Citation: Yu-Fei Lei, Xiao-Lin Wang, Bo-Wen Liu, Li Chen, Yu-Zhong Wang. Bio-based removable pressure-sensitive adhesives derived from carboxyl-terminated polyricinoleate and epoxidized soybean oil[J]. Chinese Chemical Letters, ;2021, 32(2): 875-879. doi: 10.1016/j.cclet.2020.06.015 shu

Bio-based removable pressure-sensitive adhesives derived from carboxyl-terminated polyricinoleate and epoxidized soybean oil

The Collaborative Innovation Center for Eco-Friendly and Fire-Safety Polymeric Materials (MoE), National Engineering Laboratory of Eco-Friendly Polymeric Materials (Sichuan), State Key Laboratory of Polymer Materials Engineering, College of Chemistry, Sichuan University, Chengdu 610064, China

l.chen.scu@gmail.com

Received Date: 20 May 2020
Revised Date: 4 June 2020
Accepted Date: 9 June 2020
Available Online: 10 June 2020

Figures(6)

A novel kind of fully bio-based PSAs were obtained through the curing reaction between two components derived from the plant oils: carboxyl-terminated polyricinoleate (PRA) from the castor oil and epoxidized soybean oil (ESO). The gel content, glass transition temperature (T_g), rheological behavior, tensile strength, creep resistance and 180° peel strength of the PSAs were feasibly tailored by adjusting the component ratio of ESO to PRA. At low cross-linking level, the PSAs behaved like a viscous liquid and did not possess enough cohesiveness to sustain the mechanical stress during peeling. The PSAs cross-linked at or near the optimal stoichiometric conditions displayed an adhesive (interfacial) failure between the substrate and the adhesive layer, which were associated with the lowest adhesion levels. The PSAs with the dosage amount of ESO ranging from 10~20 wt% were tacky and flexible, which exhibited 180° peel strength ranging from 0.4~2.3 N/cm; and could be easily removed without any residues on the adherend. The process for the preparation of the fully bio-based PSAs was environmentally friendly without using any organic solvent or other toxic chemical, herein showing the great potential as sustainable materials.
- Pressure sensitive adhesive,
- Polyricinoleate,
- Epoxidized soybean oil,
- Viscoelasticity,
- Removability
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