He, Tianyi Chen, De-Li Ma, Hongzheng Chen, Chang-Zhi Li. Near-infrared non-fused electron acceptors for efficient organic photovoltaics[J]. Chinese Chemical Letters, ;2024, 35(4): 109099. doi: 10.1016/j.cclet.2023.109099 shu

Near-infrared non-fused electron acceptors for efficient organic photovoltaics

State Key Laboratory of Silicon and Advanced Semiconductor Materials, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China

czli@zju.edu.cn

Received Date: 18 July 2023
Revised Date: 11 September 2023
Accepted Date: 13 September 2023
Available Online: 15 September 2023

Figures(5)

Developing narrow-bandgap organic semiconductors is important to facilitate the advancement of organic photovoltaics (OPVs). Herein, two near-infrared non-fused ring acceptors (NIR NFRAs), PTBFTT-F and PTBFTT-Cl have been developed with A-π_A-π_D-D-π_D-π_A-A non-fused structures. It is revealed that the introduction of electron deficient π-bridge (π_A) and multiple intramolecular noncovalent interactions effectively retained the structural planarity and intramolecular charge transfer of NFRAs, extending strong NIR photon absorption up to 950 nm. Further, the chlorinated acceptor, with the enlarged π-surface compared to the fluorinated counterpart, promoted not only molecular stacking in solid, but also the desirable photochemical stability in ambient, which are helpful to thereby improve the exciton and charge dynamics for the corresponding OPVs. Overall, this work provides valuable insights into the design of NIR organic semiconductors.
- Organic photovoltaic,
- Near-infrared,
- Non-fused electron acceptor,
- Noncovalent interaction,
- Stability
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