Citation: Jiajia Yuan, Xiaoya Fan, Jiacheng Yang, Xinfeng Zhang. Rare earth complexes chemiluminescence catalyzed by gold nanoparticles for fast sensing of Tb³⁺ and Eu³⁺[J]. Chinese Chemical Letters, ;2023, 34(9): 108155. doi: 10.1016/j.cclet.2023.108155 shu

Rare earth complexes chemiluminescence catalyzed by gold nanoparticles for fast sensing of Tb³⁺ and Eu³⁺

State Key Lab of Geohazard Prevention & Geoenvironment Protection, College of Materials and Chemistry & Chemical Engineering, Chengdu University of Technology, Chengdu 610059, China

zhangxinfeng09@cdut.cn

Received Date: 23 August 2022
Revised Date: 7 January 2023
Accepted Date: 18 January 2023
Available Online: 26 January 2023

Figures(5)

Developing multiplex sensing technique is of great significance for fast sample analysis. However, the broad emissions of most chemiluminescence (CL) luminophores make the multiplex CL analysis be difficult. In this work, a simple and sensitive CL analytical method has been developed for the simultaneous determination of Tb³⁺ and Eu³⁺ thanking to their narrow band emission. The technique was based on a mixed CL system of periodate (IO₄⁻)-hydrogen peroxide (H₂O₂)-rare earth complexes, in which the reactive oxygen species (ROSs) especially singlet oxygen (¹O₂) can transfer its energy to the complex of Tb³⁺/Eu³⁺-ethylenediaminetetraacetic acid disodium salt (EDTA) and then produce the characteristic emissions of Tb³⁺ and Eu³⁺ without cross-interference. The further experiment found that the CL emissions of Tb³⁺ and Eu³⁺ could be catalyzed by the gold nanoparticles (AuNPs) via enhancing the yield of ¹O₂. The CL intensities of Tb³⁺ (at 490 nm) and Eu³⁺ (at 620 nm) increased linearly with concentration of Tb³⁺ and Eu³⁺. After the optimization of the CL sensing conditions, the limits of detection (LOD) were 5.0 × 10⁻⁹ mol/L and 8.0 × 10⁻⁷ mol/L for Tb³⁺ and Eu³⁺, respectively. Finally, the method has been applied for measuring the contents of Tb³⁺ and Eu³⁺ in leaching solution of mine sample and Tb³⁺/Eu³⁺-contained nanomaterials with satisfactory results. The present system provides a new CL technique for multiplex sensing with simplicity and high sensitivity.
- Gold nanoparticles,
- Rare earth ions,
- Chemiluminescence,
- Multiplex analysis,
- Fast sensing
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Rare earth complexes chemiluminescence catalyzed by gold nanoparticles for fast sensing of Tb3+ and Eu3+

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通讯作者: 陈斌, bchen63@163.com

Rare earth complexes chemiluminescence catalyzed by gold nanoparticles for fast sensing of Tb³⁺ and Eu³⁺