Citation: Yunlei Zhang, Yiran Liu, Wen Guan, Mengxue Cao, Yao Chen, Pengwei Huo. Strong metal-support interaction between AuPd nanoparticles and oxygen-rich defect ZrO₂ for enhanced catalytic 5-hydroxymethylfurfural oxidation[J]. Chinese Chemical Letters, ;2024, 35(2): 108932. doi: 10.1016/j.cclet.2023.108932 shu

Strong metal-support interaction between AuPd nanoparticles and oxygen-rich defect ZrO₂ for enhanced catalytic 5-hydroxymethylfurfural oxidation

Yunlei Zhang ^a ,
Yiran Liu ^a ,
Wen Guan ^a ,
Mengxue Cao ^a ,
Yao Chen ^{b, *,} ,
Pengwei Huo ^{a, *,}

a.
Institute of Green Chemistry and Chemical Technology, School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, China
b.
School of the Environment and Safety, Jiangsu University, Zhenjiang 212013, China

chenyao1390@ujs.edu.cn

huopw@ujs.edu.cn

Received Date: 11 May 2023
Revised Date: 25 July 2023
Accepted Date: 13 August 2023
Available Online: 15 August 2023

Figures(4)

The unique properties of metal oxide surfaces, crystal surfaces and defects play vital roles in biomass upgrading reactions. In this work, hierarchical porous bowl-shaped ZrO₂ (HB-ZrO₂) with mixed crystal phase was designed and employed as the support for loading AuPd bimetal with different proportions to synthesize AuPd/HB-ZrO₂ catalysts. The effects of surface chemistry, oxygen defects, bimetal interaction and metal-support interaction of AuPd/HB-ZrO₂ on catalytic performance for the selective oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA) were systematically investigated. The Au₂Pd₁/HB-ZrO₂ catalyst afforded a satisfactory FDCA yield of 99.9% from HMF oxidation using O₂ as the oxidant in water, accompanied with an excellent FDCA productivity at 97.6 mmol g⁻¹ h⁻¹. This work offers fresh insights into rationally designing efficient catalysts with oxygen-rich defects for the catalytic upgrading of biomass platform chemicals.
- 5-Hydroxymethylfurfural oxidation,
- 2,5-Furandicarboxylic acid,
- Oxygen-rich defect ZrO₂,
- AuPd bimetal,
- Bowl-shaped structure
1. [1]
  N. Chi Van, D. Lewis, W.H. Chen, et al., Catal. Today 278 (2016) 344–349. doi: 10.1016/j.cattod.2016.03.022
2. [2]
  F. Menegazzo, E. Ghedini, M. Signoretto, Molecules 23 (2018) 2201. doi: 10.3390/molecules23092201
3. [3]
  T. Wang, M.W. Nolte, B.H. Shanks, Green Chem. 16 (2014) 548–572. doi: 10.1039/C3GC41365A
4. [4]
  M. Sun, Y. Wang, C. Sun, et al., Chin. Chem. Lett. 33 (2022) 385–389. doi: 10.1016/j.cclet.2021.05.009
5. [5]
  Z. Jiang, Y. Zeng, D. Hu, et al., Green Chem. 25 (2023) 871–892. doi: 10.1039/D2GC03444A
6. [6]
  P. Pal, S. Saravanamurugan, ChemSusChem 12 (2019) 145–163. doi: 10.1002/cssc.201801744
7. [7]
  J.B. Heo, Y.S. Lee, C.H. Chung, Biotechnol. Adv. 53 (2021) 107838. doi: 10.1016/j.biotechadv.2021.107838
8. [8]
  C. Chen, L. Wang, B. Zhu, et al., J. Energy Chem. 54 (2021) 528–554. doi: 10.1016/j.jechem.2020.05.068
9. [9]
  Y. Zhao, M. Cai, J. Xian, Y. Sun, G. Li, J. Mater. Chem. A 9 (2021) 20164–20183. doi: 10.1039/D1TA04981J
10. [10]
  O. Simoska, Z. Rhodes, S. Weliwatte, et al., ChemSusChem 14 (2021) 1674–1686. doi: 10.1002/cssc.202100139
11. [11]
  Y. Meng, S. Yang, H. Li, ChemSusChem 15 (2022) e202102581. doi: 10.1002/cssc.202102581
12. [12]
  D. Haldar, D. Sen, K. Gayen, Int. J. Green Energy 13 (2016) 1232–1253. doi: 10.1080/15435075.2016.1181075
13. [13]
  S. Albonetti, T. Pasini, A. Lolli, et al., Catal. Today 195 (2021) 120–126.
14. [14]
  Z. Gao, R. Xie, G. Fan, L. Yang, F. Li, ACS Sustain. Chem. Eng. 5 (2017) 5852–5861. doi: 10.1021/acssuschemeng.7b00573
15. [15]
  Y. Zhou, L. Liu, G. Li, C. Hu, ACS Catal. 11 (2021) 7099–7113. doi: 10.1021/acscatal.1c00632
16. [16]
  B. Liu, S. Xu, M. Zhang, et al., Green Chem. 23 (2021) 4034–4043. doi: 10.1039/D1GC00901J
17. [17]
  H.K. Min, Y.W. Kim, C. Kim, et al., Chem. Eng. J. 428 (2022) 131766. doi: 10.1016/j.cej.2021.131766
18. [18]
  Y. Zheng, M. Okumura, X. Hua, et al., J. Catal. 401 (2021) 188–199. doi: 10.1016/j.jcat.2021.07.021
19. [19]
  X. Yang, X. Ma, X. Yu, M. Ge, Appl. Catal. B: Environ. 263 (2020) 118355. doi: 10.1016/j.apcatb.2019.118355
20. [20]
  Y. Zhang, Y. Cao, C. Yan, et al., Chem. Eng. J. 459 (2023) 141644. doi: 10.1016/j.cej.2023.141644
21. [21]
  M.P. Casaletto, A. Longo, A. Martorana, A. Prestianni, A.M. Venezia, Surf. Interface Anal. 38 (2006) 215–218. doi: 10.1002/sia.2180
22. [22]
  F. Jiang, S. Wang, B. Liu, et al., ACS Catal. 10 (2020) 11493–11509. doi: 10.1021/acscatal.0c03324
23. [23]
  W. Li, Y. Liu, M. Mu, et al., Appl. Catal. B: Environ. 254 (2019) 531–540. doi: 10.1016/j.apcatb.2019.05.028
24. [24]
  Q. Li, H. Wang, Z. Tian, et al., Catal. Sci. Technol. 9 (2019) 1570–1580. doi: 10.1039/C9CY00211A
25. [25]
  H. Zhang, T. Gao, Q. Cao, W. Fang, ACS Sustain. Chem. Eng. 9 (2021) 6056–6067. doi: 10.1021/acssuschemeng.1c01398
26. [26]
  B.N. Zope, D.D. Hibbitts, M. Neurock, R.J. Davis, Science 330 (2010) 74–78. doi: 10.1126/science.1195055
27. [27]
  V.R. Gangwal, J. van der Schaaf, B.F.M. Kuster, J.C. Schouten, J. Catal. 229 (2005) 389–403. doi: 10.1016/j.jcat.2004.11.021
28. [28]
  G. Wu, G. Zhao, J. Sun, et al., J. Catal. 377 (2019) 271–282. doi: 10.1016/j.jcat.2019.06.030
29. [29]
  Y. Pan, G. Wu, Y. He, J. Feng, D. Li, J. Catal. 369 (2019) 222–232. doi: 10.1016/j.jcat.2018.10.030
1. [1]
  Ping Lu , Baoyin Du , Ke Liu , Ze Luo , Abiduweili Sikandaier , Lipeng Diao , Jin Sun , Luhua Jiang , Yukun Zhu . Heterostructured In2O3/In2S3 hollow fibers enable efficient visible-light driven photocatalytic hydrogen production and 5-hydroxymethylfurfural oxidation. Chinese Journal of Structural Chemistry, 2024, 43(8): 100361-100361. doi: 10.1016/j.cjsc.2024.100361
2. [2]
  Lili Wang , Ya Yan , Rulin Li , Xujie Han , Jiahui Li , Ting Ran , Jialu Li , Baichuan Xiong , Xiaorong Song , Zhaohui Yin , Hong Wang , Qingjun Zhu , Bowen Cheng , Zhen Yin . Interface engineering of 2D NiFe LDH/NiFeS heterostructure for highly efficient 5-hydroxymethylfurfural electrooxidation. Chinese Chemical Letters, 2024, 35(9): 110011-. doi: 10.1016/j.cclet.2024.110011
3. [3]
  Shiqi Peng , Yongfang Rao , Tan Li , Yufei Zhang , Jun-ji Cao , Shuncheng Lee , Yu Huang . Regulating the electronic structure of Ir single atoms by ZrO₂ nanoparticles for enhanced catalytic oxidation of formaldehyde at room temperature. Chinese Chemical Letters, 2024, 35(7): 109219-. doi: 10.1016/j.cclet.2023.109219
4. [4]
  Ke Wang , Jia Wu , Shuyi Zheng , Shibin Yin . NiCo Alloy Nanoparticles Anchored on Mesoporous Mo2N Nanosheets as Efficient Catalysts for 5-Hydroxymethylfurfural Electrooxidation and Hydrogen Generation. Chinese Journal of Structural Chemistry, 2023, 42(10): 100104-100104. doi: 10.1016/j.cjsc.2023.100104
5. [5]
  Yi Zhou , Yanzhen Liu , Yani Yan , Zonglin Yi , Yongfeng Li , Cheng-Meng Chen . Enhanced oxygen reduction reaction on La-Fe bimetal in porous N-doped carbon dodecahedra with CNTs wrapping. Chinese Chemical Letters, 2025, 36(1): 109569-. doi: 10.1016/j.cclet.2024.109569
6. [6]
  Linfang ZHANG , Wenzhu YIN , Gui YIN . A 2-dicyanomethylene-3-cyano-4,5,5-trimethyl-2,5-dihydrofuran-based near-infrared fluorescence probe for the detection of hydrogen sulfide and imaging of living cells. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 540-548. doi: 10.11862/CJIC.20240405
7. [7]
  Xinyu Guo , Chang Li , Wenjun Deng , Yi Zhou , Yan Chen , Yushuang Xu , Rui Li . Phase engineering and heteroatom incorporation enable defect-rich MoS₂ for long life aqueous iron-ion batteries. Chinese Chemical Letters, 2025, 36(3): 109715-. doi: 10.1016/j.cclet.2024.109715
8. [8]
  Zhiqiang Wang , Yajie Gao , Tianjun Wang , Wei Chen , Zefeng Ren , Xueming Yang , Chuanyao Zhou . Photocatalyzed oxidation of water on oxygen pretreated rutile TiO₂(110). Chinese Chemical Letters, 2025, 36(4): 110602-. doi: 10.1016/j.cclet.2024.110602
9. [9]
  Liang Ma , Zhou Li , Zhiqiang Jiang , Xiaofeng Wu , Shixin Chang , Sónia A. C. Carabineiro , Kangle Lv . Effect of precursors on the structure and photocatalytic performance of g-C3N4 for NO oxidation and CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(11): 100416-100416. doi: 10.1016/j.cjsc.2024.100416
10. [10]
  Chupeng Luo , Keying Su , Shan Yang , Yujia Liang , Yawen Tang , Xiaoyu Qiu . Ultrathin NiS₂ nanocages with hierarchical-flexible walls and rich grain boundaries for efficient oxygen evolution reaction. Chinese Chemical Letters, 2025, 36(5): 109940-. doi: 10.1016/j.cclet.2024.109940
11. [11]
  Luyan Shi , Ke Zhu , Yuting Yang , Qinrui Liang , Qimin Peng , Shuqing Zhou , Tayirjan Taylor Isimjan , Xiulin Yang . Phytic acid-derivative Co₂B-CoPO_x coralloidal structure with delicate boron vacancy for enhanced hydrogen generation from sodium borohydride. Chinese Chemical Letters, 2024, 35(4): 109222-. doi: 10.1016/j.cclet.2023.109222
12. [12]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
13. [13]
  Tong Li , Leping Pan , Yan Zhang , Jihu Su , Kai Li , Kuiliang Li , Hu Chen , Qi Sun , Zhiyong Wang . Electrochemical construction of 2,5-diaryloxazoles via N–H and C(sp³)-H functionalization. Chinese Chemical Letters, 2024, 35(4): 108897-. doi: 10.1016/j.cclet.2023.108897
14. [14]
  Xi Tang , Chunlei Zhu , Yulu Yang , Shihan Qi , Mengqiu Cai , Abdullah N. Alodhayb , Jianmin Ma . Additive regulating Li⁺ solvation structure to construct dual LiF−rich electrode electrolyte interphases for sustaining 4.6 V Li||LiCoO₂ batteries. Chinese Chemical Letters, 2024, 35(12): 110014-. doi: 10.1016/j.cclet.2024.110014
15. [15]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
16. [16]
  Dongsheng Yang , Zixin Li , Yaoyao Lian , Ziyao Fu , Tianjiao Li , Pengtao Ma , Guoping Yang . A novel square-shaped Zr-substituted polyoxotungstate for the efficient catalytic oxidation of sulfide to sulfone. Chinese Chemical Letters, 2025, 36(3): 109717-. doi: 10.1016/j.cclet.2024.109717
17. [17]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
18. [18]
  Jing Cao , Dezheng Zhang , Bianqing Ren , Ping Song , Weilin Xu . Mn incorporated RuO₂ nanocrystals as an efficient and stable bifunctional electrocatalyst for oxygen evolution reaction and hydrogen evolution reaction in acid and alkaline. Chinese Chemical Letters, 2024, 35(10): 109863-. doi: 10.1016/j.cclet.2024.109863
19. [19]
  Mengxiang Zhu , Tao Ding , Yunzhang Li , Yuanjie Peng , Ruiping Liu , Quan Zou , Leilei Yang , Shenglei Sun , Pin Zhou , Guosheng Shi , Dongting Yue . Graphene controlled solid-state growth of oxygen vacancies riched V₂O₅ catalyst to highly activate Fenton-like reaction. Chinese Chemical Letters, 2024, 35(12): 109833-. doi: 10.1016/j.cclet.2024.109833
20. [20]
  Shuhui Li , Rongxiuyuan Huang , Yingming Pan . Electrochemical Synthesis of 2,5-Diphenyl-1,3,4-Oxadiazole: A Recommended Comprehensive Organic Chemistry Experiment. University Chemistry, 2025, 40(5): 357-365. doi: 10.12461/PKU.DXHX202407028

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(449)
HTML views(15)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Strong metal-support interaction between AuPd nanoparticles and oxygen-rich defect ZrO2 for enhanced catalytic 5-hydroxymethylfurfural oxidation

Metrics

通讯作者: 陈斌, bchen63@163.com

Strong metal-support interaction between AuPd nanoparticles and oxygen-rich defect ZrO₂ for enhanced catalytic 5-hydroxymethylfurfural oxidation