Citation: Wu Si-Xue, Zhang Yi-Kun, Shi Hong-Wei, Yan Jie. Iodine-catalyzed N-sulfonylation of benzotriazoles with sodium sulfinates under mild conditions[J]. Chinese Chemical Letters, ;2016, 27(9): 1519-1522. doi: 10.1016/j.cclet.2016.03.024 shu

Iodine-catalyzed N-sulfonylation of benzotriazoles with sodium sulfinates under mild conditions

College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310015, China

Corresponding author: Yan Jie, jieyan87@zjut.edu.cn
Received Date: 27 January 2016
Revised Date: 2 March 2016
Accepted Date: 7 March 2016
Available Online: 24 September 2016

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A new and convenient procedure is developed for the preparation of N-sulfonylbenzotriazoles from sodium sulfinates and benzotriazoles using molecular iodine as catalyst via the S-N bond formation reaction. This catalytic radical sulfonylation proceeds efficiently in air at room temperature under neutral conditions, and in short reaction time, to afford the corresponding N-sulfonylbenzotriazoles in good yields, thus extending the catalytic application of molecular iodine in organic synthesis.
- Sulfonylation,
- Benzotriazole,
- Sodium sulfinate,
- Molecular iodine,
- Catalysis
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