Citation: Xiang Han, Tiantian Wu, Lanhui Gu, Minfeng Chen, Jianzhong Song, Dan Tian, Jizhang Chen. Li-MOF-based ions regulator enabling fast-charging and dendrite-free lithium metal anode[J]. Chinese Chemical Letters, ;2023, 34(2): 107594. doi: 10.1016/j.cclet.2022.06.017 shu

Li-MOF-based ions regulator enabling fast-charging and dendrite-free lithium metal anode

College of Materials Science and Engineering, Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Nanjing Forestry University, Nanjing 210037, China

tiandan@njfu.edu.cn

chenjizhang@njfu.edu.cn

Received Date: 27 April 2022
Revised Date: 20 May 2022
Accepted Date: 7 June 2022
Available Online: 11 June 2022

Figures(4)

Li metal has been regarded as the holy grail for the next-generation Li-ion battery. Li dendrites issues, however, impede its practical application. In general, prolonging the sand time of Li nucleation and regulating homogeneous Li⁺ flux are effective approaches to suppress the dendrites formation and growth. Regarding this view, a functional polypropylene (PP) separator is developed to regulate ion transportation via a newly designed Li-based metal-organic framework (Li-MOF) coating. The Li-MOF crystallizes in the orthorhombic space group P212121 and features a double-walled three-dimensional (3D) structure with 1D channels. The well-defined intrinsic nanochannels of Li-MOF and the steric-hinerance effect both restrict free migration of anions, contributing to a high Li⁺ transference number of 0.65, which improve the Sand time of Li nucleation. Meanwhile, the Li-MOF coating with uniform porous structure promotes homogeneous Li⁺ flux at the surface of Li metal. Furthermore, the Li-MOF coating layer helps to build solid-electrolyte interphase (SEI) layer that comprises of inorganic LiF and Li₃N, which further prohibits the dendrites growth. Consequently, a highly stable Li plating/stripping cycling for over 1000 h is achieved. The functional separator also enables high-performance full lithium metal cells, the high-rate and long-stable cycling performance of LiNi_0.8Mn_0.1Co_0.1 (NMC811)-Li and LiCoO₂ (LCO)-Li cells further demonstrate the feasibility of this concept.
- Lithium-ion battery,
- Li metal anode,
- Metal-organic framework,
- Li ions flux,
- Solid-electrolyte interphase
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