Citation: Yao Li, Mohammad Khurram Javed, Shu-Qi Wu, Arshia Sulaiman, Ying-Ying Wu, Zhao-Yang Li, Osamu Sato, Xian-He Bu. Aggregation-induced emission meets magnetic bistability: Synergy between spin crossover and fluorescence in iron(Ⅱ) complexes[J]. Chinese Chemical Letters, ;2023, 34(4): 107492. doi: 10.1016/j.cclet.2022.05.006 shu

Aggregation-induced emission meets magnetic bistability: Synergy between spin crossover and fluorescence in iron(Ⅱ) complexes

Yao Li ^{a, 1} ,
Mohammad Khurram Javed ^{a, 1} ,
Shu-Qi Wu ^b ,
Arshia Sulaiman ^a ,
Ying-Ying Wu ^a ,
Zhao-Yang Li ^{a, *,} ,
Osamu Sato ^b ,
Xian-He Bu ^a

a.
School of Materials Science and Engineering, Nankai University, Tianjin 300350, China
b.
Institute for Materials Chemistry and Engineering, Kyushu University, Fukuoka 819-0395, Japan

zhaoyang@nankai.edu.cn

Received Date: 26 March 2022
Revised Date: 13 April 2022
Accepted Date: 6 May 2022
Available Online: 10 May 2022

Figures(5)

Luminescent spin crossover (SCO) materials have attracted significant interest owing to their potential applications in magneto-optical switches. However, the majority of previously reported Fe^Ⅱ-based SCO complexes are adversely affected by fluorescence quenching in the solid-state. Here, we have constructed the first mononuclear Fe^Ⅱ complex decorated with an aggregation-induced emission (AIE) luminophore (i.e., tetraphenylethylene) that exhibits synergistic SCO and fluorescence behavior. Intriguingly, we obtained two types of crystals in different solvent systems, both displaying distinct magnetic bistability and fluorescence properties. The fluorescence intensity was observed to track the magnetic susceptibility, which confirmed that SCO and solid-state fluorescence operate synergistically. We introduce a novel approach for the construction of luminescent SCO compounds using an AIEgen as a luminophore, which leads to fluorescence emission in the solid-state, thus allowing us to study the synergy between SCO and fluorescence.
- Magnetic bistability,
- Spin crossover,
- Luminescence,
- Aggregation-induced emission,
- Supramolecular structures
1. [1]
  O. Kahn, C.J. Martinez, Science 279 (1998) 44. doi: 10.1126/science.279.5347.44
2. [2]
  O. Kahn, J. Kröber, C. Jay, Adv. Mater. 4 (1992) 718–728. doi: 10.1002/adma.19920041103
3. [3]
  H.J. Shepherd, C.M. Quintero, G. Molnár, L. Salmon, A. Bousseksou, Luminescent spin-crossover materials, in: M.A. Halcrow (Ed.), Spin-Crossover Materials: Properties and Application, John Wiley & Sons Ltd., 2013, pp. 347–373.
4. [4]
  O.I. Kucheriv, V.V. Oliynyk, V.V. Zagorodnii, et al., Sci. Rep. 6 (2016) 38334. doi: 10.1038/srep38334
5. [5]
  C. Lefter, V. Davesne, L. Salmon, et al., Magnetochemistry 2 (2016) 18. doi: 10.3390/magnetochemistry2010018
6. [6]
  K. Takahashi, H.B. Cui, Y. Okano, et al., J. Am. Chem. Soc. 130 (2008) 6688–6689. doi: 10.1021/ja801585r
7. [7]
  P.G. Lacroix, I. Malfant, J.A. Real, V. Rodriguez, Eur. J. Inorg. Chem. (2013) 615–627. doi: 10.1002/ejic.201201151
8. [8]
  Y. Bodenthin, G. Schwarz, Z. Tomkowicz, et al., J. Am. Chem. Soc. 131 (2009) 2934–2941. doi: 10.1021/ja808278s
9. [9]
  K.S. Kumar, M. Ruben, Coord. Chem. Rev. 346 (2017) 176–205. doi: 10.1016/j.ccr.2017.03.024
10. [10]
  Y. Garcia, F. Robert, A.D. Naik, et al., J. Am. Chem. Soc. 133 (2011) 15850–15853. doi: 10.1021/ja205974q
11. [11]
  J.L. Wang, Q. Liu, Y.S. Meng, et al., Chem. Sci. 9 (2018) 2892–2897. doi: 10.1039/C7SC05221A
12. [12]
  J.L. Wang, Q. Liu, X.J. Lv, et al., Dalton Trans. 45 (2016) 18552–18558. doi: 10.1039/C6DT03714C
13. [13]
  P. Dierks, A. Päpcke, O.S. Bokareva, et al., Inorg. Chem. 59 (2020) 14746–14761. doi: 10.1021/acs.inorgchem.0c02039
14. [14]
  B. Jiang, C.W. Zhang, X.L. Shi, H.B. Yang, Chinese J. Polym. Sci. 37 (2019) 372–382. doi: 10.1007/s10118-019-2216-1
15. [15]
  H.T. Feng, Y.X. Yuan, J.B. Xiong, et al., Chem. Soc. Rev. 47 (2018) 7452–7476. doi: 10.1039/c8cs00444g
16. [16]
  J.Y. Ge, Z. Chen, L. Zhang, et al., Angew. Chem. Int. Ed. 58 (2019) 8789–8793. doi: 10.1002/anie.201903281
17. [17]
  Y.R. Qiu, L. Cui, J.Y. Ge, et al., Front. Chem. 9 (2021) 692939.
18. [18]
  J. Yuan, S.Q. Wu, M.J. Liu, O. Sato, H.Z. Kou, J. Am. Chem. Soc. 140 (2018) 9426–9433. doi: 10.1021/jacs.8b00103
19. [19]
  Y. Jiao, J. Zhu, Y. Guo, W. He, Z. Guo, J. Mater. Chem. C 5 (2017) 5214–5222. doi: 10.1039/C7TC00507E
20. [20]
  J. Yuan, M.J. Liu, S.Q. Wu, et al., Inorg. Chem. Front. 6 (2019) 1170–1176. doi: 10.1039/c9qi00111e
21. [21]
  B. Benaicha, K.V. Do, A. Yangui, et al., Chem. Sci. 10 (2019) 6791–6798. doi: 10.1039/c9sc02331c
22. [22]
  C. Lochenie, K. Schötz, F. Panzer, et al., J. Am. Chem. Soc. 140 (2018) 700–709. doi: 10.1021/jacs.7b10571
23. [23]
  T. Delgado, M. Meneses-Sánchez, L. Piñeiro-López, et al., Chem. Sci. 9 (2018) 8446–8452. doi: 10.1039/c8sc02677g
24. [24]
  J.J. Amoore, C.J. Kepert, J.D. Cashion, et al., Chem. Eur. J. 12 (2006) 8220–8227. doi: 10.1002/chem.200601069
25. [25]
  C.H. Shih, C.F. Sheu, K. Kato, et al., Dalton Trans. 39 (2010) 9794–9800. doi: 10.1039/c0dt00470g
26. [26]
  C.F. Sheu, S.M. Chen, S.C. Wang, et al., Chem. Commun. (2009) 7512–7514. doi: 10.1039/b910378c
27. [27]
  N. Sabbatini, M. Guardigli, I. Manet, F. Bolletta, R. Ziessel, Inorg. Chem. 33 (1994) 955–959. doi: 10.1021/ic00083a020
28. [28]
  C.F. Wang, G.Y. Yang, Z.S. Yao, J. Tao, Chem. Eur. J. 24 (2018) 3218–3224. doi: 10.1002/chem.201704901
1. [1]
  Chun-Yun Ding , Ru-Yuan Zhang , Yu-Wu Zhong , Jiannian Yao . Binary and heterostructured microplates of iridium and ruthenium complexes: Preparation, characterization, and thermo-responsive emission. Chinese Journal of Structural Chemistry, 2024, 43(10): 100393-100393. doi: 10.1016/j.cjsc.2024.100393
2. [2]
  Hao Jiang , Yuan-Yuan He , Hai-Chao Liang , Meng-Jia Shang , Han-Han Lu , Chun-Hua Liu , Yin-Shan Meng , Tao Liu , Yuan-Yuan Zhu . Tuning lanthanide luminescence from bipyridine-bis(oxazoline/thiazoline) tetradentate ligands. Chinese Journal of Structural Chemistry, 2024, 43(9): 100354-100354. doi: 10.1016/j.cjsc.2024.100354
3. [3]
  Yan Cheng , Hua-Peng Ruan , Yan Peng , Longhe Li , Zhenqiang Xie , Lang Liu , Shiyong Zhang , Hengyun Ye , Zhao-Bo Hu . Magnetic, dielectric and luminescence synergetic switchable effects in molecular material [Et₃NCH₂Cl]₂[MnBr₄]. Chinese Chemical Letters, 2024, 35(4): 108554-. doi: 10.1016/j.cclet.2023.108554
4. [4]
  Zhu Shu , Xin Lei , Yeye Ai , Ke Shao , Jianliang Shen , Zhegang Huang , Yongguang Li . ATP-induced supramolecular assembly based on chromophoric organic molecules and metal complexes. Chinese Chemical Letters, 2024, 35(11): 109585-. doi: 10.1016/j.cclet.2024.109585
5. [5]
  Shuo Li , Qianfa Liu , Lijun Mao , Xin Zhang , Chunju Li , Da Ma . Benzothiadiazole-based water-soluble macrocycle: Synthesis, aggregation-induced emission and selective detection of spermine. Chinese Chemical Letters, 2024, 35(11): 109791-. doi: 10.1016/j.cclet.2024.109791
6. [6]
  Jun-Jie Fang , Zheng Liu , Yun-Peng Xie , Xing Lu . Superatomic Ag₅₈ nanoclusters incorporating a [MS₄@Ag₁₂]²⁺ (M = Mo or W) kernel show aggregation-induced emission. Chinese Chemical Letters, 2024, 35(10): 109345-. doi: 10.1016/j.cclet.2023.109345
7. [7]
  Yunli Xu , Xuwen Da , Lei Wang , Yatong Peng , Wanpeng Zhou , Xiulian Liu , Yao Wu , Wentao Wang , Xuesong Wang , Qianxiong Zhou . Ru(Ⅱ)-based aggregation-induced emission (AIE) agents with efficient ¹O₂ generation, photo-catalytic NADH oxidation and anticancer activity. Chinese Chemical Letters, 2025, 36(5): 110168-. doi: 10.1016/j.cclet.2024.110168
8. [8]
  Min Liu , Bin Feng , Feiyi Chu , Duoyang Fan , Fan Zheng , Fei Chen , Wenbin Zeng . An ESIPT-boosted NIR nanoprobe for ratiometric sensing of carbon monoxide via activatable aggregation-induced dual-color fluorescence. Chinese Chemical Letters, 2025, 36(5): 110043-. doi: 10.1016/j.cclet.2024.110043
9. [9]
  Pengfei Li , Chulin Qu , Fan Wu , Hu Gao , Chengyan Zhao , Yue Zhao , Zhen Shen . Robust free-base and metalated corrole radicals with reduction-induced emission. Chinese Chemical Letters, 2025, 36(2): 110292-. doi: 10.1016/j.cclet.2024.110292
10. [10]
  Pan Liu , Yanming Sun , Alberto J. Fernández-Carrión , Bowen Zhang , Hui Fu , Lunhua He , Xing Ming , Congling Yin , Xiaojun Kuang . Bismuth-based halide double perovskite Cs₂KBiCl₆: Disorder and luminescence. Chinese Chemical Letters, 2024, 35(5): 108641-. doi: 10.1016/j.cclet.2023.108641
11. [11]
  Yi Liu , Peng Lei , Yang Feng , Shiwei Fu , Xiaoqing Liu , Siqi Zhang , Bin Tu , Chen Chen , Yifan Li , Lei Wang , Qing-Dao Zeng . Topologically engineering of π-conjugated macrocycles: Tunable emission and photochemical reaction toward multi-cyclic polymers. Chinese Chemical Letters, 2024, 35(10): 109571-. doi: 10.1016/j.cclet.2024.109571
12. [12]
  Yupeng Liu , Hui Wang , Songnan Qu . Review on near-infrared absorbing/emissive carbon dots: From preparation to multi-functional application. Chinese Chemical Letters, 2025, 36(5): 110618-. doi: 10.1016/j.cclet.2024.110618
13. [13]
  Chaochao Jin , Kai Li , Jiongpei Zhang , Zhihua Wang , Jiajing Tan . N,O-Bidentated difluoroboron complexes based on pyridine-ester enolates: Facile synthesis, post-complexation modification, optical properties, and applications. Chinese Chemical Letters, 2024, 35(9): 109532-. doi: 10.1016/j.cclet.2024.109532
14. [14]
  You Zhou , Li-Sheng Wang , Shuang-Gui Lei , Bo-Cheng Tang , Zhi-Cheng Yu , Xing Li , Yan-Dong Wu , Kai-Lu Zheng , An-Xin Wu . I₂-DMSO mediated tetra-functionalization of enaminones for the construction of novel furo[2′,3′:4,5]pyrimido[1,2-b]indazole skeletons via in situ capture of ketenimine cations. Chinese Chemical Letters, 2025, 36(1): 109799-. doi: 10.1016/j.cclet.2024.109799
15. [15]
  Haibo Wan , Zhengzhong Lv , Jicai Jiang , Xuefeng Cheng , Qingfeng Xu , Haibin Shi , Jianmei Lu . Multidimensional detection of roxarsone via AIE-based sulfates. Chinese Chemical Letters, 2025, 36(3): 110023-. doi: 10.1016/j.cclet.2024.110023
16. [16]
  Xiangshuai Li , Jian Zhao , Li Luo , Zhuohao Jiao , Ying Shi , Shengli Hou , Bin Zhao . Visual and portable detection of metronidazole realized by metal-organic framework flexible sensor and smartphone scanning. Chinese Chemical Letters, 2024, 35(10): 109407-. doi: 10.1016/j.cclet.2023.109407
17. [17]
  Wen-Jun Xia , Yong-Jiang Wang , Yun-Fei Cao , Cai Sun , Xin-Xiong Li , Yan-Qiong Sun , Shou-Tian Zheng . A luminescent folded S-shaped high-nuclearity Eu₁₉-oxo-cluster embedded polyoxoniobate for information encryption. Chinese Chemical Letters, 2025, 36(2): 110248-. doi: 10.1016/j.cclet.2024.110248
18. [18]
  Yuanpeng Ye , Longfei Yao , Guofeng Liu . Engineering circularly polarized luminescence through symmetry manipulation in achiral tetraphenylpyrazine structures. Chinese Journal of Structural Chemistry, 2025, 44(2): 100460-100460. doi: 10.1016/j.cjsc.2024.100460
19. [19]
  Yinglian LI , Chengcheng ZHANG , Xinyu ZHANG , Xinyi WANG . Spin crossover in [Co(pytpy)₂]²⁺ complexes modified by organosulfonate anions. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1162-1172. doi: 10.11862/CJIC.20240087
20. [20]
  Shuai Liang , Wen-Jing Jiang , Ji-Xiang Hu . Achieving colossal anisotropic thermal expansion via synergism of spin crossover and rhombus deformation. Chinese Journal of Structural Chemistry, 2025, 44(2): 100430-100430. doi: 10.1016/j.cjsc.2024.100430

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(625)
HTML views(66)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142