Citation: Li Yong, Tang Li-Ping, Zhou Wei, Wang Xin-Rui. Fabrication of intercalated p-aminobenzoic acid into Zn-Ti layered double hydroxide and its application as UV absorbent[J]. Chinese Chemical Letters, ;2016, 27(9): 1495-1499. doi: 10.1016/j.cclet.2016.04.006 shu

Fabrication of intercalated p-aminobenzoic acid into Zn-Ti layered double hydroxide and its application as UV absorbent

Department of Chemistry, School of Science, Beijing Technology and Business University, Beijing 100048, China

Corresponding author: Wang Xin-Rui, wangxinrui@th.btbu.edu.cn
Received Date: 11 March 2016
Revised Date: 1 April 2016
Accepted Date: 6 April 2016
Available Online: 20 September 2016

Figures(8)

An organic ultraviolet (UV) ray absorbent, p-aminobenzoic acid (PABA) was intercalated into a Zn-Ti layered double hydroxide (LDH) precursor by an anion-exchange reaction to obtain ZnTi-PABA-LDH, a new organic-inorganic nanocomposite. The structure and the thermal stability of ZnTi-PABA-LDH were characterized by XRD, FT-IR and TG-DTA. The results indicate ZnTi-PABA-LDH, synthesized by this method, exhibit relatively high crystallinity, and markedly enhanced thermal stability of PABA after intercalation into ZnTi-LDH. The UV-vis-NIR spectrophotometric and ESR data show excellent UV ray resistance and greatly decreased photocatalytic activity when PABA is intercalated into the interlayers of the ZnTi-LDH. The studies suggest that ZnTi-PABA-LDH may have potential applications as safe sunscreen materials.
- Layered double hydroxide,
- p-Aminobenzoic acid,
- Intercalation,
- UV absorbent,
- Thermal stability
1. [1]
  Andrady A.L., Hamid H., Torikai A.. Effects of solar UV and climate change on materials[J]. Photochem. Photobiol. Sci., 2011,10:292-300. doi: 10.1039/c0pp90038a
2. [2]
  Matsumura Y., Ananthaswamy H.N.. Toxic effects of ultraviolet radiation on the skin[J]. Toxicol. Appl. Pharmacol., 2004,195:298-308. doi: 10.1016/j.taap.2003.08.019
3. [3]
  (a) W. Stahl, H. Sies, Carotenoids and protection against solar UV radiation, Skin Pharmacol. Appl. Skin Physiol. 15(2002) 291-296;
  (b) F. Xing, B. Zhao, W. Shi, Study on Tunable Fabrication of the Ultra-black Ni-P Film and its Blacking Mechanism, Electrochim. Acta 100(2013) 157-163.
4. [4]
  Wong T., Orton D.. Sunscreen allergy and its investigation[J]. Clin. Dermatol., 2011,29:306-310. doi: 10.1016/j.clindermatol.2010.11.002
5. [5]
  Zhao Y.B., Lin H.Y., Chen M.X., Yan D.P.. Niflumic anion intercalated layered double hydroxides with mechano-induced and solvent-responsive luminescence[J]. Ind. Eng. Chem. Res., 2014,53:3140-3147. doi: 10.1021/ie404054v
6. [6]
  Wang G.R., Xu S.M., Xia C.H.. Fabrication of host-guest UV-blocking materials by intercalation of fluorescent anions into layered double hydroxides[J]. RSC Adv., 2015,5:23708-23714. doi: 10.1039/C5RA00589B
7. [7]
  Sideris P.J., Nislsen U.G., Gan Z.H., Grey C.P.. Mg/Al ordering in layered double hydroxides revealed by multinuclear NMR spectroscopy[J]. Science, 2008,321:113-117. doi: 10.1126/science.1157581
8. [8]
  Li L., Ma R.Z., Ebina Y.. Layer-by-layer assembly and spontaneous flocculation of oppositely charged oxide and hydroxide nanosheets into inorganic sandwich layered materials[J]. J. Am. Chem. Soc., 2007,129:8000-8007. doi: 10.1021/ja0719172
9. [9]
  Yan D.P., Wei M.. Photofunctional Layered Materials, Springer International Publishing[J]. Switzerland, 2015.
10. [10]
  Fogg A.M., Green V.M., Harvey H.G., O'Hare D.. New separation science using shape-selective ion exchange intercalation chemistry[J]. Adv. Mater., 1999,11:1466-1469. doi: 10.1002/(ISSN)1521-4095
11. [11]
  Choy J.H., Kwak S.Y., Park J.S., Jeong Y.J., Portier J.. Intercalative nanohybrids of nucleoside monophosphates and DNA in layered metal hydroxide[J]. J. Am. Chem. Soc., 1999,121:1399-1400. doi: 10.1021/ja981823f
12. [12]
  Wang M.Z., Li Y., Ji J.J.. Novel hybrids of Cu²⁺ ternary complexes of salicylidene-amino acid Schiff base with phenanthroline (or bipyridine) intercalated in Mg/Al-NO₃-layered double hydroxide[J]. Chin. Chem. Lett., 2013,24:593-596. doi: 10.1016/j.cclet.2013.03.040
13. [13]
  Zhao L., Zhou J.J., Huang X.Y.. Design, synthesis and anti-proliferative effects in tumor cells of new combretastatin A-4 analogs[J]. Chin. Chem. Lett., 2015,26:993-999. doi: 10.1016/j.cclet.2015.05.003
14. [14]
  Wang X.R., Li Y., Tang L.P.. A reversible photochromic switch based on selfassembly of layered double hydroxide and decatungstate[J]. Sens. Actuators B, 2016,223:634-640. doi: 10.1016/j.snb.2015.09.147
15. [15]
  Das N., Samal A.. Synthesis, characterisation and rehydration behaviour of titanium(IV) containing hydrotalcite like compounds[J]. Microporous Mesoporous Mater., 2004,72:219-225. doi: 10.1016/j.micromeso.2004.04.004
16. [16]
  J. He, M. Wei, B. Li, et al., Preparation of layered double hydroxides, in:X. Duan, D.G. Evans (Eds.), Layered Double Hydroxides, vol. 119, Springer, Berlin/Heidelberg, 2006, pp. 89-119.
17. [17]
  Abdolmohammad-Zadeh H., Falaghi S., Rahimpour E.. An innovative nano-sorbent for selective solid-phase extraction and spectrophotometric determination of p-amino benzoic acid in cosmetic products[J]. Int. J. Cosmetic Sci., 2014,36:140-147. doi: 10.1111/ics.2014.36.issue-2
18. [18]
  Cantrell T., Jussel N., Morris S.. Sun damage and skin protection[J]. Pharmaceutics, 2002,425:1-8.
19. [19]
  Darvay A., White I.R., Rycroft R.J.G.. Photoallergic contact dermatitis is uncommon[J]. Br. J. Dermatol., 2001,145:597-601. doi: 10.1046/j.1365-2133.2001.04458.x
20. [20]
  Perioli L., Ambrogi V., Bertini B.. Anionic clays for sunscreen agent safe use:photoprotection, photostability and prevention of their skin penetration[J]. Eur. J. Pharm. Biopharm., 2006,62:185-193. doi: 10.1016/j.ejpb.2005.08.001
21. [21]
  Saber O., Tagaya H.. New layered double hydroxide, Zn-Ti LDH:preparation and intercalation reactions[J]. J. Incl. Phenom. Macrocyclic. Chem., 2003,45:107-115. doi: 10.1023/A:1023078728942
22. [22]
  Kloprogge J.T., Wharton D., Hickey L., Frost R.L.. Infrared and Raman study of interlayer anions CO₃^2-, NO₃^-, SO₄^2-, ClO₄^- in Mg/Al-hydrotalcite[J]. Am. Mineral., 2002,87:623-629. doi: 10.2138/am-2002-5-604
23. [23]
  Ma H.Y., Gao R., Yan D.P., Zhao J.W., Wei M.. Organic-inorganic hybrid fluorescent ultrathin films and their sensor application for nitroaromatic explosives[J]. J. Mater. Chem. C, 2013,1:4128-4137. doi: 10.1039/c3tc30142g
24. [24]
  Gao R., Zhao M.J., Guan Y.. Ordered and flexible lanthanide complex thin films showing up-conversion and color-tunable luminescence[J]. J. Mater. Chem. C, 2014,2:9579-9586. doi: 10.1039/C4TC01213E
25. [25]
  Yamamoto Y., Imai N., Mashima R.. Singlet oxygen from irradiated titanium dioxide and zinc oxide[J]. Methods Enzymol., 2000,319:29-37. doi: 10.1016/S0076-6879(00)19005-6
26. [26]
  Corazzari I., Livraghi S., Ferrero S.. Inactivation of TiO₂ nano-powders for the preparation of photo-stable sunscreens via carbon-based surface modification[J]. J. Mater. Chem., 2012,22:19105-19112. doi: 10.1039/c2jm32876c
1. [1]
  Xiaomeng Hu , Jie Yu , Lijie Sun , Linfeng Zhang , Wei Zhou , Dongpeng Yan , Xinrui Wang . Synthesis of an AVB@ZnTi-LDH composite with synergistically enhance UV blocking activity and high stability for potential application in sunscreen formulations. Chinese Chemical Letters, 2024, 35(11): 109466-. doi: 10.1016/j.cclet.2023.109466
2. [2]
  Guizhi Zhu , Junrui Tan , Longfei Tan , Qiong Wu , Xiangling Ren , Changhui Fu , Zhihui Chen , Xianwei Meng . Growth of CeCo-MOF in dendritic mesoporous organosilica as highly efficient antioxidant for enhanced thermal stability of silicone rubber. Chinese Chemical Letters, 2025, 36(1): 109669-. doi: 10.1016/j.cclet.2024.109669
3. [3]
  Sinong Wang , Shanshan Jin , Xue Yang , Yanyan Huang , Peng Liu , Yi Tang , Yuliang Yang . Development of Mg-Al LDH and LDO as novel protective materials for deacidification of paper-based relics. Chinese Chemical Letters, 2024, 35(9): 109890-. doi: 10.1016/j.cclet.2024.109890
4. [4]
  Shunshun Jiang , Ji Zhang , Jing Wang , Shan-Tao Zhang . Excellent energy storage properties in non-stoichiometric Bi_0.5Na_0.5TiO₃-based relaxor ferroelectric ceramics. Chinese Chemical Letters, 2024, 35(7): 108955-. doi: 10.1016/j.cclet.2023.108955
5. [5]
  Bo Yang , Pu-An Lin , Tingwei Zhou , Xiaojia Zheng , Bing Cai , Wen-Hua Zhang . Facile surface regulation for highly efficient and thermally stable perovskite solar cells via chlormequat chloride. Chinese Chemical Letters, 2024, 35(10): 109425-. doi: 10.1016/j.cclet.2023.109425
6. [6]
  Jinglin CHENG , Xiaoming GUO , Tao MENG , Xu HU , Liang LI , Yanzhe WANG , Wenzhu HUANG . NiAlNd catalysts for CO₂ methanation derived from the layered double hydroxide precursor. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1592-1602. doi: 10.11862/CJIC.20240152
7. [7]
  Bin Dong , Ning Yu , Qiu-Yue Wang , Jing-Ke Ren , Xin-Yu Zhang , Zhi-Jie Zhang , Ruo-Yao Fan , Da-Peng Liu , Yong-Ming Chai . Double active sites promoting hydrogen evolution activity and stability of CoRuOH/Co₂P by rapid hydrolysis. Chinese Chemical Letters, 2024, 35(7): 109221-. doi: 10.1016/j.cclet.2023.109221
8. [8]
  Jinqiang Gao , Haifeng Yuan , Xinjuan Du , Feng Dong , Yu Zhou , Shengnan Na , Yanpeng Chen , Mingyu Hu , Mei Hong , Shihe Yang . Methanol steam mediated corrosion engineering towards high-entropy NiFe layered double hydroxide for ultra-stable oxygen evolution. Chinese Chemical Letters, 2025, 36(1): 110232-. doi: 10.1016/j.cclet.2024.110232
9. [9]
  Yuchen Zhou , Huanmin Liu , Hongxing Li , Xinyu Song , Yonghua Tang , Peng Zhou . Designing thermodynamically stable noble metal single-atom photocatalysts for highly efficient non-oxidative conversion of ethanol into high-purity hydrogen and value-added acetaldehyde. Acta Physico-Chimica Sinica, 2025, 41(6): 100067-. doi: 10.1016/j.actphy.2025.100067
10. [10]
  Shilong Li , Ming Zhao , Yefei Xu , Zhanyi Liu , Mian Li , Qing Huang , Xiang Wu . Performance optimization of aqueous Zn/MnO₂ batteries through the synergistic effect of PVP intercalation and GO coating. Chinese Chemical Letters, 2025, 36(3): 110701-. doi: 10.1016/j.cclet.2024.110701
11. [11]
  Jingyuan Yang , Xinyu Tian , Liuzhong Yuan , Yu Liu , Yue Wang , Chuandong Dou . Enhancing stability of diradical polycyclic hydrocarbons via P=O-attaching. Chinese Chemical Letters, 2024, 35(8): 109745-. doi: 10.1016/j.cclet.2024.109745
12. [12]
  Xiping Dong , Xuan Wang , Zhixiu Lu , Qinhao Shi , Zhengyi Yang , Xuan Yu , Wuliang Feng , Xingli Zou , Yang Liu , Yufeng Zhao . Construction of Cu-Zn Co-doped layered materials for sodium-ion batteries with high cycle stability. Chinese Chemical Letters, 2024, 35(5): 108605-. doi: 10.1016/j.cclet.2023.108605
13. [13]
  Mohamed Saber Lassoued , Faizan Ahmad , Yanzhen Zheng . Film thickness effect on 2D lead-free hybrid double perovskite properties: Band gap, photocurrent and stability. Chinese Chemical Letters, 2025, 36(4): 110477-. doi: 10.1016/j.cclet.2024.110477
14. [14]
  Zhiqiang Liu , Qiang Gao , Wei Shen , Meifeng Xu , Yunxin Li , Weilin Hou , Hai-Wei Shi , Yaozuo Yuan , Erwin Adams , Hian Kee Lee , Sheng Tang . Removal and fluorescence detection of antibiotics from wastewater by layered double oxides/metal-organic frameworks with different topological configurations. Chinese Chemical Letters, 2024, 35(8): 109338-. doi: 10.1016/j.cclet.2023.109338
15. [15]
  Dongmei Dai , Xiaobing Lai , Xiaojuan Wang , Yunting Yao , Mengmin Jia , Liang Wang , Pengyao Yan , Yaru Qiao , Zhuangzhuang Zhang , Bao Li , Dai-Huo Liu . Increasing (010) active plane of P2-type layered cathodes with hexagonal prism towards improved sodium-storage. Chinese Chemical Letters, 2024, 35(10): 109405-. doi: 10.1016/j.cclet.2023.109405
16. [16]
  Juan Guo , Mingyuan Fang , Qingsong Liu , Xiao Ren , Yongqiang Qiao , Mingju Chao , Erjun Liang , Qilong Gao . Zero thermal expansion in Cs₂W₃O₁₀. Chinese Chemical Letters, 2024, 35(7): 108957-. doi: 10.1016/j.cclet.2023.108957
17. [17]
  Fengrui Yang , Debing Wang , Xinying Zhang , Jie Zhang , Zhichao Wu , Qiaoying Wang . Synergistic effects of peroxydisulfate on UV/O₃ process for tetracycline degradation: Mechanism and pathways. Chinese Chemical Letters, 2024, 35(10): 109599-. doi: 10.1016/j.cclet.2024.109599
18. [18]
  Huijuan Li , Zhu Wang , Jiagen Geng , Ruiping Song , Xiaoyin Liu , Chaochen Fu , Si Li . Current advances in UV-based advanced oxidation processes for the abatement of fluoroquinolone antibiotics in wastewater. Chinese Chemical Letters, 2025, 36(4): 110138-. doi: 10.1016/j.cclet.2024.110138
19. [19]
  Ren Shen , Yanmei Fang , Chunxiao Yang , Quande Wei , Pui-In Mak , Rui P. Martins , Yanwei Jia . UV-assisted ratiometric fluorescence sensor for one-pot visual detection of Salmonella. Chinese Chemical Letters, 2025, 36(4): 110143-. doi: 10.1016/j.cclet.2024.110143
20. [20]
  Ao Sun , Zipeng Li , Shuchun Li , Xiangbao Meng , Zhongtang Li , Zhongjun Li . Stereoselective synthesis of α-3-deoxy-D-manno-oct-2-ulosonic acid (α-Kdo) derivatives using a C3-p-tolylthio-substituted Kdo fluoride donor. Chinese Chemical Letters, 2025, 36(3): 109972-. doi: 10.1016/j.cclet.2024.109972

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(845)
HTML views(19)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142