Citation: Ying Yang, Fangsheng Tao, Lijuan Zhang, Yunshan Zhou, Yuxu Zhong, Shubo Tian, Yong'an Wang. Preparation of a porphyrin-polyoxometalate hybrid and its photocatalytic degradation performance for mustard gas simulant 2-chloroethyl ethyl sulfide[J]. Chinese Chemical Letters, ;2022, 33(5): 2625-2629. doi: 10.1016/j.cclet.2021.09.093 shu

Preparation of a porphyrin-polyoxometalate hybrid and its photocatalytic degradation performance for mustard gas simulant 2-chloroethyl ethyl sulfide

Ying Yang ^a ,
Fangsheng Tao ^a ,
Lijuan Zhang ^{a, *,} ,
Yunshan Zhou ^{a, *,} ,
Yuxu Zhong ^{b, *,} ,
Shubo Tian ^a ,
Yong'an Wang ^b

a.
State Key Laboratory of Chemical Resource Engineering, Institute of Chemistry, Beijing University of Chemical Technology, Beijing, 100029 China
b.
Toxicology and Medical Countermeasures, Beijing Institute of Pharmacology and Toxicology, Beijing, 100850, China

ljzhang@mail.buct.edu.cn

zhouys@mail.buct.edu.cn

yuxuzhong2008@aliyun.com

Received Date: 1 September 2021
Revised Date: 22 September 2021
Accepted Date: 25 September 2021
Available Online: 30 September 2021

Figures(7)

By combining 5, 10, 15, 20-tetra(4-chlorine)phenylporphyrin (TClPP) and α-Keggin polyoxometalate H₅PV₂Mo₁₀O₄₀ (H₅PVMo) via a simple ion-exchange method, an organic-inorganic hybrid material [C₄₄H₂₈N₄Cl₄]_1.5[H₂PMo₁₀V₂O₄₀]·2C₂H₆O (H₂TClPP-H₂PVMo) was prepared and thoroughly characterized by a variety of techniques. The homogeneous photocatalytic degradation of 2-chloroethyl ethyl sulfide (CEES) (5 µL) by H₂TClPP-H₂PVMo (1 × 10⁻⁶ mol/L) was studied in methanol and methanol-water mixed solvent (v/v = 1:1), in which the degradation rate of CEES reached 99.52% and 99.14%, respectively. The reaction followed first-order reaction kinetics, and the half-life and kinetic constant in methanol and the mixed solvent were respectively 33.0 min, −0.021 min⁻¹ and 15.7 min, −0.043 min⁻¹. Mechanism analysis indicated that under visible light irradiation in the air, CEES was degraded via oxidation and alcoholysis/hydrolysis in methanol and the mixed solvent. O₂^·− and ¹O₂ generated by H₂TClPP-H₂PVMo selectively oxidized CEES into a nontoxic sulfoxide. Singlet oxygen capture experiments showed that H₂TClPP-H₂PVMo (ϕ = 0.73) had a higher quantum yield of singlet oxygen than TClPP (ϕ = 0.35) under an air atmosphere and visible light irradiation.
- Chemical warfare agent,
- Mustard gas simulant,
- Porphyrin,
- Polyoxometalate,
- Photooxidation
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