Citation: Yan Deng, Xing Li, Chengyou Han, Shengyi Dong. Supramolecular control over LCST behavior of hybrid macrocyclic system based on pillar[5]arene and crown ether[J]. Chinese Chemical Letters, ;2020, 31(12): 3221-3224. doi: 10.1016/j.cclet.2020.03.074 shu

Supramolecular control over LCST behavior of hybrid macrocyclic system based on pillar[5]arene and crown ether

Yan Deng ^{a, 1} ,
Xing Li ^{a, 1} ,
Chengyou Han ^{b, *,} ,
Shengyi Dong ^{a, *,}

a.
College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China
b.
Department of Chemistry, College of Science, China University of Petroleum (East China), Qingdao 266580, China

hanchengyou@upc.edu.cn

dongsy@hnu.edu.cn

Received Date: 1 March 2020
Revised Date: 15 March 2020
Accepted Date: 30 March 2020
Available Online: 9 April 2020

Figures(6)

A hybrid system containing a pillar[5]arene unit and ten crown ether moieties was developed. The LCST behavior and thermo-responsiveness were successfully introduced into this pillar[5]arene-crown ether system. Both host-guest interactions and salting-out effect displayed great effects in realizing the supramolecular control over LCST properties and thermo-responsiveness. Compared with the individual macrocycles, this hybrid macrocycle system dramatically amplified the supramolecular control effect over LCST behavior.
- Supramolecular chemistry,
- Lower critical solution temperature,
- Pillar[n] arene,
- Host-guest interactions,
- Crown ether
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