Citation: Qianying Guo, Hongyan Ji, Lei Yang, Daizong Ji, Zhaolin Ai, Shi Luo, Jiatao Sun, Yunqi Liu, Dacheng Wei. Olefin-linked covalent organic frameworks with twisted tertiary amine knots for enhanced ultraviolet detection[J]. Chinese Chemical Letters, ;2022, 33(5): 2621-2624. doi: 10.1016/j.cclet.2021.09.082 shu

Olefin-linked covalent organic frameworks with twisted tertiary amine knots for enhanced ultraviolet detection

Qianying Guo ^{a, b, 1} ,
Hongyan Ji ^{c, 1} ,
Lei Yang ^{a, b} ,
Daizong Ji ^{a, b} ,
Zhaolin Ai ^{a, b} ,
Shi Luo ^{a, b} ,
Jiatao Sun ^{c, *,} ,
Yunqi Liu ^b ,
Dacheng Wei ^{a, b, **,}

a.
State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai 200433, China
b.
Institute of Molecular Materials and Devices, Fudan University, Shanghai 200433, China
c.
MIIT Key Laboratory for Low-Dimensional Quantum Structure and Devices, Beijing Institute of Technology, Beijing 100081, China

jtsun@bit.edu.cn

weidc@fudan.edu.cn

Received Date: 24 June 2021
Revised Date: 29 July 2021
Accepted Date: 24 September 2021
Available Online: 30 September 2021

Figures(4)

Though Olefin-linked covalent organic frameworks (oCOFs) possess excellent π-electron delocalization, the barely reversible olefin linkage brings challenges for oCOFs' synthesis and functionalization. Here, we synthesize new oCOFs with tertiary amine knots which have twisted configuration and electron-donating nature. Investigation into the structural variation and photoelectric performance shows that the twisted configuration of oCOF-TFPA could favor to the intramolecular charge transfer process and reduce the possibility of aggregation-caused quenching. Photoelectrical measurements and electric band structure calculation both verify the superiority of this oCOFs' structure in photoelectric sensing.
- Covalent organic frameworks,
- Olefin linkages,
- Tertiary amine knots,
- Twisted intramolecular charge transfer effect,
- Ultraviolet detection
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