Citation: Zhang Shouquan, Ge Xiutao, Chen Chunhua. Synthesis of carbon-coated Li₄Ti₅O₁₂ and its electrochemical performance as anode material for lithium-ion battery[J]. Chinese Chemical Letters, ;2017, 28(12): 2274-2276. doi: 10.1016/j.cclet.2017.11.034 shu

Synthesis of carbon-coated Li₄Ti₅O₁₂ and its electrochemical performance as anode material for lithium-ion battery

a.
School of Materials Science Chemical Engineering, Chuzhou University, Chuzhou 239000, China
b.
Department of Materials Science and Engineering, University of Science and Technology of China, Hefei 239026, China

Corresponding author: Zhang Shouquan, zsq780929@126.com
Received Date: 8 August 2017
Revised Date: 21 November 2017
Accepted Date: 23 November 2017
Available Online: 26 December 2017

Figures(6)

Carbon-coated Li₄Ti₅O₁₂ sample was synthesized by a sol-gel method. The Li₄Ti₅O₁₂ powders were obtained by calcinations of the gels at 750, 800, 850, 900℃ at N₂ atmosphere. The structure, morphology and electrochemical properties of the materials were characterized by SEM, XRD and charge and discharge. The final product sintered at 850℃ demonstrates excellent performance with a specific capacity of 163.5 mAh/g after 100 cycles at 1 C. Furthermore, the discharge specific capacity of the sample can retain 80 mAh/g at 10 C.
- Li₄Ti₅O₁₂,
- Sol-gel,
- Carbon-coated,
- Lithium-ion battery
1. [1]
  G.Q. Liu, L. Wen, G.Y. Liu, J. Alloys Compd. 509(2011) 6427-6432. doi: 10.1016/j.jallcom.2011.03.078
2. [2]
  T. Yuan, R. Cai, R. Ran, J. Alloys Compd. 505(2010) 367-373. doi: 10.1016/j.jallcom.2010.04.253
3. [3]
  T.F. Yi, B. Chen, H.Y. Shen, J. Alloys Compd. 558(2013) 11-17. doi: 10.1016/j.jallcom.2013.01.018
4. [4]
  C.H. Chen, J.T. Vaughey, A.N. Jansen, J. Electrochem. Soc. 148(2001) A102-A104. doi: 10.1149/1.1344523
5. [5]
  A.S. Prakash, P. Manikandan, K. Ramesha, J. Chem. Mater. 22(2010) 2857-2863. doi: 10.1021/cm100071z
6. [6]
  C.C. Li, Q.H. Li, L.B. Chen, et al., Appl. Mater. Interfaces 4(2012) 1233-1238. doi: 10.1021/am2018145
7. [7]
  S.H. Yu, A. Pucci, T. Herntrich, J. Mater. Chem. 26(2010) 806-810.
8. [8]
  J. Lim, E. Choi, V. Mathew, J. Electrochem. Soc. 158(2011) 275-280. doi: 10.1149/1.3527983
9. [9]
  Y.J. Bai, C. Gong, Y.X. Qi, J. Mater. Chem. 22(2012) 19054-19060. doi: 10.1039/c2jm34523d
10. [10]
  T.F. Yi, H.P. Liu, Y.R. Zhu, J. Power Sources 215(2012) 258-265. doi: 10.1016/j.jpowsour.2012.04.080
11. [11]
  Y.H. Yin, S.Y. Li, Z.J. Fan, J. Mater. Chem. Phys. 130(2011) 186-190. doi: 10.1016/j.matchemphys.2011.06.062
12. [12]
  B.B. Tia, H.F. Xiang, L. Zhang, J. Solid State Electrochem. 16(2012) 205-211. doi: 10.1007/s10008-011-1305-z
13. [13]
  J.P. Zhu, W. Zu, J.J. Yang, et al., Nanotechnology 12(2012) 2539-2542.
14. [14]
  J. Liu, X.F. Li, M. Cai, Electrochim. Acta 93(2013) 195-201. doi: 10.1016/j.electacta.2012.12.141
15. [15]
  M.V. Reddy, S. Madhavi, G.V. Subba Rao, B.V.R. Chowdari, J. Power Source 162(2006) 1312-1321. doi: 10.1016/j.jpowsour.2006.08.020
16. [16]
  J. Peng, Y.T. Zuo, G. Li, et al., Chin. Chem. Lett. 27(2016) 1559-1562. doi: 10.1016/j.cclet.2016.02.028
17. [17]
  L. Deng, W.H. Yang, S.X. Zhou, Chin. Chem. Lett. 26(2015) 1529-1534. doi: 10.1016/j.cclet.2015.06.009
1. [1]
  Xin Li , Ling Zhang , Yunyan Fan , Shaojing Lin , Yong Lin , Yongsheng Ying , Meijiao Hu , Haiying Gao , Xianri Xu , Zhongbiao Xia , Xinchuan Lin , Junjie Lu , Xiang Han . Carbon interconnected microsized Si film toward high energy room temperature solid-state lithium-ion batteries. Chinese Chemical Letters, 2025, 36(2): 109776-. doi: 10.1016/j.cclet.2024.109776
2. [2]
  Ming Zhong , Xue Guo , Yang Liu , Kun Zhao , Hui Peng , Suijun Liu , Xiaobo Zhang . Molybdenum-glycerate@zeolitic imidazolate framework spheres derived hierarchical nitrogen-doped carbon-encapsulated bimetallic selenides heterostructures for improved lithium-ion storage. Chinese Chemical Letters, 2025, 36(5): 109873-. doi: 10.1016/j.cclet.2024.109873
3. [3]
  Yue Qian , Zhoujia Liu , Haixin Song , Ruize Yin , Hanni Yang , Siyang Li , Weiwei Xiong , Saisai Yuan , Junhao Zhang , Huan Pang . Imide-based covalent organic framework with excellent cyclability as an anode material for lithium-ion battery. Chinese Chemical Letters, 2024, 35(6): 108785-. doi: 10.1016/j.cclet.2023.108785
4. [4]
  Huanyan Liu , Jiajun Long , Hua Yu , Shichao Zhang , Wenbo Liu . Rational design of highly conductive and stable 3D flexible composite current collector for high performance lithium-ion battery electrodes. Chinese Chemical Letters, 2025, 36(3): 109712-. doi: 10.1016/j.cclet.2024.109712
5. [5]
  Xin-Tong Zhao , Jin-Zhi Guo , Wen-Liang Li , Jing-Ping Zhang , Xing-Long Wu . Two-dimensional conjugated coordination polymer monolayer as anode material for lithium-ion batteries: A DFT study. Chinese Chemical Letters, 2024, 35(6): 108715-. doi: 10.1016/j.cclet.2023.108715
6. [6]
  Bing Jiang , Gang Zou , Bi Luo , Yan Guo , Jingru Li , Wendi Zhang , Qianxiao Fan , Lehao Liu , Lihua Chu , Qiaobao Zhang , Meicheng Li . Enhanced electrochemical performance of lithium-rich layered oxide materials: Exploring advanced coating strategies. Chinese Chemical Letters, 2025, 36(4): 109801-. doi: 10.1016/j.cclet.2024.109801
7. [7]
  Xiangkang Jiang , Zhixing Wang , Hong Dong , Xiang Zhang , Jin Hu , Manman Chu , Yanshuai Hong , Lei Xu , Wenjie Peng , Xiqian Yu , Jiexi Wang . An in-depth understanding of Al doping homogeneity affecting the performance of LiCoO₂ at cut-off voltage over 4.6 V. Chinese Chemical Letters, 2024, 35(12): 109553-. doi: 10.1016/j.cclet.2024.109553
8. [8]
  Jianjun Fang , Kunchen Xie , Yongli Song , Kangyi Zhang , Fei Xu , Xiaoze Shi , Ming Ren , Minzhi Zhan , Hai Lin , Luyi Yang , Shunning Li , Feng Pan . Break the capacity limit of Li4Ti5O12 anodes through oxygen vacancy engineering. Chinese Journal of Structural Chemistry, 2025, 44(2): 100504-100504. doi: 10.1016/j.cjsc.2024.100504
9. [9]
  Haixia Wu , Kailu Guo . Iodized polyacrylonitrile as fast-charging anode for lithium-ion battery. Chinese Chemical Letters, 2024, 35(10): 109550-. doi: 10.1016/j.cclet.2024.109550
10. [10]
  Mianying Huang , Zhiguang Xu , Xiaoming Lin . Mechanistic analysis of Co2VO4/X (X = Ni, C) heterostructures as anode materials of lithium-ion batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100309-100309. doi: 10.1016/j.cjsc.2024.100309
11. [11]
  Chenyue Huang , Hongfei Zheng , Ning Qin , Canpei Wang , Liguang Wang , Jun Lu . Single-Crystal Nickel-Rich Cathode Materials: Challenges and Strategies. Acta Physico-Chimica Sinica, 2024, 40(9): 2308051-0. doi: 10.3866/PKU.WHXB202308051
12. [12]
  Mengxiao Yang , Haicheng Huang , Shiyi Shen , Xinxin Liu , Mengyu Liu , Jiahua Guo , Fenghui Yang , Baoli Zha , Jiansheng Wu , Sheng Li , Fengwei Huo . Flexible aqueous zinc-ion battery with low-temperature resistant leather gel electrolyte. Chinese Chemical Letters, 2025, 36(6): 109988-. doi: 10.1016/j.cclet.2024.109988
13. [13]
  Jia-hui Li , Jinkai Qiu , Cheng Lian . Lithium-ion rapid transport mechanism and channel design in solid electrolytes. Chinese Journal of Structural Chemistry, 2025, 44(1): 100381-100381. doi: 10.1016/j.cjsc.2024.100381
14. [14]
  Liangliang Song , Haoyan Liang , Shunqing Li , Bao Qiu , Zhaoping Liu . Challenges and strategies on high-manganese Li-rich layered oxide cathodes for ultrahigh-energy-density batteries. Acta Physico-Chimica Sinica, 2025, 41(8): 100085-0. doi: 10.1016/j.actphy.2025.100085
15. [15]
  Xintong Zhu , Bin Cao , Chong Yan , Cheng Tang , Aibing Chen , Qiang Zhang . Advances in coating strategies for graphite anodes in lithium-ion batteries. Acta Physico-Chimica Sinica, 2025, 41(9): 100096-0. doi: 10.1016/j.actphy.2025.100096
16. [16]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . Rational Design of Bimetallic Oxide Anodes for Superior Li⁺ Storage. Acta Physico-Chimica Sinica, 2025, 41(3): 2311005-0. doi: 10.3866/PKU.WHXB202311005
17. [17]
  Jingshuo Zhang , Yue Zhai , Ziyun Zhao , Jiaxing He , Wei Wei , Jing Xiao , Shichao Wu , Quan-Hong Yang . Research Progress of Functional Binders in Silicon-Based Anodes for Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(6): 2306006-0. doi: 10.3866/PKU.WHXB202306006
18. [18]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 2408007-0. doi: 10.3866/PKU.WHXB202408007
19. [19]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-0. doi: 10.3866/PKU.WHXB202309028
20. [20]
  Chang Liu , Zirui Song , Xinglan Deng , Shihong Xu , Renji Zheng , Wentao Deng , Hongshuai Hou , Guoqiang Zou , Xiaobo Ji . Interfacial/bulk synergetic effects accelerating charge transferring for advanced lithium-ion capacitors. Chinese Chemical Letters, 2024, 35(6): 109081-. doi: 10.1016/j.cclet.2023.109081

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(935)
HTML views(44)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis of carbon-coated Li4Ti5O12 and its electrochemical performance as anode material for lithium-ion battery

Metrics

通讯作者: 陈斌, bchen63@163.com

Synthesis of carbon-coated Li₄Ti₅O₁₂ and its electrochemical performance as anode material for lithium-ion battery