Citation: Lili Tang, Kejie Du, Bing Yu, Liangnian He. Oxidation of aromatic sulfides with molecular oxygen: Controllable synthesis of sulfoxides or sulfones[J]. Chinese Chemical Letters, ;2020, 31(12): 2991-2992. doi: 10.1016/j.cclet.2020.03.030 shu

Oxidation of aromatic sulfides with molecular oxygen: Controllable synthesis of sulfoxides or sulfones

Lili Tang ^a ,
Kejie Du ^d ,
Bing Yu ^{b, *,} ,
Liangnian He ^{c, *,}

a.
College of Chemistry & Materials Engineering, Huaihua University, Huaihua 418008, China
b.
Green Catalysis Center, College of Chemistry, Zhengzhou University, Zhengzhou 450001, China
c.
State Key Laboratory of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China
d.
Hunan Key Laboratory for the Design and Application of Actinide Complexes, University of South China, Hengyang 421001, China

bingyu@zzu.edu.cn

heln@nankai.edu.cn

Received Date: 4 February 2020
Revised Date: 3 March 2020
Accepted Date: 10 March 2020
Available Online: 13 March 2020

Figures(3)

The recent development of selective oxidation of aromatic sulfides with molecular oxygen was highlighted. The sulfoxides and sulfones could be obtained by simply switching the reaction media, i.e., bis(2-butoxyethyl)ether (BBE) or poly(ethylene glycol)dimethyl ether (PEGDME). The application of the high-boiling-point polyether as an initiator and green media can eliminate the need of large quantities of additives and volatile solvents. This strategy represents an economic and eco-friendly method that could find potential applications.
- Oxidation,
- Sulfides,
- Sulfoxides,
- Sulfones,
- Catalyst-free
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