Citation: Jingwen Jin, Jie Lin, Yipeng Huang, Linchun Zhang, Yaqi Jiang, Dongjie Tian, Fangyuan Lin, Yiru Wang, Xi Chen. High sensitivity ratiometric fluorescence temperature sensing using the microencapsulation of CsPbBr₃ and K₂SiF₆: Mn⁴⁺ phosphor[J]. Chinese Chemical Letters, ;2022, 33(11): 4798-4802. doi: 10.1016/j.cclet.2022.01.017 shu

High sensitivity ratiometric fluorescence temperature sensing using the microencapsulation of CsPbBr₃ and K₂SiF₆: Mn⁴⁺ phosphor

Jingwen Jin ^a ,
Jie Lin ^a ,
Yipeng Huang ^a ,
Linchun Zhang ^a ,
Yaqi Jiang ^a ,
Dongjie Tian ^a ,
Fangyuan Lin ^a ,
Yiru Wang ^a ,
Xi Chen ^{a, b, c, *,}

a.
Department of Chemistry and the MOE Key Laboratory of Spectrochemical Analysis & Instrumentation, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China
b.
State Key Laboratory of Marine Environmental Science, Xiamen University, Xiamen 361005, China
c.
Shenzhen Research Institute of Xiamen University, Shenzhen 518000, China

xichen@xmu.edu.cn

Received Date: 28 October 2021
Revised Date: 1 December 2021
Accepted Date: 7 January 2022
Available Online: 14 January 2022

Figures(4)

A dual emission sensing film has been prepared for colorimetric temperature sensing using CsPbBr₃ perovskite nanocrystals (CsPbBr₃ NCs) and manganese doped potassium fluorosilicate (K₂SiF₆: Mn⁴⁺, KSF) encapsulated in polystyrene by a microencapsulation strategy. The CsPbBr₃-KSF-PS film shows good temperature sensing response from 30 ℃ to 70 ℃, with a relative temperature sensitivity (S_r) up to 10.31% ℃⁻¹ at 45 ℃. Meanwhile, the film maintains more than 95% intensity after 6 heating-cooling cycles and keeps its fluorescence characteristics after 3 months. The film can be used to monitor temperature change by naked eye under a UV lamp. In particular, the temperature discoloration point of the sensing film can be controlled by the ratio change of CsPbBr₃: KSF to expand its applications. The study of the CsPbBr₃-KSF-PS sensing mechanism in this work is helpful to provide effective strategies for the design of reliable, high sensitivity and stable temperature sensing system using CsPbBr₃ NCs.
- Ratiometric fluorescence sensing,
- High sensitivity,
- Perovskite nanocrystals,
- Temperature,
- Microencapsulation
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High sensitivity ratiometric fluorescence temperature sensing using the microencapsulation of CsPbBr3 and K2SiF6: Mn4+ phosphor

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High sensitivity ratiometric fluorescence temperature sensing using the microencapsulation of CsPbBr₃ and K₂SiF₆: Mn⁴⁺ phosphor