Citation: Liu Yang, Shaohua Luo, Yafeng Wang, Yang Zhan, Qing Wang, Yahui Zhang, Xin Liu, Wenning Mu, Fei Teng. Excess capacity on compound phases of Li₂FeTiO₄ composite cathode materials synthesized by hydrothermal reaction using optional titanium sources to boost battery performance[J]. Chinese Chemical Letters, ;2020, 31(12): 3200-3204. doi: 10.1016/j.cclet.2020.05.036 shu

Excess capacity on compound phases of Li₂FeTiO₄ composite cathode materials synthesized by hydrothermal reaction using optional titanium sources to boost battery performance

Liu Yang ^{a, b, c} ,
Shaohua Luo ^{b, c, d, *,} ,
Yafeng Wang ^{a, b, c} ,
Yang Zhan ^{a, b, c} ,
Qing Wang ^{b, c, d, *,} ,
Yahui Zhang ^{b, c, d} ,
Xin Liu ^{a, b, c, d} ,
Wenning Mu ^{b, d} ,
Fei Teng ^{b, d}

a.
School of Materials Science and Engineering, Northeastern University, Shenyang 110819, China
b.
School of Resources and Materials, Northeastern University at Qinhuangdao, Qinhuangdao 066004, China
c.
Key Laboratory of Dielectric and Electrolyte Functional Material Hebei Province, Qinhuangdao 066004, China
d.
Qinhuangdao Laboratory of Resources Cleaner Conversion and Efficient Utilization, Qinhuangdao 066004, China

tianyanglsh@163.com

wangswork@126.com

Received Date: 12 March 2020
Revised Date: 16 May 2020
Accepted Date: 24 May 2020
Available Online: 26 May 2020

Figures(4)

Li₂FeTiO₄ composites have been produced using commercial LiAC, FeCl₂ and different titanium sources by hydrothermal synthesis (HS) at 175 ℃ and subsequent annealing at 700 ℃. Impure phase TiO₂, Fe₂O₃ and FeTiO₄ were detected out among the Li₂FeTiO₄ composites with different titanium sources. Micron and nano-sized particles of Li₂FeTiO₄ were prepared from various titanium raw materials, with nano-sized particles predominating when titanium raw materials were layered hydrogen titanate nanowire (H₂Ti₃O₇NW, HTO-NW) and titanium oxide nanotubes (TiO₂NB). The Li₂FeTiO₄ composites synthesized by HTO-NW shows a primary particle size of 50-200 nm of high crystallinity staggered with undissolved nanowire with a diameter size of about 100 nm. The samples using one-dimensional nanometer titanium oxide (TiO₂ NB) as the raw material can get a super high initial discharge capacity of 367.8 mAh/g at the rate of C/10 and excellent cycling stability. The selection of raw materials and adopting multi-phase modification can be considered as an effective strategy to improve the electro-chemical properties of Li₂FeTiO₄ composite cathode materials for the lithium secondary battery.
- Li₂FeTiO₄ nanocomposites,
- Cathode materials,
- Hydrothermal reaction,
- Lithium ion battery,
- Post-heat-treatment
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Excess capacity on compound phases of Li2FeTiO4 composite cathode materials synthesized by hydrothermal reaction using optional titanium sources to boost battery performance

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通讯作者: 陈斌, bchen63@163.com

Excess capacity on compound phases of Li₂FeTiO₄ composite cathode materials synthesized by hydrothermal reaction using optional titanium sources to boost battery performance