Citation: Hong-Wei Shi, Chen Yu, Jie Yan. Potassium bromide or sodium chloride catalyzed acetoxyselenenylation of alkenes with diselenides and mCPBA[J]. Chinese Chemical Letters, ;2015, 26(9): 1117-1120. doi: 10.1016/j.cclet.2015.05.029 shu

Potassium bromide or sodium chloride catalyzed acetoxyselenenylation of alkenes with diselenides and mCPBA

1.
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310015, China

Corresponding author: Jie Yan,
Received Date: 11 March 2015
Available Online: 19 April 2015

KBr or NaCl is found to be a good catalyst in Se-Se bond cleavage of diselenides in the present of the oxidant mCPBA. The electrophilic addition of the in situ generated reactive electrophilic selenium species PhSeX (X=Br, Cl) to alkenes in AcOH provides a convenient access to 2-acetoxy-1-selenides. Compared with other catalysts, KBr or NaCl is less expensive and more environment-friendly.
- Acetoxyselenenylation,
- Diselenide,
- Alkene,
- Catalysis
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沈阳化工大学材料科学与工程学院沈阳 110142