Citation: Diankun Jia, Hua Zhong, Sixun Jiang, Risheng Yao, Feng Wang. Simultaneous enhancement of phosphorescence and chirality by host–guest recognition of molecular tweezers[J]. Chinese Chemical Letters, ;2022, 33(11): 4900-4903. doi: 10.1016/j.cclet.2022.02.081 shu

Simultaneous enhancement of phosphorescence and chirality by host–guest recognition of molecular tweezers

Diankun Jia ^{a, b} ,
Hua Zhong ^c ,
Sixun Jiang ^c ,
Risheng Yao ^{a, b, *,} ,
Feng Wang ^{c, *,}

a.
School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei 230009, China
b.
School of Food and Biological Engineering, Hefei University of Technology, Hefei 230009, China
c.
CAS Key Laboratory of Soft Matter Chemistry, Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei 230026, China

yaors@hfut.edu.cn

drfwang@ustc.edu.cn

Received Date: 23 December 2021
Revised Date: 27 February 2022
Accepted Date: 27 February 2022
Available Online: 4 March 2022

Figures(4)

A novel type of host–guest recognition systems have been developed on the basis of a Au(Ⅲ) molecular tweezer receptor and chiral Pt(Ⅱ) guests. The complementary host–guest motifs display high non-covalent binding affinity (K_a: ~10⁴ L/mol) due to the participation of two-fold intermolecular π–π stacking interactions. Both phosphorescence and chirality signals of the Pt(Ⅱ) guests strengthen in the resulting host–guest complexes, because of the cooperative rigidifying and shielding effects rendered by the tweezer receptor. Their intensities can be reversibly switched toward pH changes, by taking advantage of the electronic repulsion effect between the protonated form of tweezer receptor and the positive-charged guests in acidic environments. Overall, the current study demonstrates the feasibility to enhance and modulate phosphorescence and chirality signals simultaneously via molecular tweezer-based host–guest recognition.
- Host–guest chemistry,
- Molecular tweezer,
- Room-temperature phosphorescence,
- Chirality,
- Stimuli-responsiveness
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