Citation: Feng Yu, Ming-Yuan Zhu, Fei-Hong Ouyang, Bin Dai, Jian-Ming Dan. Hydrochlorination of acetylene using expanded multilayered vermiculite (EML-VMT)-supported catalysts[J]. Chinese Chemical Letters, ;2015, 26(9): 1101-1104. doi: 10.1016/j.cclet.2015.05.020 shu

Hydrochlorination of acetylene using expanded multilayered vermiculite (EML-VMT)-supported catalysts

¹ ,
Feng Yu ^1,2,3,, ,
Ming-Yuan Zhu ¹ ,
Fei-Hong Ouyang ¹ ,
Bin Dai ¹ ,
Jian-Ming Dan ^1,2,3,,

1.
1 Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, School of Chemistry and Chemical Engineering, Shihezi University, Shihezi 832003, China;
2.
2 Engineering Research Center of Materials-Oriented Chemical Engineering of Xinjiang Production and Construction Corps, Shihezi 832003, China;
3.
3 Key Laboratory of Materials-Oriented Chemical Engineering of Xinjiang Uygur Autonomous Region, Shihezi 832003, China

Corresponding author: Feng Yu, Jian-Ming Dan,
Received Date: 27 March 2015
Available Online: 5 May 2015
Fund Project: This work was financially supported by National Natural Science Foundation of China (Nos. 21163015, 21366027) (Nos. 21163015, 21366027) the Doctor Foundation of Bingtuan (No. 2014BB004) (No. 2014BB004) the National Basic Research Program of China (973Program, No. 2012CB720300) (973Program, No. 2012CB720300) the Program for Changjiang Scholars, Innovative Research Team in University (No. IRT1161) (No. IRT1161)

Catalyst supports have very important effects on catalyst performance. A novel expanded multilayered vermiculite (EML-VMT) is successfully used as the catalyst support for the acetylene hydrochlorination. By mixing carbon on the surface of EML-VMT (i.e., EML-VMT-C), the HgCl₂/EML-VMT-C achieved a high acetylene conversion of 97.3%, a vinyl chloride selectivity of 100% and a turn over frequency (TOF) value of 8.83×10^-3 s^-1 at a temperature of 140℃, an acetylene gas hourly space velocity (GHSV) of 108 h^-1, and a feed volume ratio V(HCl)/V(C₂H₂) of 1.15. Moreover, the HgCl₂/EML-VMT-C shows good stability. The EML-VMT also shows potential in the preparation of other EML-VMT-supported catalysts.
- Acetylene hydrochlorination,
- Vermiculite,
- Catalyst support,
- Acetylene conversion,
- Vinyl chloride selectivity
1. [1]
  [1] X.Y. Li, M.Y. Zhu, B. Dai, AuCl₃ on polypyrrole-modified carbon nanotubes as acetylene hydrochlorination catalysts, Appl. Catal. B:Environ. 142-143(2013) 234-240.
2. [2]
  [2] J.L. Zhang, N. Liu, W. Li, B. Dai, Progress on cleaner production of vinyl chloride monomers over non-mercury catalysts, Front. Chem. Sci. Eng. 5(2011) 514-520.
3. [3]
  [3] K. Zhou, B. Li, Q. Zhang, et al., The catalytic pathways of hydrohalogenation over metal-free nitrogen-doped carbon nanotubes, ChemSusChem 7(2014) 723-728.
4. [4]
  [4] K. Zhou, J.C. Jia, X.G. Li, et al., Continuous vinyl chloride monomer production by acetylene hydrochlorination on Hg-free bismuth catalyst:from lab-scale catalyst characterization, catalytic evaluation to a pilot-scale trial by circulating regeneration in coupled fluidized beds, Fuel Process. Technol. 108(2013) 12-18.
5. [5]
  [5] H. Bremer, H. Lieske, Kinetics of the hydrochlorination of acetylene on HgCl₂/active carbon catalysts, Appl. Catal. 18(1985) 191-203.
6. [6]
  [6] C.Y. Hou, L.R. Feng, F.L. Qiu, Highly active catalyst for vinyl acetate synthesis by modified activated carbon, Chin. Chem. Lett. 20(2009) 865-868.
7. [7]
  [7] X.Y. Li, X.L. Pan, X.H. Bao, Nitrogen doped carbon catalyzing acetylene conversion to vinyl chloride, J. Energy Chem. 23(2014) 131-135.
8. [8]
  [8] J.H. Xu, J. Zhao, J.T. Xu, et al., Influence of surface chemistry of activated carbon on the activity of gold/activated carbon catalyst in acetylene hydrochlorination, Ind. Eng. Chem. Res. 53(2014) 14272-14281.
9. [9]
  [9] K. Zhou, J.C. Jia, C.H. Li, et al., A low content Au-based catalyst for hydrochlorination of C₂H₂ and its industrial scale-up for future PVC processes, Green Chem. 17(2015) 356-364.
10. [10]
  [10] K. Zhou, J.K. Si, J.C. Jia, et al., Reactivity enhancement of N-CNTs in green catalysis of C₂H₂ hydrochlorination by a Cu catalyst, RSC Adv. 4(2014) 7766-7769.
11. [11]
  [11] X.Y. Li, X.L. Pan, L. Yu, et al., Silicon carbide-derived carbon nanocomposite as a substitute for mercury in the catalytic hydrochlorination of acetylene, Nat. Commun. 5(2014) 3688.
12. [12]
  [12] J. Zhang, T.Y. Liu, R. Chen, X.H. Liu, Vermiculite as a natural silicate crystal for hydrogen generation from photocatalytic splitting of water under visible light, RSC Adv. 4(2014) 406-408.
13. [13]
  [13] F.H. do Nascimento, J.C. Masini, Influence of humic acid on adsorption of Hg(II) by vermiculite, J. Environ. Manag. 143(2014) 1-7.
14. [14]
  [14] Y.F. Liu, Z.H. He, L. Zhou, Z.S. Hou, W.M.J. Eli, Simultaneous oxidative conversion and CO₂ reforming of methane to syngas over Ni/vermiculite catalysts, Catal. Commun. 42(2013) 40-44.
15. [15]
  [15] L.C.R. Machado, C.B. Torchia, R.M. Lago, Floating photocatalysts based on TiO₂ supported on high surface area exfoliated vermiculite for water decontamination, Catal. Commun. 7(2006) 538-541.
16. [16]
  [16] Y. Sun, L. Liu, D.Z. Jia, J.H. Liu, Preparation and properties of vermiculite supported TiO₂ photocatalyst, Chin. J. Inorg. Chem. 27(2011) 40-46.
17. [17]
  [17] X.G. Wang, B. Dai, Y. Wang, F. Yu, Nitrogen-doped pitch-based spherical active carbon as a nonmetal catalyst for acetylene hydrochlorination, ChemCatChem 6(2014) 2339-2344.
18. [18]
  [18] H.Y. Zhang, B. Dai, W. Li, et al., Non-mercury catalytic acetylene hydrochlorination over spherical activated-carbon-supported Au-Co (III)-Cu (II) catalysts, J. Catal. 316(2014) 141-148.
19. [19]
  [19] M.Y. Zhu, L.H. Kang, Y. Su, S.Z. Zhang, B. Dai, MCl_x (M=Hg, Au, Ru; x=2, 3) catalyzed hydrochlorination of acetylene-A density functional theory study, Can. J. Chem. 91(2013) 120-125.
20. [20]
  [20] F. Yu, L.L. Zhang, M.Y. Zhu, et al., Overwhelming microwave irradiation assisted synthesis of olivine-structured LiMPO₄(M=Fe, Mn, Co and Ni) for Li-ion batteries, Nano Energy 3(2014) 64-79.
21. [21]
  [21] F. Yu, S.H. Lim, Y.D. Zhen, Y.X. An, J.Y. Lin, Optimized electrochemical performance of three-dimensional porous LiFePO₄/C microspheres via microwave irradiation assisted synthesis, J. Power Sources 271(2014) 223-230.
22. [22]
  [22] Y.-H. Ma, G. Wu, N. Jiang, et al., Microwave-assisted, facile, rapid and solvent-free one pot two-component synthesis of some special acylals, Chin. Chem. Lett. 26(2015) 81-84.
23. [23]
  [23] S. Ittu, N. Constantin, Some characteristics of vermiculite mineral, Metal. Int. 18(2013) 73-76.
24. [24]
  [24] S. Hillier, E.M.M. Marwa, C.M. Rice, On the mechanism of exfoliation of 'Vermiculite', Clay Miner. 48(2013) 563-582.
25. [25]
  [25] X.X. Huo, L.M. Wu, L.B. Liao, Z.G. Xia, L.J. Wang, The effect of interlayer cations on the expansion of vermiculite, Powder Technol. 224(2012) 241-246.
26. [26]
  [26] L.L. Xu, X.G. Wang, H.Y. Zhang, et al., Application of a novel carbon carrier in acetylene hydrochlorination, Chem. Ind. Eng. Prog. 30(2011) 536-541.
1. [1]
  Yongsheng Xu , Lisha Yao , Jian Li , Yanzhao Dong , Dongyang Xie , Miaomiao Zhang , Feng Li , Yunsheng Dai , Jinli Zhang , Haiyang Zhang . Dual-ligand engineering over Au-based catalyst for efficient acetylene hydrochlorination. Chinese Chemical Letters, 2025, 36(3): 110318-. doi: 10.1016/j.cclet.2024.110318
2. [2]
  Junchen Peng , Xue Yin , Dandan Dong , Zhongyuan Guo , Qinqin Wang , Minmin Liu , Fei He , Bin Dai , Chaofeng Huang . Promotion effect of epoxy group neighboring single-atom Cu site on acetylene hydrochlorination. Chinese Chemical Letters, 2024, 35(6): 109508-. doi: 10.1016/j.cclet.2024.109508
3. [3]
  Sixiao Liu , Tianyi Wang , Lei Zhang , Chengyin Wang , Huan Pang . Cerium-based metal-organic framework-modified natural mineral vermiculite for photocatalytic nitrogen fixation under visible-light irradiation. Chinese Chemical Letters, 2025, 36(3): 110058-. doi: 10.1016/j.cclet.2024.110058
4. [4]
  Shaoming Dong , Yiming Niu , Yinghui Pu , Yongzhao Wang , Bingsen Zhang . Subsurface carbon modification of Ni-Ga for improved selectivity in acetylene hydrogenation reaction. Chinese Chemical Letters, 2024, 35(12): 109525-. doi: 10.1016/j.cclet.2024.109525
5. [5]
  Chunxiu Yu , Zelin Wu , Hongle Shi , Lingyun Gu , Kexin Chen , Chuan-Shu He , Yang Liu , Heng Zhang , Peng Zhou , Zhaokun Xiong , Bo Lai . Insights into the electron transfer mechanisms of peroxydisulfate activation by modified metal-free acetylene black for degradation of sulfisoxazole. Chinese Chemical Letters, 2024, 35(8): 109334-. doi: 10.1016/j.cclet.2023.109334
6. [6]
  Qijun Tang , Wenguang Tu , Yong Zhou , Zhigang Zou . High efficiency and selectivity catalyst for photocatalytic oxidative coupling of methane. Chinese Journal of Structural Chemistry, 2023, 42(12): 100170-100170. doi: 10.1016/j.cjsc.2023.100170
7. [7]
  Haodong Wang , Xiaoxu Lai , Chi Chen , Pei Shi , Houzhao Wan , Hao Wang , Xingguang Chen , Dan Sun . Novel 2D bifunctional layered rare-earth hydroxides@GO catalyst as a functional interlayer for improved liquid-solid conversion of polysulfides in lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(5): 108473-. doi: 10.1016/j.cclet.2023.108473
8. [8]
  Jinli Chen , Shouquan Feng , Tianqi Yu , Yongjin Zou , Huan Wen , Shibin Yin . Modulating Metal-Support Interaction Between Pt3Ni and Unsaturated WOx to Selectively Regulate the ORR Performance. Chinese Journal of Structural Chemistry, 2023, 42(10): 100168-100168. doi: 10.1016/j.cjsc.2023.100168
9. [9]
  Dong Sui , Jiayi Liu . Constriction-susceptible lithium support for fast cycling of solid-state lithium metal battery. Chinese Chemical Letters, 2025, 36(2): 110417-. doi: 10.1016/j.cclet.2024.110417
10. [10]
  Yunxia Liu , Guandong Wu , Lin Li , Yiming Niu , Bingsen Zhang , Botao Qiao , Junhu Wang . Construction of sintering-resistant gold catalysts via ascorbic-acid inducing strong metal-support interactions. Chinese Chemical Letters, 2025, 36(4): 110608-. doi: 10.1016/j.cclet.2024.110608
11. [11]
  Hong Yin , Zhipeng Yu . Hexavalent iridium catalyst enhances efficiency of hydrogen production. Chinese Journal of Structural Chemistry, 2025, 44(1): 100382-100382. doi: 10.1016/j.cjsc.2024.100382
12. [12]
  Jin Long , Xingqun Zheng , Bin Wang , Chenzhong Wu , Qingmei Wang , Lishan Peng . Improving the electrocatalytic performances of Pt-based catalysts for oxygen reduction reaction via strong interactions with single-CoN₄-rich carbon support. Chinese Chemical Letters, 2024, 35(5): 109354-. doi: 10.1016/j.cclet.2023.109354
13. [13]
  Xingxing Jiang , Yuxin Zhao , Yan Kong , Jianju Sun , Shangzhao Feng , Xin Lu , Qi Hu , Hengpan Yang , Chuanxin He . Support effect and confinement effect of porous carbon loaded tin dioxide nanoparticles in high-performance CO₂ electroreduction towards formate. Chinese Chemical Letters, 2025, 36(1): 109555-. doi: 10.1016/j.cclet.2024.109555
14. [14]
  Kailong Zhang , Chao Zhang , Luanhui Wu , Qidong Yang , Jiadong Zhang , Guang Hu , Liang Song , Gaoran Li , Wenlong Cai . Chloride molten salt derived attapulgite with ground-breaking electrochemical performance. Chinese Chemical Letters, 2024, 35(10): 109618-. doi: 10.1016/j.cclet.2024.109618
15. [15]
  Zimo Peng , Quan Zhang , Gaocan Qi , Hao Zhang , Qian Liu , Guangzhi Hu , Jun Luo , Xijun Liu . Nanostructured Pt@RuOx catalyst for boosting overall acidic seawater splitting. Chinese Journal of Structural Chemistry, 2024, 43(1): 100191-100191. doi: 10.1016/j.cjsc.2023.100191
16. [16]
  Yizhe Chen , Yuzhou Jiao , Liangyu Sun , Cheng Yuan , Qian Shen , Peng Li , Shiming Zhang , Jiujun Zhang . Nonmetallic phosphorus alloying to regulate the oxygen reduction mechanisms of platinum catalyst. Chinese Chemical Letters, 2025, 36(4): 110789-. doi: 10.1016/j.cclet.2024.110789
17. [17]
  Huipeng Zhao , Xiaoqiang Du . Polyoxometalates as the redox anolyte for efficient conversion of biomass to formic acid. Chinese Journal of Structural Chemistry, 2024, 43(2): 100246-100246. doi: 10.1016/j.cjsc.2024.100246
18. [18]
  Tao LIU , Yuting TIAN , Ke GAO , Xuwei HAN , Ru'nan MIN , Wenjing ZHAO , Xueyi SUN , Caixia YIN . A photothermal agent with high photothermal conversion efficiency and high stability for tumor therapy. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1622-1632. doi: 10.11862/CJIC.20240107
19. [19]
  Zhao Li , Huimin Yang , Wenjing Cheng , Lin Tian . Recent progress of in situ/operando characterization techniques for electrocatalytic energy conversion reaction. Chinese Chemical Letters, 2024, 35(9): 109237-. doi: 10.1016/j.cclet.2023.109237
20. [20]
  Guilong Li , Wenbo Ma , Jialing Zhou , Caiqin Wu , Chenling Yao , Huan Zeng , Jian Wang . A composite hydrogel with porous and homogeneous structure for efficient osmotic energy conversion. Chinese Chemical Letters, 2025, 36(2): 110449-. doi: 10.1016/j.cclet.2024.110449

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(984)
HTML views(41)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142