Citation: Xianqiang Huang, Yanan Cui, Jinhong Zhou, Yalin Zhang, Guodong Shen, Qingxia Yao, Jikun Li, Zechun Xue, Guoping Yang. Self-assembly of three Ag-polyoxovanadates frameworks for their efficient construction of CN bond and detoxification of simulant sulfur mustard[J]. Chinese Chemical Letters, ;2022, 33(5): 2605-2610. doi: 10.1016/j.cclet.2021.09.042 shu

Self-assembly of three Ag-polyoxovanadates frameworks for their efficient construction of CN bond and detoxification of simulant sulfur mustard

Xianqiang Huang ^{a, *,} ,
Yanan Cui ^a ,
Jinhong Zhou ^a ,
Yalin Zhang ^a ,
Guodong Shen ^a ,
Qingxia Yao ^a ,
Jikun Li ^{b, *,} ,
Zechun Xue ^a ,
Guoping Yang ^{c, *,}

a.
Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry & Chemical Engineering, Liaocheng University, Liaocheng 252059, China
b.
College of Chemistry and Chemical Engineering, Taishan University, Taian 271021, China
c.
Jiangxi Province Key Laboratory of Synthetic Chemistry, Jiangxi Key Laboratory for Mass Spectrometry and Instrumentation, East China University of Technology, Nanchang 330013, China

hxqqxh2008@163.com

lijk0212@163.com

erick@ecut.edu.cn

Received Date: 18 August 2021
Revised Date: 2 September 2021
Accepted Date: 10 September 2021
Available Online: 16 September 2021

Figures(6)

Three imidazole-modified Ag-polyoxovanadates frameworks (APFs) with a controllable molar ratio of Ag⁺ to polyoxovanadates (POVs) [Ag(IM)₂]₂V₄O₁₂2Ag(IM)₂ (APF-1), [Ag₂(1-eIM)₄]₂[Ag(1-eIM)₂]₃2Ag(1-eIM)₂3(1-HeIM)[V₁₀O₂₈]₂ (APF-2) and [Ag(1-pIM)₂]₃[HV₁₀O₂₈]2Ag(1-pIM)₂2H₂O (APF-3) (IM = imidazole; 1-eIM = 1-ethylimidazole and 1-pIM = 1-propylimidazole) have been successfully achieved by self-assembly of POVs, Ag⁺ cations, and three different imidazole derivatives. Interestingly, the molar ratios of Ag⁺ to POVs vary from 4:1, 4.5:1 to 5:1 by changing the vanadium resources and imidazole derivatives. Notably, the coordination environment of Ag⁺ cations and the structure of POVs in the APFs are also different. Specifically, for APF-1, the four Ag atoms adopt three-coordinated and four-coordinated geometries, respectively, and Ag-imidazole complexes and [V₄O₁₂]⁴⁻ cluster form the one-dimensional polymeric chains. While Ag atoms in APF-2 and APF-3 exhibit two-, four- and five-coordinated geometries for APF-2, four-, five- and six-coordinated geometries for APF-3, respectively. These Ag⁺ cations and decavanadate clusters are assembled into the 2D supramolecular structure through the Ag-O bonds and Ag^…Ag argentophilic interaction. Remarkably, thus-obtained APF-2 can serve as powerful efficient heterogeneous catalyst for construction of CN bond and detoxification of simulant sulfur mustard (yields up to 99%), which enable successful recycling for three cycles with remained catalytic activities and structure stability.
- Ag-polyoxovanadates,
- Crystal engineering,
- Controllable synthesis,
- Bifunctional catalysts,
- Heterogeneous reaction
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